17608-09-2

• 常用中文名：2-甲氧基异硫氰酸苄酯
• 常用英文名：2-Methoxybenzyl isothiocyanate
• CAS号：17608-09-2
• 分子式：C₉H₉NOS
• 分子量：179.23900
• 发布时间：2018-03-17 08:00:00
• 更新时间：2024-01-14 13:52:24

名称

• 中文名: 2-甲氧基异硫氰酸苄酯
• 英文名: 2-Methoxybenzyl isothiocyanate
• 英文别名: 1-(isothiocyanatomethyl)-2-methoxybenzene

物化性质

• 密度: 1.06g/cm3
• 沸点: 133ºC
• 熔点: 28ºC
• 分子式: C₉H₉NOS
• 分子量: 179.23900
• 闪点: 122.2ºC
• 精确质量: 179.04000
• PSA: 53.68000
• LogP: 2.29800
• 蒸汽压: 0.00722mmHg at 25°C
• 折射率: 1.544

MSDS

Name: 2-Methoxybenzyl isothiocyanate 95+% Material Safety Data Sheet Synonym: CAS: 17608-09-2 Section 1 - Chemical Product MSDS Name:2-Methoxybenzyl isothiocyanate 95+% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 17608-09-2 2-Methoxybenzyl isothiocyanate 95+% unlisted Hazard Symbols: XN Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin.Moisture sensitive. Potential Health Effects Eye: Causes eye irritation. Lachrymator (substance which increases the flow of tears). Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 17608-09-2: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 115 - 117 deg C @0.2mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C9H9NOS Molecular Weight: 179 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to moist air or water. Incompatibilities with Other Materials: Amines, strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 17608-09-2 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Methoxybenzyl isothiocyanate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2811 Packing Group: III IMO Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: III RID/ADR Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 17608-09-2: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 17608-09-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 17608-09-2 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 风险声明 (欧洲): 20/21/22-36/37/38
• 安全声明 (欧洲): 26-36/37/39
• 危险品运输编码: UN 2810
• 海关编码: 2930909090

合成路线

75-15-0 6850-57-3 ~98% 17608-09-2

文献：Cao, Sheng-Li; Xu, Hong; Wang, Yao; Liao, Ji; Zhang, Jing-Jing; Li, Zhong-Feng; Guo, Yan-Wen; Li, Xiao-Rong; Cui, Xue-Mei; Xu, Xingzhi Medicinal Chemistry, 2012 , vol. 8, # 2 p. 163 - 173

333-20-0 7035-02-1 ~% 17608-09-2

文献：ALLERGAN, INC. Patent: US2011/28523 A1, 2011 ; Location in patent: Page/Page column 10-11 ;

6850-57-3 463-71-8 ~% 17608-09-2

文献：SHIONOGI and CO., LTD. Patent: EP1219612 A1, 2002 ;

6850-57-3 ~% 17608-09-2

文献：Kjaer; Jensen Acta Chemica Scandinavica (1947-1973), 1956 , vol. 10, p. 141

上下游产品

上游产品  5
75-15-0 6850-57-3 333-20-0 7035-02-1
463-71-8
下游产品  3
6850-57-3 612-16-8 66892-30-6

海关

海关编码	2930909090
中文概述	2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%