1314-28-9

• 常用中文名：氧化铼
• 常用英文名：rhenium trioxide
• CAS号：1314-28-9
• 分子式：O₃Re
• 分子量：234.20500
• 相关类别： 无机化工 氧化物和过氧化物 金属氧化物
• 发布时间：2018-04-14 08:00:00
• 更新时间：2024-01-06 10:09:53

• 为二氧化硫转化成三氧化硫、亚硝酸转化为硝酸的催化剂。

名称

• 中文名: 氧化铼(VI)
• 英文名: trioxorhenium
• 英文别名: Rhenia; Rhenium trioxide; EINECS 215-228-8; MFCD00016306

物化性质

• 密度: 6.9-7.4
• 沸点: 400ºC
• 熔点: 400ºC (dec.)
• 分子式: O₃Re
• 分子量: 234.20500
• 闪点: 400°C
• 精确质量: 234.94000
• PSA: 51.21000
• 外观性状: Powder | Violet
• 储存条件:

  保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置

• 稳定性:

  如果遵照规格使用和储存则不会分解，未有已知危险反应，避免氧化物、水分/潮湿。散成薄层时，在透射光下呈绿色。它对于水和多数非氧化性或还原性试剂均无作用。在400℃时，它在真空中歧化成金属铼与七氧化二铼。

• 水溶解性: Insoluble in water.
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：234.940344 Da

  8、标称质量：235 Da

  9、平均质量：234.2052 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:3

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积51.2

  7.重原子数量:4

  8.表面电荷:0

  9.复杂度:61.8

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：绿色紫色粉末，无气味，一种红色的固体，立方晶系晶体。

  2. 密度（g/cm³,20℃）：6.9-7.4

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：400

  5. 沸点（ºC,常压）：400

  6. 沸点（ºC,0.05mmHg）：未确定

  7. 折射率（n20/D）：未确定

  8. 闪点（ºC）：400

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（mmHg,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：可溶于乙醇、丙酮、吡啶和甲醇等有机溶剂中，但不溶于纯醚与四氯化碳。

MSDS

Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE Product identifiers Product name: Rhenium(VI) oxide CAS-No.: 1314-28-9 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Laboratory chemicals, Manufacture of substances Section2. HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Eye irritation (Category 2) Specific target organ toxicity - single exposure (Category 3) Classification according to EU Directives 67/548/EEC or 1999/45/EC Irritating to eyes and respiratory system. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal wordWarning Hazard statement(s) H319Causes serious eye irritation. H335May cause respiratory irritation. Precautionary statement(s) P261Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Supplemental Hazardnone Statements According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R36/37Irritating to eyes and respiratory system. S-phrase(s) S22Do not breathe dust. S26In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39Wear suitable gloves and eye/face protection. Other hazards - none Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substances Formula: O3Re Molecular Weight: 234,21 g/mol ComponentConcentration Rhenium trioxide CAS-No.1314-28-9- EC-No.215-228-8 Section4. FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Indication of any immediate medical attention and special treatment needed no data available Section5. FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture rhenium oxides Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available Section6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. Section7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. strongly hygroscopic Specific end use(s) no data available Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Section9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) AppearanceForm: powder Colour: red, purple b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingno data available point f) Initial boiling point and no data available boiling range g) Flash pointnot applicable h) Evaporation rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerno data available flammability or explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative densityno data available n) Water solubilityno data available o) Partition coefficient: n- no data available octanol/water p) Auto-ignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available Section10. STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid Avoid moisture. Incompatible materials Strong oxidizing agents Hazardous decomposition products Other decomposition products - no data available Section11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure Inhalation - May cause respiratory irritation. Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects InhalationMay be harmful if inhaled. Causes respiratory tract irritation. IngestionMay be harmful if swallowed. SkinMay be harmful if absorbed through skin. May cause skin irritation. EyesCauses serious eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS: Not available Section12. ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects no data available Section13. DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. Section14. TRANSPORT INFORMATION UN number ADR/RID: -IMDG: -IATA: - UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA:Not dangerous goods Transport hazard class(es) ADR/RID: -IMDG: -IATA: - Packaging group ADR/RID: -IMDG: -IATA: - Environmental hazards ADR/RID: noIMDG Marine Pollutant: noIATA: no Special precautions for user no data available SECTION 15 - REGULATORY INFORMATION N/A SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常来说对水是无害的，若无政府许可，勿将材料排入周围环境。

安全

• 符号: GHS07
• 信号词: Warning
• 危害声明: H319-H335
• 警示性声明: P261-P305 + P351 + P338
• 个人防护装备: dust mask type N95 (US);Eyeshields;Gloves
• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): 36/37
• 安全声明 (欧洲): 22-26-37/39
• 危险品运输编码: NONH for all modes of transport
• WGK德国: 3

制备

在150℃下空气或氧气中氧化金属铼制取。

1.将装有约1g七氧化二铼的反应管从制备七氧化二铼的装置上取下来。将4mL的无水二氧六环(加入金属钠后进行蒸馏而被干燥的)倾在样品上，这个操作要快以免吸收水汽。然后缓慢地将反应管加热使氧化物溶解成无色的溶液。避免局部过热，否则会产生有色的溶液与不纯的产物。将此清亮的溶液放在冰浴中并使之冻结。将冻结物加热至室温，七氧化二铼二氧六环络合物以亮灰色的沉积物结晶出来，而过量的二氧六环则熔化了。冻结与熔化步骤至少需重复一次以保证络合物的良好分离。无色的澄清液中仅含有极微量的铼，用倾泻法将母液分离。室温下，将此络合物放在一只装有浓硫酸的真空干燥器中干燥。

将干燥后的络合物迅速地移入一只坩埚中，在电热板上缓慢地加热，首先熔化成无色至蓝绿色的液体，继续加热时它便分解成红色的三氧化铼和不含铼的挥发物。反应在数分钟内即完成。产物是化学纯的。产率约为95%，由于络合物在二氧六环中有一些溶解度而造成一些损耗。

2.将制备七氧化二铼的装置作如下的修改，即在图的装置中在反应管与装置的其余部分之间加一段长2～3mm，直径为1mm的毛细管。将1/10至1g的金属铼转化成七氧化二铼，然后利用升华将它提纯。熔封反应管顶部所有不挥发的残留物并将它拉下来。将反应管从水平位置弯成垂直位置，如图所示。

图VII-4 制备七氧化二铼的装置

图Ⅶ-5制备三氧化铼的装置(参阅图)

将系统抽空并充入100kPa的一氧化碳气。将装有七氧化二铼的管子放在甘油浴中慢慢地加热至175℃，并保持这个温度直到氧化物变为蓝色。然后将温度缓慢地升高到225℃，并在制品变为红色后，将温度升高到280℃。全部加热过程应不少于2至3h。红色的产物是纯的ReO3。产率是定量的。