10003-69-7

• 常用中文名：(乙烷二硫代亚基四)四乙酸
• 常用英文名：4-PYRIDYLACETONITRILEHYDROCHLORIDE
• CAS号：10003-69-7
• 分子式：C₁₀H₁₄O₈S₄
• 分子量：390.47300
• 发布时间：2018-03-20 08:00:00
• 更新时间：2024-01-20 20:36:58

名称

• 中文名: (乙烷二硫代亚基四)四乙酸
• 英文名: 2-[1,2,2-tris(carboxymethylsulfanyl)ethylsulfanyl]acetic acid
• 中文别名: (乙烷二亚基四硫代)四乙酸
• 英文别名: EINECS 232-998-0; 2,2',2'',2'''-1,2-ethanedilidenetetrakis(thio)tetrakisacetic acid; 1,1',2,2'-ethanetetra(thioglycolic acid); 1,1,2,2-tetrakis-carboxymethylsulfanyl-ethane; 1,1,2,2-Tetrakis-carboxymethylmercapto-ethan; ETTA; 1,1,2,2-Tetrakis-carboxymethylmercapto-aethan; 2,2',2'',2'''-[1,2-ethanediylidenetetrakis(thio)]tetraacetic acid; 2,2',2'',2'''-[1,2-ethanediylidenetetrakis(thio)]tetrakisacetic acid

物化性质

• 密度: 1.707g/cm3
• 沸点: 777.7ºC at 760mmHg
• 熔点: 196-201ºC
• 分子式: C₁₀H₁₄O₈S₄
• 分子量: 390.47300
• 闪点: 424.2ºC
• 精确质量: 389.95700
• PSA: 250.40000
• LogP: 0.90980
• 蒸汽压: 1.65E-26mmHg at 25°C
• 折射率: 1.681
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、 摩尔折射率：86.54

  2、 摩尔体积（m³/mol）：228.7

  3、 等张比容（90.2K）：714.5

  4、 表面张力（3.0 dyne/cm）：95.2

  5、 极化率（0.5 10 ^-24cm ³）：34.30

• 计算化学:

  1.疏水参数计算参考值（XlogP）:1.5

  2.氢键供体数量:4

  3.氢键受体数量:12

  4.可旋转化学键数量:13

  5.互变异构体数量:无

  6.拓扑分子极性表面积250

  7.重原子数量:22

  8.表面电荷:0

  9.复杂度:342

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：196-201

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Name: (Ethanediylidenetetrathio)tetraacetic acid 99% Material Safety Data Sheet Synonym: None CAS: 10003-69-7 Section 1 - Chemical Product MSDS Name:(Ethanediylidenetetrathio)tetraacetic acid 99% Material Safety Data Sheet Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 10003-69-7 Acetic Acid,2,2',2'',2'''-1,2-Ethanedi 99 232-998-0 Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Corrosive. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: None Section 4 - FIRST AID MEASURES Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use carbon dioxide or dry chemical. Use agent most appropriate to extinguish fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Do not get on skin or in eyes. Avoid ingestion and inhalation. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes. Storage: Store in a cool, dry place. Keep container closed when not in use. Corrosives area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 10003-69-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Crystalline powder Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 196-201 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C10H14O8S4 Molecular Weight: 390.47 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Dust generation, excess heat. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 10003-69-7 unlisted. LD50/LC50: Not available. Carcinogenicity: Acetic Acid,2,2',2'',2'''-1,2-Ethanediylidenetetrakis(thio)e - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: IMO Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: RID/ADR Shipping Name: Not regulated. Hazard Class: UN Number: Packing group: Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 10003-69-7: No information available. Canada CAS# 10003-69-7 is listed on Canada's NDSL List. CAS# 10003-69-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 10003-69-7 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。

安全

• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): 36/37/38
• 安全声明 (欧洲): 37/39-26
• 危险品运输编码: UN 1759
• 包装等级: III
• 海关编码: 2930909090

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海关

海关编码	2930909090
中文概述	2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%