1005-22-7
1005-22-7结构式
- 常用中文名：环己基膦酰二氯
- 常用英文名：cyclohexylphosphonic dichloride
- CAS号：1005-22-7
- 分子式：C6H11Cl2OP
- 分子量：201.03100
- 发布时间：2018-06-27 18:19:45
- 更新时间：2024-01-09 09:25:48
| 中文名 | 环己基膦酰二氯 |
|---|---|
| 英文名 | cyclohexylphosphonic dichloride |
| 英文别名 |
cyclohexylphosphonic acid dichloride
Cyclohexyl-phosphonsaeure-dichlorid AURORA KA-1369 Cyclohexylphosphorigsaeuredichlorid cyclohexylphosphonyl dichloride cyclohexanephosphonyl chloride |
| 密度 | 1.296 g/mL at 25ºC(lit.) |
|---|---|
| 沸点 | 127-129ºC (15 mmHg) |
| 熔点 | 40-43ºC |
| 分子式 | C6H11Cl2OP |
| 分子量 | 201.03100 |
| 闪点 | 111.5ºC |
| 精确质量 | 199.99200 |
| PSA | 26.88000 |
| LogP | 3.98980 |
| 蒸汽压 | 0.0195mmHg at 25°C |
| 折射率 | n20/D 1.506(lit.) |
| 储存条件 | 50°C以下密封储存 |
| 稳定性 | 常温常压下稳定，避免强氧化剂 空气 水分 强碱 酒精 胺接触 |
| 分子结构 | 1、 摩尔折射率：44.16 2、 摩尔体积（m3/mol）：159.0 3、 等张比容（90.2K）：387.8 4、 表面张力（dyne/cm）：35.3 5、 介电常数：不可用 6、 偶极距（10 -24cm 3）：不可用 7、 极化率：17.50 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:2.8 2.氢键供体数量:0 3.氢键受体数量:1 4.可旋转化学键数量:1 5.互变异构体数量:无 6.拓扑分子极性表面积17.1 7.重原子数量:10 8.表面电荷:0 9.复杂度:148 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：未确定。 2. 密度（g/mL,25℃）：1.296 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：40-43 5. 沸点（ºC,常压）：127-129 6. 沸点（ºC,23mmHg）：未确定 7. 折射率(n 20/D) ：1.506 8. 闪点（ºF）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
Synonym:None Known Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Causes burns.Moisture sensitive. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Chronic exposure may cause effects similar to those of acute exposure. Section 4 - FIRST AID MEASURES Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Wash clothing before reuse. Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Do NOT get water inside containers. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers. Section 7 - HANDLING and STORAGE Handling: Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use and store under nitrogen. Do not allow contact with water. Use only in a chemical fume hood. Discard contaminated shoes. Keep from contact with moist air and steam. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Store protected from moisture. Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1005-22-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 127 - 129 deg C @ 15mmHg Freezing/Melting Point: 40 - 43 deg C Autoignition Temperature: Not available. Flash Point: > 109 deg C (> 228.20 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C6H11Cl2OP Molecular Weight: 200.96 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Moisture sensitive. Conditions to Avoid: Incompatible materials, dust generation, moisture. Incompatibilities with Other Materials: Alcohols, strong bases, strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, oxides of phosphorus, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1005-22-7 unlisted. LD50/LC50: Not available. Carcinogenicity: Cyclohexylphosphonic dichloride - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Ecotoxicity: Fish: Pseudomonas putida: Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 1005-22-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 1005-22-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1005-22-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
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| 危害码 (欧洲) | C: Corrosive; |
|---|---|
| 风险声明 (欧洲) | 34 |
| 安全声明 (欧洲) | 45-36/37/39-26-27 |
| 危险品运输编码 | UN 3261 8/PG 2 |
| 海关编码 | 2931900090 |
|
~92%
1005-22-7 |
| 文献：Rogers, Roland S. Tetrahedron Letters, 1992 , vol. 33, # 49 p. 7473 - 7474 |
|
~79%
1005-22-7 |
| 文献：Morita, Tsuyoshi; Okamoto, Yoshiki; Sakurai, Hiroshi Chemistry Letters, 1980 , p. 435 - 438 |
|
~45%
1005-22-7 |
| 文献：Titov; Zakharov; Krivchun; Ionin Russian Journal of General Chemistry, 2011 , vol. 81, # 3 p. 481 - 487 |
|
~%
1005-22-7 |
| 文献：Journal of the Chemical Society, , p. 3437,3440 |
|
~%
1005-22-7 |
| 文献：Journal of Organic Chemistry, , vol. 31, p. 2076 |
|
~%
1005-22-7 |
| 文献：Chemische Berichte, , vol. 100, p. 639 - 646 |
| 海关编码 | 2931900090 |
|---|---|
| 中文概述 | 2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0% |
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |