106990-43-6

• 常用中文名：光稳定剂 119
• 常用英文名：Chimassorb 119
• CAS号：106990-43-6
• 分子式：C₁₃₂H₂₅₀N₃₂
• 分子量：2285.61000
• 相关类别： 催化剂及助剂 紫外线吸收剂
• 发布时间：2018-02-08 08:00:00
• 更新时间：2024-01-03 11:49:49
• 【用途一】
  106990-43-6(光稳定剂 119)是一种非聚合型高分子量的受阻胺类光稳定剂，与其它受阻胺光稳定剂相比，其优点是能增强着色聚烯烃制品的色度。由于它的大分子结构，它适用于所有要求低挥发性和高抗迁移性的领域。106990-43-6(光稳定剂 119)同时也是一种有效的抗氧剂，可显著改善聚烯烃的长效热稳定性。

名称

• 中文名: 光稳定剂 119
• 英文名: Chimassorb 119
• 中文别名: 光稳定剂UV-119; 光稳定剂 944; 1,5,8,12-四[4,6-二(N-丁基-N-1,2,2,6,6-五甲基-4-哌啶基氨基)-1,3,5-三嗪-2-基]-1,5; 光稳定剂
• 英文别名: MFCD00134691; EINECS 401-990-0; 135TRIAZINE246TRIAMINENN12ETHANEDIYLBIS; Chimassorb 944; 6,6-pentamethyl-4-piperidinyl)amino]-1,3,5-triazin-2-yl]imino]-3,1-propenediyl]

物化性质

• 密度: 1.019g/cm3
• 熔点: 146-150 °C(lit.)
• 分子式: C₁₃₂H₂₅₀N₃₂
• 分子量: 2285.61000
• 闪点: 275 °C
• 精确质量: 2284.05000
• PSA: 237.06000
• LogP: 25.45640
• 折射率: 1.541
• 储存条件:

  保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置

• 稳定性:

  如果遵照规格使用和储存则不会分解，未有已知危险反应，避免强氧化物

• 水溶解性: chloroform, methylene chloride, and toluene: ≥20 % (w/w) at 20 °C
• 分子结构:

