58-36-6

• 常用中文名：10,10'-氧代双吩砒
• 常用英文名：Bis(10-phenoxarsyl)oxide
• CAS号：58-36-6
• 分子式：C₂₄H₁₆As₂O₃
• 分子量：502.225
• 发布时间：2018-04-19 08:00:00
• 更新时间：2024-01-02 20:12:15

名称

• 中文名: 10,10’-氧代双吩砒
• 英文名: 10-phenoxarsinin-10-yloxyphenoxarsinine
• 中文别名: 10,10’-氧双吩恶砒; 10,10’-氧双-10H-吩恶砒; 防霉剂 OBPA; 吩砒嗪氧化物; 防霉剂75号
• 英文别名: OBPA; Vinyzene SB 1; EINECS 200-377-3; 10,10'-Oxybis(10H-phenoxarsinine); Vinyzene BP 5-2; Vinadine; diphenoxarsin-10-yl oxide; 10H,10'H-10,10'-oxy-bis-phenoxarsine; 10,10'-oxybis phenoxarsine; Durotex; Bis(10-phenoxarsyl)oxide; bis-phenoxarsin-10-yl oxide; Bis(phenoxarsin-10-yl)ether; Phenoxarsine oxide; 10H-Phenoxarsine, 10,10'-oxybis-; Vinyzene BP 5; Phenoxaksine oxide; Vinyzene (pesticide); Bis-phenoxarsin-10-yl-oxid

物化性质

• 密度: 1.40-1.42
• 沸点: 531.3±43.0 °C at 760 mmHg
• 熔点: 180-184°C
• 分子式: C₂₄H₁₆As₂O₃
• 分子量: 502.225
• 闪点: 214.1±28.1 °C
• 精确质量: 501.953125
• PSA: 27.69000
• LogP: 2.82620
• 外观性状: 一种透明淡黄色液体带有一种温和气味
• 蒸汽压: 0.0±1.3 mmHg at 25°C
• 储存条件: 2-8℃
• 水溶解性: insoluble
• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:3

  4.可旋转化学键数量:2

  5.互变异构体数量:无

  6.拓扑分子极性表面积27.7

  7.重原子数量:29

  8.表面电荷:0

  9.复杂度:482

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1.熔点（℃）：180-184。

  2.密度：1.40-1.42。

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : SP6800000 CHEMICAL NAME : Phenoxarsine, 10,10'-oxydi- CAS REGISTRY NUMBER : 58-36-6 BEILSTEIN REFERENCE NO. : 0055641 LAST UPDATED : 199710 DATA ITEMS CITED : 14 MOLECULAR FORMULA : C24-H16-As2-O3 MOLECULAR WEIGHT : 502.24 WISWESSER LINE NOTATION : T C666 BO I-AS-J IO IO- IT C666 BO I-AS-J IO HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - guinea pig REFERENCE : TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 10,341,1978 ** ACUTE TOXICITY DATA ** TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 40 mg/kg TOXIC EFFECTS : Behavioral - muscle weakness Lungs, Thorax, or Respiration - respiratory stimulation Skin and Appendages - hair REFERENCE : TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 10,341,1978 TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 42 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 14,111,1985 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 24 mg/kg TOXIC EFFECTS : Behavioral - muscle weakness Lungs, Thorax, or Respiration - respiratory stimulation Skin and Appendages - hair REFERENCE : TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 10,341,1978 TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 141 mg/m3/2H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 10,341,1978 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Bird - wild bird species DOSE/DURATION : 24 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 21,315,1972 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 OSHA PEL (Gen Indu):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.02 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1280 No. of Facilities: 1937 (estimated) No. of Industries: 13 No. of Occupations: 19 No. of Employees: 30800 (estimated) No. of Female Employees: 7033 (estimated)

安全

• 危害码 (欧洲): Xi
• 危险品运输编码: 1557
• 包装等级: II
• 危险类别: 6.1(a)

合成路线

2865-70-5 ~% 58-36-6

文献：J. Gen. Chem. USSR (Engl. Transl.), , vol. 42, p. 1963 - 1966,1957 - 1959

55369-40-9 ~% 58-36-6

文献：J. Gen. Chem. USSR (Engl. Transl.), , vol. 44, p. 2506 - 2508,2465 - 2467

101-84-8 ~% 58-36-6

文献：J. Gen. Chem. USSR (Engl. Transl.), , vol. 31, p. 845 - 849,776 - 780

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