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71-55-6

71-55-6结构式
71-55-6结构式
  • 常用中文名:1,1,1-三氯乙烷
  • 常用英文名:1,1,1-Trichloroethane
  • CAS号:71-55-6
  • 分子式:C2H3Cl3
  • 分子量:133.404
  • 相关类别: 有机原料 烃类化合物及其衍生物 烃类卤化物
  • 发布时间:2018-07-26 08:01:34
  • 更新时间:2024-01-03 07:40:55
  • 【用途一】
    主要用作金属清洗剂、纺织品的干洗剂,还可用作粘接剂和金属切削添加剂及DAP树脂的聚合溶剂等
    【用途二】
    不燃性溶剂,可作清洗剂,清洗电子零部件,也可作金属脱脂的清洗剂。还可利用本品的低表面张力和高渗透能力的特性,测定金属焊接处的泄漏,也可用作气溶胶烟雾剂、耐火焰涂层材料、切削油冷却剂和制作低毒不燃的粘合剂。偏三氯乙烷的衍生物是有效的杀虫剂,制药工业的中间体。经氯化可制1,1,1,2-四氯乙烷。经脱氯化氢可制偏二氯乙烯。
    【用途三】
    1,1,1一三氯乙烷具有不燃不爆、微毒、溶解能力强、使用方便等特点,主要用作金属零件的脱脂洗净剂;精密仪器清洁剂、金属去油污、杀虫剂;印刷机、纤维的去污剂;有机物的革取剂、气溶胶添加剂;亦可用作耐火焰涂层材料,冷部乳胶液体及作为优良溶剂被广泛采用。
    【用途四】
    1,1,1一三氯乙烷具有不燃不爆、微毒、溶解能力强、使用方便等特点,主要用作金属零件的脱脂洗净剂;精密仪器清洁剂、金属去油污、杀虫剂;印刷机、纤维的去污剂;有机物的革取剂、气溶胶添加剂;亦可用作耐火焰涂层材料,冷部乳胶液体及作为优良溶剂被广泛采用。校准仪器和装置;评价方法;工作标准;质量保证/质量控制;其他。

化源商城直购

中文名 1,1,1-三氯乙烷
英文名 1,1,1-trichloroethane
中文别名 甲基氯仿
α-三氯乙烷
英文别名 Trichloroethane
Methyl Chloroform
Chloroform, methyl-
methyltrichloromethane
Ethana
trichloroethane,1,1,1-
MFCD00000806
EINECS 200-756-3
f140a
Trichloromethylmethane
Trichloroethane, 1,1,1-
R-140a
Ethane, 1,1,1-trichloro-
2,2,2-trichloroethane
Chlorothene
CH3CCl3
ethane, trichloro-
methylchloroform
1,1,1-TCE
密度 1.4±0.1 g/cm3
沸点 74.1±0.0 °C at 760 mmHg
熔点 −35 °C(lit.)
分子式 C2H3Cl3
分子量 133.404
闪点 -3.7±14.0 °C
精确质量 131.930038
LogP 2.11
外观性状 无色液体带有一种温和像醚的气味
蒸汽密度 4.6 (vs air)
蒸汽压 121.6±0.1 mmHg at 25°C
折射率 1.452
储存条件

储存注意事项储存于阴凉、通风的库房。远离火种、热源。保持容器密封。应与氧化剂、碱类、食用化学品分开存放,切忌混储。配备相应品种和数量的消防器材。储区应备有泄漏应急处理设备和合适的收容材料。

稳定性

1.在钴、镍、铂、钯盐及其氧化物存在下,反应可在150℃左右进行。在硫酸或金属氯化物存在下与水一起于加压下加热至75~160℃,生成乙酰氯和乙酸。在光照下氯化得到1,1,2,2-四氯乙烷。不含稳定剂的1,1,1-三氯乙烷于高温空气中氧化生成光气。1,1,1-三氯乙烷对石灰乳非常稳定,加热回流也几乎不发生分解。

