14742-32-6

• 常用中文名：2-氨基-5-苯基-3-呋喃甲腈
• 常用英文名：2-amino-5-phenyl-3-furonitrile
• CAS号：14742-32-6
• 分子式：C₁₁H₈N₂O
• 分子量：184.19400
• 发布时间：2018-12-30 17:35:30
• 更新时间：2024-01-02 16:07:12
• 下载msds

名称

• 中文名: 2-氨基-5-苯基-3-呋喃甲腈
• 英文名: 2-amino-5-phenylfuran-3-carbonitrile
• 中文别名: 2-氨基-5-苯基-3-氰基呋喃
• 英文别名: 2-amino-5-phenyl-3-cyanofuran; MFCD00463472; 2-amino-5-phenyl-3-furonitrile; 2-Amino-5-phenyl-furan-3-carbonitrile; 2-amino-3-cyano-5-phenylfuran; F0777-1641; 2-amino-5-phenyl-3-furancarbonitrile

物化性质

• 密度: 1.26g/cm3
• 沸点: 378.8ºC at 760mmHg
• 熔点: 196ºC
• 分子式: C₁₁H₈N₂O
• 分子量: 184.19400
• 闪点: 182.9ºC
• 精确质量: 184.06400
• PSA: 62.95000
• LogP: 2.98168
• 蒸汽压: 6.12E-06mmHg at 25°C
• 折射率: 1.633

MSDS

Name: 2-Amino-5-phenyl-3-furonitrile 97% Material Safety Data Sheet Synonym: CAS: 14742-32-6 Section 1 - Chemical Product MSDS Name:2-Amino-5-phenyl-3-furonitrile 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 14742-32-6 2-Amino-5-phenyl-3-furonitrile 97% unlisted Hazard Symbols: XN Risk Phrases: 20/21/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 14742-32-6: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 196 - 198 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C11H8N2O Molecular Weight: 184 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 14742-32-6 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Amino-5-phenyl-3-furonitrile - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: NITRILES, SOLID, TOXIC, N.O.S.* Hazard Class: 6.1 UN Number: 3276 Packing Group: III IMO Shipping Name: NITRILES, TOXIC, N.O.S. Hazard Class: 6.1 UN Number: 3276 Packing Group: III RID/ADR Shipping Name: NITRILES, TOXIC, N.O.S. Hazard Class: 6.1 UN Number: 3276 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Safety Phrases: S 36/37 Wear suitable protective clothing and gloves. WGK (Water Danger/Protection) CAS# 14742-32-6: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 14742-32-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 14742-32-6 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): 22-36
• 安全声明 (欧洲): 26
• 海关编码: 2932190090

合成路线

70-11-1 109-77-3 ~80% 14742-32-6

文献：Bakavoli, Mehdi; Rahimizadeh, Mohammad; Gordi, Zinat Journal of Chemical Research, 2008 , # 10 p. 564 - 565

14476-72-3 ~70% 14742-32-6

文献：Abdelhamid, Abdou O.; Negm, Abdalla M.; Abbas, Ikhlass M. Journal fuer Praktische Chemie (Leipzig), 1989 , vol. 331, # 1 p. 31 - 36

14476-72-3 ~14% 14742-32-6 158692-52-5

文献：Foley, Louise H. Tetrahedron Letters, 1994 , vol. 35, # 33 p. 5989 - 5992

100805-20-7 ~89% 14742-32-6

文献：Nasakin; Sheverdov; Moiseeva; Ershov; Chernushkin; Tafeenko Russian Journal of General Chemistry, 1999 , vol. 69, # 2 p. 291 - 300

70-11-1 ~% 14742-32-6

文献：Maeda, Yutaka; Nakano, Masato; Sato, Hideyuki; Miyazaki, Yasushi; Schweiker, Stephanie L.; Smith, Jeffery L.; Truesdale, Anne T. Bioorganic and Medicinal Chemistry Letters, 2004 , vol. 14, # 15 p. 3907 - 3911

上下游产品

上游产品  3
70-11-1 109-77-3 14476-72-3
下游产品  2
220696-22-0 18031-97-5

海关

海关编码	2932190090
中文概述	2932190090 其他结构上有非稠合呋喃环化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%