41484-35-9

• 常用中文名：抗氧剂1035
• 常用英文名：Irganox-1035
• CAS号：41484-35-9
• 分子式：C₃₈H₅₈O₆S
• 分子量：642.92900
• 相关类别： 催化剂及助剂 抗氧剂
• 发布时间：2018-02-03 08:00:00
• 更新时间：2024-01-02 20:33:25

名称

• 中文名: 抗氧剂 1035
• 英文名: Irganox-1035
• 中文别名: 硫代二乙撑双[3-(3,5-二叔丁基-4-羟基苯基)丙酸酯]; 二[3,5-二-(1,1-二甲基乙基)-4-羟基-]苯丙酸硫杂二甘醇酯; 3,5-双(1,1-二甲基乙基)-4-羟基苯丙酸硫代二-2,1-乙二醇酯; 3,5-双(1,1-二甲基乙基)-4-羟基苯丙酸硫代二-2,1-乙二醇酯; 2,2'-硫代二乙基双[3-(3,5-二叔丁基-4-羟苯基)丙酸酯]; 抗氧剂1035
• 英文别名: Antioxidants 1035; diylester; fenozan30; MFCD00059346; EINECS 255-392-8; ANTIOXIDANT 1035; Thiodiethylene bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate); IRGANOX 1035; Thanox1035; 4-hydroxy-3,5-di-tert-butylphenylpropionicacidthioglycolate; 2,2'-Thiodiethylene Bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]

物化性质

• 密度: 1.072 g/cm C
• 沸点: 664.94ºC
• 熔点: 78 °C
• 分子式: C₃₈H₅₈O₆S
• 分子量: 642.92900
• 闪点: 352.6ºC
• 精确质量: 642.39500
• PSA: 118.36000
• LogP: 8.67280
• 外观性状: 白色至灰白色结晶粉末
• 折射率: 1.526
• 储存条件:

  密封、阴凉、干燥保存

• 稳定性:

  常规情况下不会分解，没有危险反应

• 计算化学:

  1.疏水参数计算参考值（XlogP）:10.4

  2.氢键供体数量:2

  3.氢键受体数量:7

  4.可旋转化学键数量:18

  5.互变异构体数量:3

  6.拓扑分子极性表面积118

  7.重原子数量:45

  8.表面电荷:0

  9.复杂度:799

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：未确定

  2. 密度（g/mL,25ºC）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）： 未确定

  4. 熔点（ºC）：78

  5. 沸点（ºC）：未确定

  6. 沸点（ºC，20mm hg）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（ºC）：未确定

  10. 自燃点或引燃温度（ºC）： 未确定

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

2,2'-Thiodiethylene Bis[3-(3,5-di-tert-butyl-4- Revision number: 5 hydroxyphenyl)propionate] SAFETY DATA SHEET Section1. IDENTIFICATION Product name:2,2'-Thiodiethylene Bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] Revision number:5 Section2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDSNot classified Not classified HEALTH HAZARDS ENVIRONMENTAL HAZARDSNot classified GHS label elements, including precautionary statements Pictograms or hazard symbolsNone Signal wordNo signal word Hazard statementsNone Precautionary statements:None Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Substance/mixture: Components:2,2'-Thiodiethylene Bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] >98.0%(LC)(T) Percent: CAS Number:41484-35-9 Chemical Formula:C38H58O6S Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Remove/Take off immediately all contaminated clothing. Rinse skin with Skin contact: water/shower. If skin irritation or rash occurs: Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present Eye contact: and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth. Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air- tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to generate poisonous fume. from the chemical: 2,2'-Thiodiethylene Bis[3-(3,5-di-tert-butyl-4- hydroxyphenyl)propionate] Section5. FIRE-FIGHTING MEASURES Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Use personal protective equipment. Keep people away from and upwind of spill/leak. Personal precautions, protective equipment and Entry to non-involved personnel should be controlled around the leakage area by emergency procedures: roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it. containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with up: appropriate laws and regulations. Section7. HANDLING AND STORAGE Precautions for safe handling Handling is performed in a well ventilated place. Wear suitable protective equipment. Technical measures: Prevent dispersion of dust. Wash hands and face thoroughly after handling. Use a local exhaust if dust or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Storage conditions:Keep container tightly closed. Store in a cool and dark place. Store away from incompatible materials such as oxidizing agents. Packaging material:Comply with laws. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Install a closed system or local exhaust as possible so that workers should not be Engineering controls: exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Dust respirator. Follow local and national regulations. Hand protection:Protective gloves. Eye protection:Safety glasses. A face-shield, if the situation requires. Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Solid Form:Crystal- Powder White - Almost white Colour: Odour:No data available pH: No data available Melting point/freezing point:78°C No data available Boiling point/range: Flash point:No data available Flammability or explosive limits: No data available Lower: Upper:No data available No data available Relative density: Solubility(ies): No data available [Water] [Other solvents]No data available 2,2'-Thiodiethylene Bis[3-(3,5-di-tert-butyl-4- hydroxyphenyl)propionate] Section10. STABILITY AND REACTIVITY Chemical stability:Stable under proper conditions. Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide, Sulfur oxides products: Section11. TOXICOLOGICAL INFORMATION orl-rat LD50:6300 mg/kg Acute Toxicity: Skin corrosion/irritation: No data available No data available Serious eye damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: No data available IARC = NTP =No data available No data available Reproductive toxicity: RTECS Number:DA8342500 Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available Crustacea:No data available Algae:No data available Persistence / degradability: No data available BioaccumulativeNo data available potential(BCF): Mobility in soil Log Pow:No data available Soil adsorption (Koc):No data available Henry's LawNo data available constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:Does not correspond to the classification standard of the United Nations UN-No:Not listed Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. 2,2'-Thiodiethylene Bis[3-(3,5-di-tert-butyl-4- hydroxyphenyl)propionate] SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统，若无政府许可，勿将材料排入周围环境。 CHEMICAL IDENTIFICATION RTECS NUMBER : DA8342500 CHEMICAL NAME : Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, thiodi-2,1-ethanediyl ester CAS REGISTRY NUMBER : 41484-35-9 LAST UPDATED : 199710 DATA ITEMS CITED : 6 MOLECULAR FORMULA : C38-H58-O6-S MOLECULAR WEIGHT : 643.02 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 6300 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : KSTPD7 Khimicheskaya Promyshlennost, Seriya: Toksikologiya i Sanitarnaya Khimiya Plastmass. Chemical Industry, Series: Toxicology and Sanitation Chemistry of Plastics. (V/o Mezhdunarodnaya Kniga, 113095 Moscow, USSR) 1979- Volume(issue)/page/year: (4),36,1979 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 6300 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : KSTPD7 Khimicheskaya Promyshlennost, Seriya: Toksikologiya i Sanitarnaya Khimiya Plastmass. Chemical Industry, Series: Toxicology and Sanitation Chemistry of Plastics. (V/o Mezhdunarodnaya Kniga, 113095 Moscow, USSR) 1979- Volume(issue)/page/year: (4),36,1979 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 6300 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : KSTPD7 Khimicheskaya Promyshlennost, Seriya: Toksikologiya i Sanitarnaya Khimiya Plastmass. Chemical Industry, Series: Toxicology and Sanitation Chemistry of Plastics. (V/o Mezhdunarodnaya Kniga, 113095 Moscow, USSR) 1979- Volume(issue)/page/year: (4),36,1979 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - E0670 No. of Facilities: 40 (estimated) No. of Industries: 2 No. of Occupations: 11 No. of Employees: 8942 (estimated) No. of Female Employees: 2234 (estimated)

安全

• RTECS号: DA8342500
• 海关编码: 2930909090

海关

海关编码	2930909090
中文概述	2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%