63214-58-4

63214-58-4结构式

常用中文名：哌啶(4-哌啶)甲烷酮
常用英文名：1-(PIPERIDIN-4-YLCARBONYL)PIPERIDINE
CAS号：63214-58-4
分子式：C₁₁H₂₀N₂O
分子量：196.28900
发布时间：2018-06-28 10:09:24
更新时间：2024-01-05 20:13:39

中文名	哌啶(4-哌啶)甲烷酮
英文名	piperidin-1-yl(piperidin-4-yl)methanone
中文别名	1-(哌啶-4-羰基)哌啶盐酸盐
英文别名	4-piperidyl piperidyl ketone Piperidin-4-yl-piperidin-1-yl-methanone

密度	1.047 g/cm3
沸点	350.5ºC at 760 mmHg
分子式	C₁₁H₂₀N₂O
分子量	196.28900
闪点	165.8ºC
精确质量	196.15800
PSA	32.34000
LogP	1.26520
折射率	1.505

Name:	Piperidino(4-piperidinyl)methanone Material Safety Data Sheet
Synonym:	None Known
CAS:	63214-58-4

Section 1 - Chemical Product MSDS Name:Piperidino(4-piperidinyl)methanone Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
63214-58-4	Piperidino(4-piperidinyl)methanone	97+	unlisted

Hazard Symbols: C
Risk Phrases: 20/21/22 34

Section 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Harmful if absorbed through the skin. Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Harmful if inhaled. Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure may cause effects similar to those of acute exposure.

Section 4 - FIRST AID MEASURES
Eyes: Do NOT allow victim to rub eyes or keep eyes closed. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Vacuum or sweep up material and place into a suitable, dry disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. Use only with adequate ventilation.
Storage:
Keep container closed when not in use. Corrosives area. Store in a cool, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 63214-58-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 107-109 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C11H20N2O
Molecular Weight: 196.29

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Oxidizing agents, acids, acid chlorides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 63214-58-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Piperidino(4-piperidinyl)methanone - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Pseudomonas putida:

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE SOLID, TOXIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 2923
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, TOXIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 2923
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, TOXIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 2923
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 63214-58-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 63214-58-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 63214-58-4 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A

危害码 (欧洲)	C,Xi

757949-38-5

~89%

63214-58-4

文献：BOTHMANN, Hendrick; Roncarati, Renza; Micco, Jolanda; Nencini, Arianna; Ghiron, Chiara Patent: US2010/16288 A1, 2010 ;

147635-70-9

63214-58-4

文献：Journal of Medicinal Chemistry, , vol. 26, # 10 p. 1433 - 1438

4968-87-0

63214-58-4

文献：Journal of Medicinal Chemistry, , vol. 26, # 10 p. 1433 - 1438

84358-13-4

63214-58-4

文献：European Journal of Medicinal Chemistry, , vol. 78, p. 401 - 418

110-89-4

63214-58-4

文献：European Journal of Medicinal Chemistry, , vol. 78, p. 401 - 418

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