126683-99-6

• 常用中文名：双(1-金刚烷基)膦酰氯
• 常用英文名：Bis(1-adamantyl)phosphinic chloride
• CAS号：126683-99-6
• 分子式：C₂₀H₃₀ClOP
• 分子量：352.878
• 相关类别： 有机原料 有机膦化合物
• 发布时间：2018-08-09 18:30:35
• 更新时间：2024-01-11 20:25:15

名称

• 中文名: 二-1-金刚烷基氯化膦
• 英文名: 1-[1-adamantyl(chloro)phosphoryl]adamantane
• 中文别名: 双(1-金刚烷基)膦酰氯
• 英文别名: Diadamantan-1-ylphosphinic chloride; Di-1-adamantylphosphinsaeurechlorid; Phosphinic chloride, P,P-ditricyclo[3.3.1.1]dec-1-yl-; DI-1-ADAMANTYLPHOSPHINIC CHLORIDE

物化性质

• 密度: 1.2±0.1 g/cm3
• 沸点: 498.0±12.0 °C at 760 mmHg
• 熔点: 214ºC
• 分子式: C₂₀H₃₀ClOP
• 分子量: 352.878
• 闪点: 255.0±19.6 °C
• 精确质量: 352.172272
• PSA: 26.88000
• LogP: 5.01
• 外观性状: crystal | white
• 蒸汽压: 0.0±1.2 mmHg at 25°C
• 折射率: 1.570
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、 摩尔折射率：93.85

  2、 摩尔体积（m³/mol）：286.2

  3、 等张比容（90.2K）：744.8

  4、 表面张力（dyne/cm）：45.8

  5、 极化率（10 ^-24cm ³）：37.20

• 计算化学:

  1.疏水参数计算参考值（XlogP）:5.5

  2.氢键供体数量:0

  3.氢键受体数量:1

  4.可旋转化学键数量:2

  5.互变异构体数量:无

  6.拓扑分子极性表面积17.1

  7.重原子数量:23

  8.表面电荷:0

  9.复杂度:466

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：214

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Section 1: Product Identification Chemical Name:Di-1-adamantylphosphinic chloride, 98% CAS Registry Number:126683-99-6 Formula:(C10H15)2POCl EINECS Number:none Chemical Family:organophosphine ligand Synonym:Di-1-adamantylchlorophosphane Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound126683-99-6100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Inhalation, skin, eyes. Eye Contact:Dust causes moderate to severe irritation of the eyes. Skin Contact:Causes moderate to severe irritation of the skin. May cause redness, itching and pain. Inhalation:Dust is irritating to the nose, mucous membranes and respiratory tract. Ingestion:No specific information is available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry powder or foam. Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus Special Fire Fighting Procedures: and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up. SECTION 7: Handling and Storage Handling and Storage:Store the material in a cool, dry place in a tightly sealed container. Handle under a dry atmosphere. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white xtl. Molecular Weight:352.88 Melting Point:214° Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:not determined Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:moisture sensitive Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents and halogens Decomposition Products:carbon monoxide, carbon dioxide, hydrogen chloride, organic fumes and phosphorus pentoxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to federal, state, and local regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。

安全

• 海关编码: 2903890090

合成路线

281-23-2 ~93% 126683-99-6

文献：No, B. I.; Zotov, Yu. L.; Karev, V. N. J. Gen. Chem. USSR (Engl. Transl.), 1990 , vol. 60, # 8.1 p. 1795 - 1799,1603 - 1606

768-90-1 23906-91-4 ~87% 126683-99-6

文献：Yurchenko, R. I.; Peresypkina, L. P.; Miroshnichenko, V. V.; Yurchenko, A. G. Russian Journal of General Chemistry, 1993 , vol. 63, # 7.1 p. 1072 - 1076 Zhurnal Obshchei Khimii, 1993 , vol. 63, # 7 p. 1534 - 1539

7446-70-0 281-23-2 7719-12-2 ~95% 126683-99-6

文献：Beller, Matthias; Ehrentraut, Andreas; Ehrentraut, Wilhelm Hubert; Ehrentraut, Theresia Elisabeth; Fuhrmann, Christa; Zapf, Alexander Patent: US2004/68131 A1, 2004 ;

768-95-6 23906-91-4 ~87% 126683-99-6

文献：Yurchenko, R. I.; Peresypkina, L. P. J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 10.2 p. 2389 - 2390,1971

57680-77-0 ~44% 126683-99-6

文献：Yurchenko, A. G.; Fedorenko, T. V.; Titova, M. I.; Yurchenko, R. I.; Voitsekhovskaya, O. M. J. Gen. Chem. USSR (Engl. Transl.), 1989 , vol. 59, # 10.1 p. 2212 - 2217,1982 - 1986

上下游产品

上游产品  7
281-23-2 768-90-1 23906-91-4 7446-70-0
7719-12-2 768-95-6 57680-77-0
下游产品  3
131266-79-0 131211-27-3 157282-19-4

海关

海关编码	2903890090
中文概述	2903890090. 其他环烷烃、环烯烃或环萜烯烃的卤化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%