145428-94-0

• 常用中文名：番木鳖碱
• 常用英文名：brucine dihydrate
• CAS号：145428-94-0
• 分子式：C₂₃H₃₀N₂O₆
• 分子量：430.49400
• 相关类别： 天然产物 生物碱
• 发布时间：2018-04-02 08:00:00
• 更新时间：2024-01-13 19:32:37

名称

• 中文名: 番木鳖碱
• 英文名: brucine dihydrate
• 英文别名: 2,3-DIMETHOXYSTRYCHNIDIN-10-ONE DIHYDRATE; MFCD00149384; Strychnidin-10-one,2,3-dimethoxy-,dihydrate; 10,11-DIMETHOXYSTRYCHNINE DIHYDRATE; BRUCINE N-HYDRATE

物化性质

• 沸点: 633.7ºC at 760mmHg
• 熔点: 174 °C
• 分子式: C₂₃H₃₀N₂O₆
• 分子量: 430.49400
• 闪点: 337.1ºC
• 精确质量: 430.21000
• PSA: 69.70000
• LogP: 1.98400
• 外观性状: 白色结晶粉末或晶体
• 蒸汽压: 0mmHg at 25°C
• 储存条件: Poison room
• 更多:

  1. 性状：无色光亮针状结晶，味极苦

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：284～286

  分子结构数据 纠错 | 编辑

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：430.210387 Da

  8、标称质量：430 Da

  9、平均质量：430.4941 Da

MSDS

Name: Brucine dihydrate 99% Material Safety Data Sheet Synonym: Non CAS: 145428-94-0 Section 1 - Chemical Product MSDS Name:Brucine dihydrate 99% Material Safety Data Sheet Synonym:Non Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 145428-94-0 Brucine dihydrate 99.0 unlisted Hazard Symbols: T+ Risk Phrases: 26/28 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Very toxic by inhalation and if swallowed. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. Poison by ingestion. May cause tremors and convulsions. Inhalation: May cause respiratory tract irritation. May cause effects similar to those described for ingestion. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. SPEED IS ESSENTIAL. A DOCTOR MUST BE NOTIFIED AT ONCE. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Use only in a chemical fume hood. Storage: Poison room locked. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels. Exposure Limits CAS# 145428-94-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: @ 760.00mm Hg Freezing/Melting Point: 176.00 - 178.00 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: slightly soluble Specific Gravity/Density: Molecular Formula: C23H26N2O4.2H2O Molecular Weight: 430.50 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable. Conditions to Avoid: None reported. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Oxides of nitrogen, oxides of carbon, nitrogen. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 145428-94-0 unlisted. LD50/LC50: Not available. Carcinogenicity: Brucine dihydrate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: BRUCINE Hazard Class: 6.1 UN Number: 1570 Packing Group: I IMO Shipping Name: BRUCINE Hazard Class: 6.1 UN Number: 1570 Packing Group: I RID/ADR Shipping Name: BRUCINE Hazard Class: 6.1 UN Number: 1570 Packing group: I Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T+ Risk Phrases: R 26/28 Very toxic by inhalation and if swallowed. Safety Phrases: S 1 Keep locked up. S 13 Keep away from food, drink and animal feeding stuffs. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 145428-94-0: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 145428-94-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 145428-94-0 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): T+
• 风险声明 (欧洲): R26/28;R52/53
• 安全声明 (欧洲): S24/25
• WGK德国: 3