14099-01-5

• 常用中文名：五羰基氯铼(I)
• 常用英文名：Chloropentacarbonylrhenium(I)
• CAS号：14099-01-5
• 分子式：C₅ClO₅Re
• 分子量：361.71000
• 相关类别： 有机原料 有机金属类化合物 有机铋、钴、镨、钆、镓、铱、铼、钇、铽等
• 发布时间：2018-08-09 16:38:29
• 更新时间：2024-01-06 15:37:03

名称

• 中文名: 五羰基氯铼(I)
• 英文名: Rhenium pentacarbonyl chloride
• 中文别名: 氯化五羰基铼; 五羰基氯化铼(I); 氯代五羰基铼(I)
• 英文别名: MFCD00013296; carbon monoxide,chlororhenium; Chloropentacarbonylrhenium(I); EINECS 237-948-1

物化性质

• 分子式: C₅ClO₅Re
• 分子量: 361.71000
• 精确质量: 361.89900
• 外观性状: crystal | off-white
• 储存条件:

  常温密闭避光，通风干燥

• 稳定性:

  常温常压下稳定

  避免的物料：水分/潮湿 空气 氧化物
• 水溶解性: Insoluble in water.
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：361.899026 Da

  8、标称质量：362 Da

  9、平均质量：361.7105 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:5

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积5

  7.重原子数量:12

  8.表面电荷:0

  9.复杂度:12

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:6

• 更多:

  1. 性状：米色粉末

  2. 密度（g/mL,25/4℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Section 1: Product Identification Chemical Name:Rhenium pentacarbonyl chloride, 98% CAS Registry Number:14099-01-5 Formula:Re(CO)5Cl EINECS Number:237-948-1 Chemical Family:metal carbonyl complexes Synonym:none Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound14099-01-5100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Inhalation Eye Contact:May cause mild irritation to the eyes. Skin Contact:Causes mild irritation to the skin. Inhalation:Irritating to the nose mucous membranes and respiratory tract. Ingestion:No specific information is available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Inhalation could lead to headache and dizziness. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 15 minutes. A victim will need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical Skin Exposure: assistance if irritation persists. Remove victim to fresh air immediately. Keep the victim lying down and warm. Give oxygen as soon as Inhalation: possible. If shock occurs, respond with appropriate first aid. Transport the victim to a hospital. Seek medical attention immediately. Keep the victim calm. Give water to dilute the toxin (only if conscious). Ingestion: Induce vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry chemical or foam If involved in a fire, fire fighters should be equipped with a NIOSH-approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus. Hazardous Combustion andcarbon monoxide, carbon dioxide, and rhenium oxide dust. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small quantities can be mixed with sodium carbonate or vermiculite and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry, well-ventilated area away from heat and direct sunlight. Keep containers tightly sealed. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling chemical substances. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:This product should be handled in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance 29 CFR 1910.134. Ventilation:This product should be handled in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:off-white xtl. Molecular Weight:361.71 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents, halogens and active metals Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, hydrogen chloride, and rhenium oxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available. SECTION 13: Disposal Considerations Disposal:Dispose of this material according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 1、急性毒性：主要的刺激性影响： 在皮肤上面：刺激皮肤和粘膜； 在眼睛上面：刺激的影响；没有已知的敏化影响。 生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

安全

• 危害码 (欧洲): T: Toxic;
• 风险声明 (欧洲): 23/24/25-36/37/38
• 安全声明 (欧洲): 26-28-36/37/39-45
• 危险品运输编码: UN 3288 6.1/PG 3
• WGK德国: 3
• 包装等级: II
• 危险类别: 6.1
• 海关编码: 28369917

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