3107-33-3

• 常用中文名：3-(三氟甲基)苯肼盐酸盐
• 常用英文名：(3-(Trifluoromethyl)phenyl)hydrazine hydrochloride
• CAS号：3107-33-3
• 分子式：C₇H₈ClF₃N₂
• 分子量：212.600
• 相关类别： 化学试剂 有机试剂 肼
• 发布时间：2018-08-03 07:54:19
• 更新时间：2024-01-11 12:17:14

名称

• 中文名: 3-(三氟甲基)苯肼盐酸盐
• 英文名: [3-(trifluoromethyl)phenyl]hydrazine,hydrochloride
• 中文别名: 3-三氟甲基苯肼HC; 3-三氟甲基苯肼盐酸盐; 间三氟甲基苯肼盐酸盐
• 英文别名: ZMR CXFFF &&HCl; (3-(Trifluoromethyl)phenyl)hydrazine hydrochloride; 3-(Trifluoromethyl)phenylhydrazine Hydrochloride; m-trifluoromethylphenylhydrazine hydrochloride; 3-Hydrazinobenzotrifluoride hydrochloride; n'-(3-trifluoromethyl-phenyl)-hydrazinium,chloride; [3-(Trifluoromethyl)phenyl]hydrazinium chloride; [3-(Trifluoromethyl)phenyl]hydrazine hydrochloride (1:1); [3-(trifluoromethyl)phenyl]hydrazine hydrochloride; 3-(trifluoromethyl)phenylhydrazine,hydrochloride salt; 3-(trifluoromethyl)phenylhydrazine hcl; 1-Hydrazino-3-(trifluoromethyl)benzene hydrochloride; Hydrazine, [3-(trifluoromethyl)phenyl]-, hydrochloride (1:1); MFCD00100503

物化性质

• 密度: 1.348
• 沸点: 204.6ºC at 760mmHg
• 分子式: C₇H₈ClF₃N₂
• 分子量: 212.600
• 闪点: 107.2ºC
• 精确质量: 212.032806
• PSA: 38.05000
• LogP: 3.56630
• 折射率: 1.525
• 储存条件:

  密封储存，储存于阴凉、干燥的库房。

• 稳定性:

  避免与不相容材料接触。与强氧化剂反应。

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:3

  3.氢键受体数量:5

  4.可旋转化学键数量:1

  5.互变异构体数量:无

  6.拓扑分子极性表面积38

  7.重原子数量:13

  8.表面电荷:0

  9.复杂度:146

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:2

• 更多:

  1. 性状：灰白色粉末

  2. 密度（g/mL,25℃）：1.348

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,25mmHg）：未确定

  7. 折射率(n20/D)：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（mPa,20ºC）：未确定

  12. 饱和蒸气压（kPa,25ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Name: 3-(Trifluoromethyl)phenylhydrazine hydrochloride Material Safety Data Sheet Synonym: CAS: 3107-33-3 Section 1 - Chemical Product MSDS Name:3-(Trifluoromethyl)phenylhydrazine hydrochloride Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 3107-33-3 3-(Trifluoromethyl)phenylhydrazine hyd unlisted Hazard Symbols: XN Risk Phrases: 20/21/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 3107-33-3: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: off-white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H7F3N2.HCl Molecular Weight: 212.6 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride gas. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 3107-33-3 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-(Trifluoromethyl)phenylhydrazine hydrochloride - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2811 Packing Group: III IMO Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: III RID/ADR Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Safety Phrases: S 36/37 Wear suitable protective clothing and gloves. WGK (Water Danger/Protection) CAS# 3107-33-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 3107-33-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 3107-33-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xn:Harmful;
• 风险声明 (欧洲): R20/21/22
• 安全声明 (欧洲): S36/37
• 海关编码: 2928000090

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110821-29-9 103986-06-7 66000-40-6

海关

海关编码	2928000090
中文概述	2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%