  1、摩尔折射率：705.49

  2、摩尔体积（cm³/mol）：2241.9

  3、等张比容（90.2K）：5684.6

  4、表面张力（dyne/cm）：41.3

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：279.67

  7、单一同位素质量：2284.054626 Da

  8、标称质量：2282 Da

  9、平均质量：2285.6118 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:29.8

  2.氢键供体数量:2

  3.氢键受体数量:32

  4.可旋转化学键数量:55

  5.互变异构体数量:6

  6.拓扑分子极性表面积237

  7.重原子数量:164

  8.表面电荷:0

  9.复杂度:3790

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：未确定

  2. 密度（g/mL,25ºC）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：146-150

  5. 沸点（ºC）：未确定

  6. 沸点（ºC，50mmHg）：未确定

  7. 折射率：未确定

  8. 闪点（°C）：未确定

  9. 比旋光度（ºF）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,20ºC）：未确定

  12. 饱和蒸气压（kPa,110ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：能溶于水的

MSDS

SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifiers Product name: 1,5,8,12-Tetrakis[4,6-bis(N-butyl-N-1,2,2,6,6- pentamethyl-4-piperidylamino)-1,3,5-triazin-2-yl]- 1,5,8,12-tetraazadodecane REACH No.: A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline. CAS-No.: 106990-43-6 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Laboratory chemicals, Manufacture of substances SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Skin sensitisation (Category 1), H317 Chronic aquatic toxicity (Category 2), H411 For the full text of the H-Statements mentioned in this Section, see Section 16. Classification according to EU Directives 67/548/EEC or 1999/45/EC R43 N Dangerous for theR51/53 environment For the full text of the R-phrases mentioned in this Section, see Section 16. Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal wordWarning Hazard statement(s) H317May cause an allergic skin reaction. H411Toxic to aquatic life with long lasting effects. Precautionary statement(s) P273Avoid release to the environment. P280Wear protective gloves. Supplemental Hazardnone Statements Other hazards - none SECTION 3: Composition/information on ingredients Substances Formula: C132H250N32 Molecular Weight: 2.285,61 g/mol CAS-No.: 106990-43-6 EC-No.: 401-990-0 Index-No.: 613-078-00-1 Hazardous ingredients according to Regulation (EC) No 1272/2008 ComponentClassificationConcentration N,N',N'',N'''-tetrakis(4,6-bis(butyl-(N-methyl-2,2,6,6-tetramethylpiperidin-4-yl)amino)triazin-2-yl)-4,7- diazadecane-1,10-diamine CAS-No.106990-43-6Skin Sens. 1; Aquatic Chronic <= 100 % EC-No.401-990-02; H317, H411 Index-No.613-078-00-1 Hazardous ingredients according to Directive 1999/45/EC ComponentClassificationConcentration N,N',N'',N'''-tetrakis(4,6-bis(butyl-(N-methyl-2,2,6,6-tetramethylpiperidin-4-yl)amino)triazin-2-yl)-4,7- diazadecane-1,10-diamine CAS-No.106990-43-6Xi, N, R43 - R51/53<= 100 % EC-No.401-990-0 Index-No.613-078-00-1 For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 SECTION 4: First aid measures Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 Indication of any immediate medical attention and special treatment needed no data available SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx) Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Avoid breathing dust. For personal protection see section 8. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. SECTION 7: Handling and storage Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated SECTION 8: Exposure controls/personal protection Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties a) AppearanceForm: powder Colour: white, off-white b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingMelting point/range: 146 - 150 °C - lit. point f) Initial boiling point and > 400 °C at 1.013 hPa boiling range g) Flash point275 °C h) Evapouration rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerno data available flammability or explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative density1,03 g/cm3 n) Water solubility0,0051 g/l at 20 °C at 5,2 - 5,8 hPa o) Partition coefficient: n- log Pow: 4,5 at 25 °C octanol/water p) Auto-ignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information Surface tension51,1 mN/m at 20 °C SECTION 10: Stability and reactivity Reactivity no data available Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials Strong oxidizing agents, Strong acids and strong bases Hazardous decomposition products In the event of fire: see section 5 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 Oral - rat - male and female - > 5.000 mg/kg (OECD Test Guideline 401) LD50 Dermal - rat - male and female - > 2.000 mg/kg (OECD Test Guideline 402) Skin corrosion/irritation Skin - rabbit Result: No skin irritation (OECD Test Guideline 404) Serious eye damage/eye irritation Eyes - rabbit Result: No eye irritation (OECD Test Guideline 405) Respiratory or skin sensitisation Maximisation Test - guinea pig May cause sensitisation by skin contact. (OECD Test Guideline 406) Germ cell mutagenicity in vitro assay S. typhimurium Result: negative Mutagenicity (micronucleus test) Hamster - male and female Result: negative Carcinogenicity IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Additional Information Repeated dose toxicity - rat - male and female - Oral - No observed adverse effect level - 5 mg/kg RTECS: Not available To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. SECTION 12: Ecological information Toxicity Toxicity to fishstatic test LC50 - Danio rerio (zebra fish) - > 119 mg/l - 96 h (OECD Test Guideline 203) Toxicity to algaestatic test EC50 - Pseudokirchneriella subcapitata (Selenastrum capricornutum) - 6,5 mg/l - 72 h (OECD Test Guideline 201) Persistence and degradability Biodegradabilityaerobic - Exposure time 28 d Result: 6 % - Not readily biodegradable. (OECD Test Guideline 301B) Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted Other adverse effects Toxic to aquatic life with long lasting effects. no data available SECTION 13: Disposal considerations Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. SECTION 14: Transport information UN number ADR/RID: -IMDG: -IATA: - UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA:Not dangerous goods Transport hazard class(es) ADR/RID: -IMDG: -IATA: - Packaging group ADR/RID: -IMDG: -IATA: - Environmental hazards ADR/RID: noIMDG Marine pollutant: noIATA: no Special precautions for user no data available SECTION 15: Regulatory information This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment For this product a chemical safety assessment was not carried out SECTION 16: Other information Full text of H-Statements referred to under sections 2 and 3. Aquatic ChronicChronic aquatic toxicity H317May cause an allergic skin reaction. H411Toxic to aquatic life with long lasting effects. Skin Sens.Skin sensitisation Full text of R-phrases referred to under sections 2 and 3 NDangerous for the environment XiIrritant R43May cause sensitisation by skin contact. R51/53Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Further information Copyright 2014 Co. LLC. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

安全

• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): R43
• 安全声明 (欧洲): 26-36-61-37-24-22
• WGK德国: 2