2.稳定性 稳定

3.禁配物 强氧化剂、铝及其合金、强碱

4.避免接触的条件 光照

5.聚合危害不聚合

6.分解产物 氯化氢

水溶解性 1.4 g/L (20 ºc)
分子结构

1、摩尔折射率:25.82

2、摩尔体积(cm3/mol):95.7

3、等张比容(90.2K):222.1

4、表面张力(dyne/cm):28.9

5、介电常数:无可用的

6、极化率(10-24cm3):10.23

7、单一同位素质量:131.930033 Da

8、标称质量:132 Da

9、平均质量:133.4042 Da

计算化学

1.疏水参数计算参考值(XlogP):2.4

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:5

8.表面电荷:0

9.复杂度:26.4

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

更多

1.性状:无色液体

2.熔点(℃):-32.5

3.沸点(℃):74.1

4.相对密度(水=1):1.3376(20℃)

5.相对蒸气密度(空气=1):4.6

6.饱和蒸气压(kPa):13.33(20℃)

7.临界温度(℃):311.5

8.临界压力(MPa):4.48

9.辛醇/水分配系数:2.49

10.引燃温度(℃):500~537

11.爆炸上限(%):12.5

12.爆炸下限(%):7.5

13.溶解性:不溶于水,溶于乙醇、乙醚、丙酮、苯、甲醇、氯仿等。

14.黏度(mPa·s,15ºC):0.903

15.蒸发热(KJ/mol,b.p.):32.198

16.熔化热(KJ/mol):4.500

17.生成热(KJ/mol,25ºC,液体):138.1

18.比热容(KJ/(kg·K),-15~26ºC,平均):1.0684

19.电导率(S/m):7.3×10-9

20.相对密度(25℃,4℃):1.3299

21.常温折射率(n25):1.4313

22.偏心因子:0.216

23.溶度参数(J·cm-3)0.5:17.301

24.van der Waals面积(cm2·mol-1):7.580×109

25.van der Waals体积(cm3·mol-1):53.720

26.气相标准声称热(焓)( kJ·mol-1) :-142.3

27.气相标准熵(J·mol-1·K-1) :320.14

28.气相标准生成自由能( kJ·mol-1):-76.1

29.气相标准热熔(J·mol-1·K-1):92.34

30.液相标准声称热(焓)( kJ·mol-1):-177.40

31.液相标准熵(J·mol-1·K-1) :226.7

32.液相标准生成自由能( kJ·mol-1):-83.47

33.液相标准热熔(J·mol-1·K-1):144.4

国标编号: 61555
CAS: 71-55-6
中文名称: 1,1,1-三氯乙烷
英文名称: 1,1,1-trichloroethane;methyl chloroform
别 名: 甲基氯仿
分子式: C2H3Cl3;CH3CCl3
分子量: 133.42
熔 点: -32.5℃ 沸点:74.1℃
密 度: 相对密度(水=1)1.35;
蒸汽压:
溶解性: 不溶于水,溶于乙醇、乙醚等
稳定性: 稳定
外观与性状: 无色液体
危险标记: 14(有毒品)
用 途: 用作溶剂、金属清洁剂

2.对环境的影响
该物质对环境可能有危害,应特别注意对地下水的污染。在对人类重要食物链中,特别是在水生生物体中发生生物蓄积。
一、健康危害
侵入途径:吸入、食入、经皮吸收。
健康危害:急性中毒主要损害中枢神经系统。轻者表现为头痛、眩晕、步态蹒跚、共济失调、嗜睡等;重埏可出现抽搐,甚至昏迷。可引起心律不齐。对皮肤有轻度脱脂和刺激作用。
二、毒理学资料及环境行为
毒性:属低毒类。
急性毒性:LD 5010300mg/kg(大鼠经口);LC 5097920mg/m 3,4小时(大鼠吸入);人吸入54.6~14.96g/m 3,全麻醉,血压下降,心律不齐;人吸入14.196g/m 3×15分钟,不能站起;人吸入2.73g/m 3×180分钟,轻度嗜睡及眼刺激,头痛。
亚急性和慢性毒性:豚鼠吸入5.46g/m 3,3小时/天,3个月,肝重增加,有脂肪变性,肺炎。
危险特性:遇明火、高热能燃烧,并产生剧毒的光气和氯化氢烟雾。与碱金属和碱土金属能发生强烈反应。与活性金属粉末(如镁铝等)能发生反应,引起分解。
燃烧(分解)产物:一氧化碳、二氧化碳、氯化氢、光气。

