203863-17-6

• 常用中文名：二水六氟乙酰丙酮钙
• 常用英文名：CALCIUM HEXAFLUOROACETYLACETONATE DIHYDRATE
• CAS号：203863-17-6
• 分子式：C₁₀H₆CaF₁₂O₆
• 分子量：490.21000
• 发布时间：2018-09-20 14:53:42
• 更新时间：2024-02-01 09:39:07

名称

• 中文名: 二水六氟乙酰丙酮钙
• 英文名: calcium,(Z)-1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olate,dihydrate
• 英文别名: Calcium hexafluoroacetylacetonate dihydrate

物化性质

• 沸点: 230-240ºC
• 熔点: 135-140ºC
• 分子式: C₁₀H₆CaF₁₂O₆
• 分子量: 490.21000
• 精确质量: 489.96000
• PSA: 71.06000
• LogP: 3.96120
• 外观性状: 灰白色粉末
• 更多:

  1. 性状：未确定

  2. 密度（g/mL20 ºC）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）未确定

  4. 熔点（ºC）：135-140

  5. 沸点（ºC,常压）：230-240

  6. 沸点（ºC5mmHg）：未确定

  7. 折射率：未确定

  8. 闪点（ºC5mmHg）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Section 1: Product Identification Chemical Name:Calcium hexafluoroacetylacetonate dihydrate, 97% CAS Registry Number:203863-17-6 Formula:Ca(CF3COCHCOCF3)2.2H2O EINECS Number:none Chemical Family:metal fluorobeta-diketonate complexes Synonym:Tris-hexafluoroacetylacetonate)calcium; tris(1,1,1,5,5,5-hexafluoro-2,4-pentandionato)calcium Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound203863-17-6100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and mucous membranes. Primary Routes of Exposure:Ingestion ,inhalation of dust, skin, eyes Eye Contact:Irritating to eyes. May cause redness and pain. Skin Contact:Mildly irritating to skin. May cause itching and redness. Inhalation:Inhalation of dust can lead to irritation of the respiratory tract, causing coughing and sore throat. Ingestion:No specific information is available on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Product contains fluorine which under certain conditions of use, decomposition, or metabolism, may generate Chronic Health Affects:fluoride ion, causing, nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth structure, kidney and liver damage. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:dry chemical, carbon dioxide, water fog, or foam. If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and corrosive hydrogen fluoride. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store the material in a tightly sealed container in a cool, dry place. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and clothing. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:off-white powder Molecular Weight:454.18 (486.18) Melting Point:135-140° Boiling Point:dec.230-240° Vapor Pressure:sublimes (180°C/.07mm) Specific Gravity:no data Odor:none Solubility in Water:slightly soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents Decomposition Products:carbon monoxide, carbon dioxide, calcium oxide, hydrogen fluoride, carbonyl fluoride, and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to federal, state, and local regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi