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12209-98-2生产厂家

12209-98-2价格

12209-98-2

12209-98-2结构式
12209-98-2结构式
  • 常用中文名:三水锡酸钠
  • 常用英文名:Sodium Stannate Trihydrate
  • CAS号:12209-98-2
  • 分子式:H6Na2O6Sn
  • 分子量:266.72500
  • 相关类别: 无机化工 无机盐 金属氧化物酸盐、金属过氧化物酸盐
  • 发布时间:2018-03-26 08:00:00
  • 更新时间:2024-01-04 23:44:21
  • 【用途一】
    用作织物防火剂和陶瓷工业的媒染剂
    【用途二】
    用作媒染剂,纺织品的防火剂、增重剂,以及制造陶瓷、玻璃和用于镀锡等
    【用途三】
    本品是碱性镀锡的主盐,它与氢氧化钠组成的络盐,溶解在镀锡溶液中,当溶液通电时,锡包含在阴络离子中,直接在阳极上还原碱性镀锡溶液。一般用量在75~90 kg/L,还可用于氰化物镀铜锡合金和焦磷酸盐,锡酸盐,铜锡合金的电镀辅助主盐。本品在印染行业作媒染剂,沉淀色素及陶瓷、玻璃和防火织物。

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中文名 三水锡(IV) 酸钠
英文名 dioxotin,sodium,trihydrate
中文别名 三水锡酸钠
锡酸钠,三水合物
英文别名 MFCD00150189
EINECS 235-030-5
Stannate (SnO32-),disodium,trihydrate (9CI)
Sodium tin(IV) oxide trihydrate
Sodium stannate hydrate
Sodium Stannate Trihydrate
熔点 140°C (dec.)
分子式 H6Na2O6Sn
分子量 266.72500
精确质量 267.89800
PSA 90.88000
外观性状 白色到灰白色 粉末
储存条件

常温密闭避光,通风干燥处

稳定性

140℃失水成为无水锡酸钠。易水解生成。锡酸xSnO2·yH2O,放置加热会变成β锡酸。

分子结构

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:267.898177 Da

8、标称质量:268 Da

9、平均质量:266.7336 Da

计算化学

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:3

3.氢键受体数量:5

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积37.1

7.重原子数量:7

8.表面电荷:0

9.复杂度:18.3

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:5

更多

1. 性状:白色或无色结晶。

2. 密度(g/mL,20℃):未确定

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):未确定

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,1mmHg):未确定

7. 折射率:未确定

8. 闪点(ºC):未确定

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):未确定

11. 蒸气压(20ºC):未确定

12. 饱和蒸气压(kPa,60ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:溶于水,不溶于乙醇和丙酮。


Section 1: Product Identification
Chemical Name:Sodium stannate trihydrate, min. 95%
CAS Registry Number:12209-98-2
Formula:Na2SnO3.3H2O
EINECS Number:none
Chemical Family:inorganic compound
Synonym:none

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound12209-98-2100%2mg/m3 (as Sn)2mg/m3 (as Sn)

Section 3: Hazards Identification
Emergency Overview:Irritating to eyes, skin and respiratory tract. May be harmful if swallowed
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:Prolonged exposure to dust of tin compounds may result in benign pneumoconiosis.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:none required
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andNone
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store material in a tightly sealed bottle away from moisture.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:If possible, handle the material in an efficient fume hood.
In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a
Respirator:
Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white pwdr.
Molecular Weight:212.68 (266.71)
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:Soluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:Active metals
Decomposition Products:none

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜

在眼睛上面:刺激的影响

致敏作用:没有已知的敏化现象

生态学数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

个人防护装备 Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
危害码 (欧洲) Xn
安全声明 (欧洲) S22-S24/25
危险品运输编码 NONH for all modes of transport
WGK德国 3
海关编码 2841900090

1.将446 kg锡(99.5%),320 kg苛性钠(90%),105 硝酸钠(95%)依次加入反应锅中,加热至300 ℃,当温度升至800 ℃时停止加热。继续搅拌待物料发火,经0.5 h的发火后,再冷却出锅。将粗品加水溶解,加硫化钠除铅,加过氧化氢除铁。常常后进行真空过滤,浓缩,离心脱水,干燥,粉碎得成品。反应式为:

12209-98-2 preparation

海关编码 2841900090