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4-硝基二苯胺

4-硝基二苯胺名称

[ CAS 号 ]:
836-30-6

[ 中文名 ]:
4-硝基二苯胺

[ 英文名 ]:
4-Nitrodiphenylamine

[中文别名 ]:

对硝基二苯胺

[英文别名 ]:

p-Nitrodiphenylamine
4-Nitro-N-phenylaniline
N-(4-Nitrophenyl)-N-phenylamine
EINECS 212-646-2
Benzenamine, 4-nitro-N-phenyl-
4-Nitrodiphenylamine
MFCD00007301

4-硝基二苯胺物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
382.6±25.0 °C at 760 mmHg

[ 熔点 ]:
132-135 °C(lit.)

[ 分子式 ]:
C₁₂H₁₀N₂O₂

[ 分子量 ]:
214.220

[ 闪点 ]:
185.2±23.2 °C

[ 精确质量 ]:
214.074234

[ PSA ]:
57.85000

[ LogP ]:
3.74

[ 外观性状 ]:
橙色结晶固体

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.666

[ 储存条件 ]:
室温

[ 水溶解性 ]:
INSOLUBLE

4-硝基二苯胺MSDS

4-硝基二苯胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: JJ9600000

CHEMICAL NAME :: Diphenylamine, 4-nitro-

CAS REGISTRY NUMBER :: 836-30-6

BEILSTEIN REFERENCE NO. :: 2051910

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C12-H10-N2-O2

MOLECULAR WEIGHT :: 214.24

WISWESSER LINE NOTATION :: WNR DMR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,66,1990 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >7940 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,66,1990

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 4 gm/kg

TOXIC EFFECTS :: Behavioral - excitement Behavioral - muscle contraction or spasticity Blood - hemorrhage

REFERENCE :: TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 8,126,1966

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >7940 mg/kg

TOXIC EFFECTS :: Behavioral - food intake (animal) Behavioral - changes in motor activity (specific assay)

REFERENCE :: ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,66,1990 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4095 No. of Facilities: 6 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 348 (estimated) No. of Female Employees: 34 (estimated)

4-硝基二苯胺安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
3077

[ WGK德国 ]:
3

[ RTECS号 ]:
JJ9600000

[ 包装等级 ]:
III

[ 危险类别 ]:
9

[ 海关编码 ]:
2921440000

4-硝基二苯胺合成路线

4-硝基二苯胺上下游产品

4-硝基二苯胺上游产品

4-硝基二苯胺下游产品

4-硝基二苯胺海关

[ 海关编码 ]: 2921440000

[ 中文概述 ]:
2921440000. 二苯胺及其衍生物以及它们的盐. 增值税率:17.0%. 退税率:17.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921440000. diphenylamine and its derivatives; salts thereof. VAT:17.0%. Tax rebate rate:17.0%. . MFN tariff:6.5%. General tariff:30.0%

4-硝基二苯胺文献

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Analyst 139(23) , 6232-41, (2014)

A method based on scanning laser ablation and inductively coupled plasma-mass spectrometry (SLA-ICPMS) and Raman micro-spectroscopy for the detection and identification of compounds consistent with gu...

Reduction of Nitrated Diphenylamine Derivatives under Anaerobic Conditions.

Appl. Environ. Microbiol. 61(9) , 3282-7, (1995)

2-Nitrodiphenylamine, 4-nitrodiphenylamine, and 2,4-dinitrodiphenylamine were anaerobically metabolized in sediment-water batch enrichments inoculated with mud from the German North Sea coast. The fir...

Heterogeneous catalytic transfer hydrogenation of 4-nitrodiphenylamine to p-phenylenediamines. Banerjee AA and Mukesh D.

J. Chem. Soc. Chem. Commun. 18 , 1275-1276, (1988)

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