24734-68-7

• 常用中文名：3-苯基-1-丙烷硫醇
• 常用英文名：3-phenylpropane-1-thiol
• CAS号：24734-68-7
• 分子式：C₉H₁₂S
• 分子量：152.25700
• 发布时间：2018-08-19 12:45:15
• 更新时间：2024-01-10 09:33:37

名称

• 中文名: 3-苯基-1-丙烷硫醇
• 英文名: 3-phenylpropane-1-thiol
• 英文别名: 3-phenylpropylmercaptan; 3-phenyl-propane-1-thiol; EINECS 246-440-9; 3-phenylpropanethiol; 3-phenylpropylthiol; Benzenepropanethiol; phenylpropyl mercaptan

物化性质

• 密度: 0.996g/cm3
• 沸点: 242.2ºC at 760mmHg
• 分子式: C₉H₁₂S
• 分子量: 152.25700
• 闪点: 90.6ºC
• 精确质量: 152.06600
• PSA: 38.80000
• LogP: 2.54900
• 蒸汽压: 0.0535mmHg at 25°C
• 折射率: 1.545

MSDS

Name: 3-Phenylpropyl mercaptan 97% (gc) Material Safety Data Sheet Synonym: 3-Phenyl-1-propanethio CAS: 24734-68-7 Section 1 - Chemical Product MSDS Name:3-Phenylpropyl mercaptan 97% (gc) Material Safety Data Sheet Synonym:3-Phenyl-1-propanethio Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 24734-68-7 3-Phenylpropyl mercaptan, 99% 99% 246-440-9 Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin.Combustible liquid.The toxicological properties of this material have not been fully investigated.Stench. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Inhalation: Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Keep away from sources of ignition. Store in a tightly closed container. Store in a dry area. Keep refrigerated. (Store below 4C/39F.) Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Limits CAS# 24734-68-7: Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: clear, colorless Odor: Stench pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 109 deg C @ 10.00mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 90 deg C ( 194.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.0100g/cm3 Molecular Formula: C9H12S Molecular Weight: 152.25 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, strong bases. Hazardous Decomposition Products: Carbon monoxide, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 24734-68-7 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-Phenylpropyl mercaptan, 99% - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 24734-68-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 24734-68-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 24734-68-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi:Irritant;
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S37/39
• 海关编码: 2930909090

合成路线

105444-69-7 ~% 24734-68-7

文献：Hamilton, Gregory S.; Wu, Yong-Qian; Limburg, David C.; Wilkinson, Douglas E.; Vaal, Mark J.; Li, Jia-He; Thomas, Christine; Huang, Wei; Sauer, Hansjorg; Ross, Douglas T.; Soni, Raj; Chen, Yi; Guo, Hongshi; Howorth, Pamela; Valentine, Heather; Liang, Shi; Spicer, Dawn; Fuller, Mike; Steiner, Joseph P. Journal of Medicinal Chemistry, 2002 , vol. 45, # 16 p. 3549 - 3557

114764-12-4 ~91% 24734-68-7

文献：Anderson, M.B.; Ranasinghe, M.G.; Palmer, J.T.; Fuchs, P.L. Journal of Organic Chemistry, 1988 , vol. 53, # 13 p. 3125 - 3127

89987-96-2 ~82% 24734-68-7

文献：Anderson, M.B.; Ranasinghe, M.G.; Palmer, J.T.; Fuchs, P.L. Journal of Organic Chemistry, 1988 , vol. 53, # 13 p. 3125 - 3127

30134-13-5 ~99% 24734-68-7

文献：Iimura, Shinya; Manabe, Kei; Kobayashi, Shu Organic Letters, 2003 , vol. 5, # 2 p. 101 - 103

637-59-2 ~% 24734-68-7

文献：Hamilton, Gregory S.; Wu, Yong-Qian; Limburg, David C.; Wilkinson, Douglas E.; Vaal, Mark J.; Li, Jia-He; Thomas, Christine; Huang, Wei; Sauer, Hansjorg; Ross, Douglas T.; Soni, Raj; Chen, Yi; Guo, Hongshi; Howorth, Pamela; Valentine, Heather; Liang, Shi; Spicer, Dawn; Fuller, Mike; Steiner, Joseph P. Journal of Medicinal Chemistry, 2002 , vol. 45, # 16 p. 3549 - 3557

114764-11-3 ~% 24734-68-7

文献：Anderson, M.B.; Ranasinghe, M.G.; Palmer, J.T.; Fuchs, P.L. Journal of Organic Chemistry, 1988 , vol. 53, # 13 p. 3125 - 3127

99168-03-3 ~% 24734-68-7

文献：v. Braun Chemische Berichte, 1912 , vol. 45, p. 1564

上下游产品

上游产品  4
105444-69-7 114764-12-4 89987-96-2 637-59-2
下游产品  7
104-53-0 30134-08-8 104-52-9 87598-28-5
88358-61-6 89987-96-2 99858-12-5

海关

海关编码	2930909090
中文概述	2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%