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呫吨-9-羧酸

呫吨-9-羧酸用途

【用途一】
抗胆碱药溴化丙胺太林的中间体。

呫吨-9-羧酸名称

[ CAS 号 ]:
82-07-5

[ 中文名 ]:
呫吨-9-甲酸

[ 英文名 ]:
Xanthene-9-carboxylic acid

[中文别名 ]:

[英文别名 ]:

Xanthene-9-carboxylic acid
9H-Xanthene-9-carboxylic acid
EINECS 201-394-9
MFCD00005059
9H-xanthene-9-carboxylicacid

呫吨-9-羧酸物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
391.3±41.0 °C at 760 mmHg

[ 熔点 ]:
221-225 °C(lit.)

[ 分子式 ]:
C₁₄H₁₀O₃

[ 分子量 ]:
226.227

[ 闪点 ]:
153.1±21.1 °C

[ 精确质量 ]:
226.062988

[ PSA ]:
46.53000

[ LogP ]:
2.45

[ 外观性状 ]:
固体;White to Almost white powder to crystal

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.646

[ 储存条件 ]:
室温

[ 水溶解性 ]:
methanol: 0.1 g/mL, clear

呫吨-9-羧酸MSDS

呫吨-9-羧酸安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36

[ 危险品运输编码 ]:
2811

[ WGK德国 ]:
3

[ 海关编码 ]:
2932999099

呫吨-9-羧酸合成路线

呫吨-9-羧酸上下游产品

呫吨-9-羧酸上游产品

呫吨-9-羧酸下游产品

呫吨-9-羧酸制备

呫吨醇、氰化钠、冰乙酸、乙醇及水的混合物，在密闭的反应罐中加热，缓缓升温至95℃，压力0.1-0.2MPa，反应6h，得9-氰基呫吨。然后用碱液回流20h，再用盐酸酸化，得呫吨-9-羧酸。

呫吨-9-羧酸海关

[ 海关编码 ]: 2932999099

[ 中文概述 ]:
2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

呫吨-9-羧酸文献

Fluorescein analogue xanthene-9-carboxylic acid: a transition-metal-free CO releasing molecule activated by green light.

Org. Lett. 15(17) , 4552-5, (2013)

6-Hydroxy-3-oxo-3H-xanthene-9-carboxylic acid is introduced as the first transition-metal-free carbon monoxide releasing molecule activated by visible light (photoCORM). This water-soluble fluorescein...

Anti-absence activity of mGlu1 and mGlu5 receptor enhancers and their interaction with a GABA reuptake inhibitor: Effect of local infusions in the somatosensory cortex and thalamus.

Epilepsia 56 , 1141-51, (2015)

Glutamate and γ-aminobutyric acid (GABA) are the key neurotransmitter systems in the cortical-thalamocortical network, involved in normal and pathologic oscillations such as spike-wave discharges (SWD...

A new method for assaying propantheline and its degradation product, xanthene-9-carboxylic acid using high-performance liquid chromatography.

J. Pharm. Sci. 72(1) , 96-8, (1983)

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