3、现场应急监测方法


便携式气相色谱法;水质检测管法;气体检测管法

4、实验室监测方法

监测方法 来源 类别
气相色谱法 《城市和工业废水中有机化合物分析》王克欧等译 废水
气相色谱法 《空气中有害物质的测定方法》(第二版),杭士平主编 空气
吹扫捕集-气相色谱法 中国环境监测总站 水质
气相色谱法 《固体废弃物试验与分析评价手册》中国环境监测总站等译 固体废弃物
色谱/质谱法 美国EPA524.2方法 水质

5、环境标准

前苏联 车间空气中有害物质的最高容许浓度 20mg/m3
日本(1993) 环境标准 地面水:1mg/L
废水:3mg/L
土壤浸出液:1mg/L
  嗅觉阈浓度 400ppm

6、应急处理处置方法


一、泄漏应急处理
迅速撤离泄漏污染区人员至安全区,并进行隔离,严格限制出入。切断火源。建议应急处理人员戴自给正压式呼吸器,穿一般作业工作服。从上风处进入现场。尽可能切断泄漏源,防止进入下水道、排洪沟等限制性空间。小量泄漏:用砂土或其它不燃材料吸附或吸收。大量泄漏:构筑围堤或挖坑收容;用泡沫覆盖,降低蒸气灾害。用防爆泵转移至槽车或专用收集器内,回收或运至废物处理场所处置。
废弃物处置方法:用焚烧法。废料同其它燃料混合后焚烧,燃烧要充分,防止生成光气。焚烧炉排气中的卤化氢通过酸洗涤器除去。另外还应从废气废液中回收三氯乙烷,再循环使用。
二、防护措施
呼吸系统防护:空气中浓度超标时,应该佩戴直接式防毒面具(半面罩)。紧急事态抢救或撤离时,佩戴空气呼吸器。
眼睛防护:戴安全防护眼镜。
身体防护:穿防毒物渗透工作服。
手防护:戴防化学品手套。
其它:工作现场禁止吸烟、进食和饮水。工作毕,沐浴更衣。单独存放被毒物污染的衣服,洗后备用。注意个人清洁卫生。
三、急救措施
皮肤接触:脱去被污染的衣着,用肥皂水和清水彻底冲洗皮肤。
眼睛接触:提起眼睑,用流动清水或生理盐水冲洗。就医。
吸入:迅速脱离现场至空气新鲜处。保持呼吸道通畅。如困难,给输氧。如呼吸停止,立即进行人工呼吸。就医。
食入:饮足量温水,催吐,就医。
灭火方法:消防人员须佩戴防毒面具、穿全身消防服。喷水保持火场容器冷却,直至灭火结束。灭火剂:雾状水、泡沫、二氧化碳、砂土。

毒理学数据:

1.急性毒性

LD50:9600mg/kg(大鼠经口)

LC50:17000ppm(大鼠吸入,4h)

2.刺激性

家兔经皮:20mg(24h),中度刺激。

家兔经眼:100mg,轻度刺激。

3.亚急性与慢性毒性 豚鼠吸入5.46g/m3,每天3h,3个月,肝重增加,有脂肪变性,肺炎。

4.致突变性 微生物致突变:鼠伤寒沙门菌10μg/皿。DNA修复:大肠杆菌500mg/L。基因转化和有丝分裂重组:酿酒酵母5350mg/L。细胞遗传学分析:仓鼠卵巢160mg/L。

