12145-60-7

• 常用中文名：甲代烯丙基氯化镍二聚物
• 常用英文名：METHALLYLNICKEL CHLORIDE DIMER
• CAS号：12145-60-7
• 分子式：C₈H₁₄Cl₂Ni₂
• 分子量：298.49000
• 发布时间：2018-05-26 08:00:00
• 更新时间：2024-01-11 12:04:05

名称

• 中文名: 甲代烯丙基氯化镍二聚物
• 英文名: chloronickel,2-methanidylprop-1-ene
• 英文别名: methallylnickel chloride dimer

物化性质

• 分子式: C₈H₁₄Cl₂Ni₂
• 分子量: 298.49000
• 精确质量: 295.91800
• LogP: 4.43920
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、摩尔折射率：无可用

  2、 摩尔体积（cm³/mol）：无可用

  3、 等张比容（90.2K）：无可用

  4、 表面张力（dyne/cm）：无可用

  5、 极化率：无可用

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：无可用

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Section 1: Product Identification Chemical Name:Methallylnickel chloride dimer CAS Registry Number:12145-60-7 Formula:[C4H7NiCl]2 EINECS Number:none Chemical Family:organometallic complexes Synonym:Chloro(methallyl)nickel (II) dimer Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound12145-60-7100%0.2mg/m3(as Ni)1mg/m3 (as Ni) Section 3: Hazards Identification Irritating to skin, eyes and respiratory tract. Dust may cause headaches, sore throat, shortness of breath and Emergency Overview: lung damage. Ingestion of large amounts may cause convulsions and asphyxia. May cause cancer. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes Eye Contact:Causes mild to moderate irritation to the eyes. May cause redness and pain. Skin Contact:Causes moderate irritation of the skin with redness or rash. Prolonged contact may cause dermatitis. Inhalation:Inhalation causes irritation to the nose, mucous membranes and respiratory tract. Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness and convulsions. Irritating to skin, eyes and respiratory tract. May causes intestinal disorders, convulsions, asphyxia, Acute Health Affects: sensitization dermatitis, allergic asthma and pneumonitis. May cause cancer. Prolonged exposure to nickel and nickel compounds may lead to skin irritation and dermatitis. May cause Chronic Health Affects: cancer. NTP:Yes IARC:Yes OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam. Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus Special Fire Fighting Procedures: and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Keep material in a tightly sealed container. Store cold. Prolonged exposure to moisture will result in Handling and Storage: degradation of the product. Handle and store under an inert atmosphere of nitrogen or argon. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:orange-brown xtl. Molecular Weight:298.49 Melting Point:none Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitve, moisture sensitive (store cold) Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:moisture sensitive (store cold) Incompatibility:oxygen, oxidizing agents and halogens Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, hydrochloric acid and chloride. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:Carcinogen (as Ni) Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to federal, state, and local regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):See category code N495 for reporting. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。

安全

• 风险声明 (欧洲): 20/21/22-42/43-45
• 安全声明 (欧洲): 26-36/37/39
• 危险品运输编码: UN 2811