15699-18-0

• 常用中文名：硫酸镍铵
• 常用英文名：Nickel ammonium sulfate
• CAS号：15699-18-0
• 分子式：H₈N₂NiO₈S₂
• 分子量：286.89600
• 相关类别： 无机化工 无机盐 金属硫化物及硫酸盐
• 发布时间：2018-03-07 08:00:00
• 更新时间：2024-01-04 16:54:13
• 【用途一】
  用于电镀， 也可用作颜料
  【用途二】
  用作分析试剂
  【用途三】
  电镀、分析试剂。

名称

• 中文名: 硫酸镍铵
• 英文名: ammonium nickel sulfate
• 英文别名: MFCD00016251; azanium,nickel,sulfate; Ammonium Nickel Sulfate; EINECS 239-793-5

物化性质

• 密度: 1.929 g/cm3
• 沸点: 330ºC at 760mmHg
• 熔点: 85-89 °C(lit.)
• 分子式: H₈N₂NiO₈S₂
• 分子量: 286.89600
• 精确质量: 285.90800
• PSA: 178.10000
• LogP: 0.81860
• 外观性状: 暗绿色晶体
• 储存条件:

  存于密闭容器内， 置于凉爽、 通风处， 避免接触强酸、 硫。

• 稳定性:

  1.加热时失去结晶水变为黄色结晶粉末。

  2.皮肤接触过敏， 症状为发痒、 发红， 而后出现皮疹， 高度暴露或重复暴露会伤肺，引起咳嗽、气短、肺积水、气喘，对心脏、肝、肾有损害。

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:1

  3.氢键受体数量:4

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积89.6

  7.重原子数量:7

  8.表面电荷:-1

  9.复杂度:62.2

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:3

• 更多:

  1. 性状：蓝绿色结晶或结晶性粉末。略有风化性。

  2. 密度（g/mL,25/4℃）：1.923

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：85-89

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19.溶解性：易溶于水，不溶于乙醇。

MSDS

Name: Ammonium Nickel Sulfate Material Safety Data Sheet Synonym: Nickel ammonium sulfate CAS: 15699-18-0 Section 1 - Chemical Product MSDS Name:Ammonium Nickel Sulfate Material Safety Data Sheet Synonym:Nickel ammonium sulfate Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 15699-18-0 Nickel ammonium sulfate 100 % 239-793-5 Hazard Symbols: XN Risk Phrases: 22 40 42/43 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful if swallowed. Possible risks of irreversible effects. May cause sensitization by inhalation and skin contact. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Ingestion: Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Inhalation: Dust is irritating to the respiratory tract. May cause allergic respiratory reaction. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid immediately. Skin: Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Autoignition Temperature: Not applicable. Flash Point: Not applicable. NFPA Rating: Not published. Explosion Limits, Lower: Not available. Upper: Not available. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, observing precautions in the Protective Equipment section. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Avoid contact with skin and eyes. Do not ingest or inhale. Storage: Store in a cool, dry place. Keep container closed when not in use. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Appearance: green Odor: Not available. pH: Not available. Vapor Pressure: Not available. Vapor Density: Not available. Evaporation Rate: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Decomposition Temperature: Not available. Solubility: Soluble in hot water. Specific Gravity/Density: Not available. Molecular Formula: O8S2Ni.2H4N Molecular Weight: 286.8746 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, dust generation. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Oxides of nitrogen, oxides of sulfur, nickel oxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 15699-18-0: WS6050000 LD50/LC50: CAS# 15699-18-0: Oral, rat: LD50 = 400 mg/kg. Carcinogenicity: Nickel ammonium sulfate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION For further information, contact Fisher Scientific. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION CDG/CPL IMO No information available. IATA No information available. RID/ADR No information available. Canadian TDG No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. R 40 Possible risks of irreversible effects. R 42/43 May cause sensitization by inhalation and skin contact. Safety Phrases: S 22 Do not inhale dust. S 36/37 Wear suitable protective clothing and gloves. WGK (Water Danger/Protection) CAS# 15699-18-0: Canada CAS# 15699-18-0 is listed on Canada's DSL/NDSL List. WHMIS: Not available. CAS# 15699-18-0 is listed on Canada's Ingredient Disclosure List. Exposure Limits CAS# 15699-18-0:. OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3. OEL-A USTRALIA:TWA 1 mg(Ni)/m3. OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compo unds). OEL-BELGIUM:TWA 1 mg(Ni)/m3. OEL-CZECHOSLOVAKIA:TWA 0.05 mg(Ni) /m3;STEL 0.25 mg(Ni)/m3. OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen. OE L-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds). OEL-FINLAND:TWA 0.1 m g(Ni)/m3;Carcinogen. OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;CAR (insoluble compounds). OEL-FRANCE:TWA 1 mg(Ni)/m3. OEL-GERMANY;Carcinogen UNGARY:STEL 0.005 mg(Ni)/m3;CAR (insoluble compounds). OEL-HUNGARY:STE L 0.005 mg(Ni)/m3;Carcinogen. OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen. OE L-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3. OEL-THE NETHERLANDS:TWA 1 mg(Ni)/ m3 (insoluble compounds). OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3. OEL-RUS SIA:STEL 0.05 mg(Ni)/m3. OEL-SWEDEN:TWA 0.5 mg(Ni)/m3. OEL-SWITZERLAND :TWA 0.5 mg(Ni)/m3 (insoluble compounds). OEL-SWITZERLAND:TWA 0.5 mg(N i)/m3;Carcinogen JAN9. OEL-THAILAND:TWA 1 mg(Ni)/m3. OEL-UNITED KINGDO M:TWA 0.5 mg(Ni)/m3 (insoluble compounds). OEL-UNITED KINGDOM:TWA 1 mg (Ni)/m3 IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV US FEDERAL TSCA CAS# 15699-18-0 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : WS6050000 CAS REGISTRY NUMBER : 15699-18-0 LAST UPDATED : 199712 DATA ITEMS CITED : 37 MOLECULAR FORMULA : O8-S2.Ni.2H4-N MOLECULAR WEIGHT : 286.93 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 400 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : FDRLI* Food & Drug Research Laboratories, Inc., Papers. (P.O. Box 107, Rt. 17C, Waverly, NY 14892-0107) Volume(issue)/page/year: 8005A,1984 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 68100 ug/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold REFERENCE : INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 19600 ug/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold REFERENCE : INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 926 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold REFERENCE : INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 68100 ug/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold REFERENCE : INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 43 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold REFERENCE : INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 49,257,1990 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,178,1971 OSHA PEL (Gen Indu):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3 JAN 1993 OEL-AUSTRALIA:TWA 1 mg(Ni)/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen JAN 1993 OEL-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;Carcinogen (insoluble compounds) JAN 1993 OEL-FRANCE:TWA 1 mg(Ni)/m3 JAN 1993 OEL-GERMANY;Carcinogen JAN 1993 OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;Carcinogen (insoluble compounds) JAN 1993 OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3 JAN 1993 OEL-RUSSIA:STEL 0.05 mg(Ni)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Ni)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3;Carcinogen JAN 1993 OEL-THAILAND:TWA 1 mg(Ni)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg(Ni)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4948 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 7 (estimated)

安全

• 危害码 (欧洲): T
• 风险声明 (欧洲): R45
• 安全声明 (欧洲): S53-S22-S36/37-S45
• WGK德国: 3
• RTECS号: WS6061000

制备

1.制法

由热的硫酸镍饱和溶液和热的硫酸铵饱和溶液经酸化后混合而得。