5.致畸性 大鼠孕后1~22d经口给予最低中毒剂量(TDLo)43mg/kg,致心血管系统发育畸形。

6.致癌性 IARC致癌性评论:G3,对人及动物致癌性证据不足。

生态学数据:

1.生态毒性

LC50:42.3~105mg/L(96h)(黑头呆鱼);73mg/L(48h)(青鳉)

2.生物降解性

好氧生物降解(h):3360~6552

厌氧生物降解(h):13440~26208

生物降解-二次沉降处理(h):220~250

3.非生物降解性

空气中光氧化半衰期(h):5393~53929

一级水解半衰期(h):0.73

4.其他有害作用 该物质对环境有危害,应特别注意对地下水的污染。

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KJ2975000
CHEMICAL NAME :
Ethane, 1,1,1-trichloro-
CAS REGISTRY NUMBER :
71-55-6
BEILSTEIN REFERENCE NO. :
1731614
LAST UPDATED :
199712
DATA ITEMS CITED :
89
MOLECULAR FORMULA :
C2-H3-Cl3
MOLECULAR WEIGHT :
133.40
WISWESSER LINE NOTATION :
GXGG1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Human - man
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
350 ppm
TOXIC EFFECTS :
Behavioral - hallucinations, distorted perceptions Behavioral - changes in motor activity (specific assay) Behavioral - changes in psychophysiological tests
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human
DOSE/DURATION :
670 mg/kg
TOXIC EFFECTS :
Gastrointestinal - hypermotility, diarrhea Gastrointestinal - nausea or vomiting Gastrointestinal - other changes
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human
DOSE/DURATION :
920 ppm/70M
TOXIC EFFECTS :
Behavioral - changes in motor activity (specific assay) Sense Organs and Special Senses (Eye) - conjunctive irritation
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
200 ppm/4H
TOXIC EFFECTS :
Behavioral - changes in motor activity (specific assay) Behavioral - irritability
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
9600 mg/kg
TOXIC EFFECTS :
Cardiac - pulse rate Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
18000 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3593 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
6 gm/kg
TOXIC EFFECTS :
Cardiac - pulse rate Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3911 ppm/2H
TOXIC EFFECTS :
Behavioral - excitement
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2568 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
16 gm/kg
TOXIC EFFECTS :
Behavioral - sleep Behavioral - ataxia
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
750 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
3100 mg/kg
TOXIC EFFECTS :
Liver - liver function tests impaired
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
95 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LC - Lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Primate - monkey
DOSE/DURATION :
>5000 ppm/7H
TOXIC EFFECTS :
Behavioral - tremor Behavioral - ataxia
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - cat
DOSE/DURATION :
24400 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
5660 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
15800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
9470 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10000 ppm/1H/13W-I
TOXIC EFFECTS :
Liver - other changes
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
1000 ppm/1H/13W-I
TOXIC EFFECTS :
Liver - other changes
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
3000 ppm/7H/29D-I
TOXIC EFFECTS :
Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
650 ppm/7H/58D-I
TOXIC EFFECTS :
Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
43 mg/kg
SEX/DURATION :
female 1-22 day(s) after conception lactating female 21 day(s) post-birth
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - cardiovascular (circulatory) system
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
DOSE :
2100 ppm/6H
SEX/DURATION :
female 1-20 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

