16037-50-6

• 常用中文名：氯铬酸钾
• 常用英文名：potassium chlorochromate
• CAS号：16037-50-6
• 分子式：ClCrKO₃
• 分子量：174.54600
• 发布时间：2018-08-10 20:07:28
• 更新时间：2024-01-11 15:40:06

名称

• 中文名: 氯铬酸钾
• 英文名: potassium chlorochromate
• 英文别名: potassium chlorotrioxochromate; EINECS 240-174-7; MFCD00064578

物化性质

• 熔点: 293-295ºC
• 分子式: ClCrKO₃
• 分子量: 174.54600
• 精确质量: 173.85800
• PSA: 57.20000
• LogP: 0.33310
• 计算化学:

  1、疏水参数计算参考值（XlogP）:

  2、氢键供体数量：.0

  3、氢键受体数量：4

  4、可旋转化学键数量:0

  5、互变异构体数量：

  6、拓扑分子极性表面积（TPSA）:51.2

  7、重原子数量：6

  8、表面电荷：0

  9、复杂度：69.4

  10、同位素原子数量：0

  11、确定原子立构中心数量：0

  12、不确定原子立构中心数量：0

  13、确定化学键立构中心数量：0

  14、不确定化学键立构中心数量：0

  15、共价键单元数量：3

• 更多:

  1.性状：未确定

  2.密度（g/mL,25/4℃）：未确定

  3.相对蒸汽密度（g/mL,空气=1）：未确定

  4.熔点（ºC）：293-295

  5.沸点（ºC,常压）：未确定

  6.沸点（ºC,5.2kPa）：未确定

  7.折射率：未确定

  8.闪点（ºC）：未确定

  9.比旋光度（º）：未确定

  10.自燃点或引燃温度（ºC）：未确定

  11.蒸气压（kPa,25ºC）：未确定

  12.饱和蒸气压（kPa,60ºC）：未确定

  13.燃烧热（KJ/mol）：未确定

  14.临界温度（ºC）：未确定

  15.临界压力（KPa）：未确定

  16.油水（辛醇/水）分配系数的对数值：未确定

  17.爆炸上限（%,V/V）：未确定

  18.爆炸下限（%,V/V）：未确定

  19.溶解性：未确定

MSDS

Name: Potassium chlorochromate 98% Material Safety Data Sheet Synonym: CAS: 16037-50-6 Section 1 - Chemical Product MSDS Name:Potassium chlorochromate 98% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 16037-50-6 Potassium chlorochromate 98% 240-174-7 Hazard Symbols: T O N Risk Phrases: 43 8 49 50/53 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW May cause sensitization by skin contact. Contact with combustible material may cause fire. May cause cancer by inhalation. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: May cause cancer in humans. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid immediately. Wash mouth out with water. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Oxidizer. Greatly increases the burning rate of combustible materials. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Do not store near combustible materials. Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 16037-50-6: United Kingdom, WEL - TWA: (listed as chromium (vi) compounds): 0 mg/m3 TWA (as Cr) United Kingdom, WEL - STEL: (listed as chromium (vi) compounds): mg/m3 STEL (as Cr) Belgium - TWA: (listed as chromium (vi) compounds- water soluble) 0.05 mg/m3 VLE (as Cr) France - VME: (listed as chromium (vi) compounds): 0.05 mg/m3 VME Cr) Germany: (listed as chromium (vi) compounds): 0.05 mg/m3 VME (as Japan: (listed as chromium (vi) compounds): 0.05 mg/m3 OEL (as Cr 0.01 mg/m3 OEL (certain compounds, as Cr) Malaysia: (listed as chromium (vi) compounds- water soluble): 0.0 mg/m3 TWA (as Cr) Netherlands: (listed as chromium (vi) compounds- water soluble): mg/m3 STEL Netherlands: (listed as chromium (vi) compounds- water soluble): 0.025 mg/m3 MAC Spain: (listed as chromium (vi) compounds- water soluble): 0.05 m VLA-ED (as Cr) Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder and chunks Color: red-orange - orange Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 293 - 295 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: hydrolysis water Specific Gravity/Density: Molecular Formula: KClCrO3 Molecular Weight: 174.55 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: High temperatures, incompatible materials, dust generation, moisture, combustible materials. Incompatibilities with Other Materials: Alcohols, strong reducing agents. Hazardous Decomposition Products: Chlorine. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 16037-50-6 unlisted. LD50/LC50: Not available. Carcinogenicity: Potassium chlorochromate - California: carcinogen, initial date 2/27/87 (listed as Chromium (VI) NTP: Known carcinogen (listed as Chromium (VI) compounds). IARC: Group 1 carcinogen (listed as Chromium (VI) compounds). Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: OXIDIZING SOLID, N.O.S.* Hazard Class: 5.1 UN Number: 1479 Packing Group: II IMO Shipping Name: OXIDIZING SOLID, N.O.S. Hazard Class: 5.1 UN Number: 1479 Packing Group: II RID/ADR Shipping Name: OXIDIZING SOLID, N.O.S. Hazard Class: 5.1 UN Number: 1479 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T O N Risk Phrases: R 49 May cause cancer by inhalation. R 43 May cause sensitization by skin contact. R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 8 Contact with combustible material may cause fire. Safety Phrases: S 53 Avoid exposure - obtain special instructions before use. S 17 Keep away from combustible material. S 24 Avoid contact with skin. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 60 This material and its container must be disposed of as hazardous waste. S 61 Avoid release to the environment. Refer to special instructions/safety data sheets. WGK (Water Danger/Protection) CAS# 16037-50-6: No information available. Canada CAS# 16037-50-6 is listed on Canada's NDSL List. CAS# 16037-50-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 16037-50-6 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): N-T-O
• 风险声明 (欧洲): 8-50/53-49-43
• 安全声明 (欧洲): 61-60-53-45-37-24-17
• 危险品运输编码: UN3087
• 包装等级: II
• 危险类别: 5.1