494199-72-3

• 常用中文名：2-(二叔丁基膦甲基)吡啶
• 常用英文名：ditert-butyl(pyridin-2-ylmethyl)phosphane
• CAS号：494199-72-3
• 分子式：C₁₄H₂₄NP
• 分子量：237.32100
• 发布时间：2017-04-24 18:03:10
• 更新时间：2024-01-02 19:46:12

名称

• 中文名: 2-(二叔丁基膦甲基)吡啶
• 英文名: ditert-butyl(pyridin-2-ylmethyl)phosphane

物化性质

• 分子式: C₁₄H₂₄NP
• 分子量: 237.32100
• 精确质量: 237.16500
• PSA: 26.48000
• LogP: 4.66050

MSDS

Section 1: Product Identification Chemical Name:2-(Di-t-butylphosphinomethyl)pyridine, 98% CAS Registry Number:494199-72-3 Formula:C14H24NP EINECS Number:none Chemical Family:organophosphine ligand Synonym:none Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound494199-72-3100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry powder or foam If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep in a cool, dry, Handling and Storage: well-ventilated area. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:pale yellow liq Molecular Weight:237.32 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:no data Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:prolonged exposure to air Incompatibility:strong oxidizing agents Decomposition Products:carbon monoxide, carbon dioxide, phosphorus oxides and organic fumes SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Not reportable under SARA 313 Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

合成路线

109-06-8 13716-10-4 ~% 494199-72-3

文献：Zhang, Lei; Peng, Dongjie; Leng, Xuebing; Huang, Zheng Angewandte Chemie - International Edition, 2013 , vol. 52, # 13 p. 3676 - 3680 Angew. Chem., 2013 , vol. 52, # 13 p. 3676 - 3680,5

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