MUTATION DATA

TYPE OF TEST :
Cytogenetic analysis
TEST SYSTEM :
Rodent - hamster Ovary
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 10(Suppl 10),1,1987 *** REVIEWS *** ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-STEL 2460 mg/m3 (450 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 1910 mg/m3 (350 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 20,515,1979 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 20,515,1979 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987 TOXICOLOGY REVIEW FAZMAE Fortschritte der Arzneimittelforschung. Progress in Drug Research. (Birkhauser Boston, Inc., c/o Springer-Verlag New York, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1959- Volume(issue)/page/year: 18,365,1974 TOXICOLOGY REVIEW EATR** U.S. Army, Edgewood Arsenal Technical Report. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: EB-TR-75047 TOXICOLOGY REVIEW AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 40(3),A46,1979 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 MSHA STANDARD-air:TWA 350 ppm (1900 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,161,1971 OSHA PEL (Gen Indu):8H TWA 350 ppm (1900 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 350 ppm (1900 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 350 ppm (1900 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 350 ppm (1900 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 125 ppm (680 mg/m3) JAN 1993 OEL-BELGIUM:TWA 350 ppm (1910 mg/m3);STEL 450 ppm (2460 mg/m3) JAN 1993 OEL-DENMARK:TWA 100 ppm (540 mg/m3) JAN 1993 OEL-FINLAND:TWA 100 ppm (540 mg/m3);STEL 250 ppm (1400 mg/m3) JAN 1993 OEL-FRANCE:TWA 300 ppm (1650 mg/m3);STEL 450 ppm (2500 mg/m3) JAN 1993 OEL-GERMANY:TWA 200 ppm (1080 mg/m3) JAN 1993 OEL-HUNGARY:TWA 100 mg/m3;STEL 300 mg/m3;Skin JAN 1993 OEL-JAPAN:TWA 200 ppm (1100 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 200 ppm (1080 mg/m3);STEL 500 ppm JAN 1993 OEL-THE PHILIPPINES:TWA 350 ppm (1900 mg/m3) JAN 1993 OEL-RUSSIA:TWA 200 ppm;STEL 20 mg/m3 JAN 1993 OEL-SWEDEN:TWA 50 ppm (300 mg/m3);STEL 90 ppm (500 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 200 ppm (1080 mg/m3);STEL 1000 ppm JAN 1993 OEL-TURKEY:TWA 350 ppm (1900 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 350 ppm (1900 mg/m3);STEL 450 ppm JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO 1,1,1-TRICHLOROETHANE-air:CL 350 ppm/15M REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 46970 No. of Facilities: 109850 (estimated) No. of Industries: 412 No. of Occupations: 205 No. of Employees: 1511801 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 46970 No. of Facilities: 120527 (estimated) No. of Industries: 417 No. of Occupations: 243 No. of Employees: 2528300 (estimated) No. of Female Employees: 762399 (estimated)

符号 GHS07
GHS07
信号词 Warning
危害声明 H420
警示性声明 P502
个人防护装备 Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
危害码 (欧洲) Xn:Harmful
风险声明 (欧洲) R19;R20;R40;R59;R66
安全声明 (欧洲) S24/25-S59-S61-S9-S46-S16-S45-S36/37
危险品运输编码 UN 2831 6.1/PG 3
WGK德国 3
RTECS号 KJ2975000
包装等级 III
危险类别 6.1(b)
海关编码 2903191090

1.乙烷氯化法由乙烷(或乙烯)氯化制得。

71-55-6 preparation

2.偏二氯乙烯氢氯化法由偏二氯乙烯与氯化氢经催化加成而得。

71-55-6 preparation

3.氯乙烯氢氯化法由氯乙烯与氯化氢作用,制得偏二氯乙烯,再经氯化而得。

71-55-6 preparation

海关编码 2903191010
中文概述 2903191010 1,1,1-三氯乙烷(甲基氯仿)〔用于清洗剂的除外〕。监管条件:14abxy。增值税率:17.0%。退税率:9.0%。最低关税:8.0%。普通关税:30.0%
申报要素 品名, 成分含量, 用途
监管条件 1.进口许可证 4.出口许可证 A.入境货物通关单 B.出境货物通关单 x.出口许可证(加工贸易) y.出口许可证(边境小额贸易)
检验检疫 M.进口商品检验 N.出口商品检验
Summary 2903191010 1,1,1-trichloroethane。supervision conditions:14abxy。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:8.0%。general tariff:30.0%