866395-16-6

• 常用中文名：三苯基膦金(I)双(三氟甲磺酰基)亚氨酸酯
• 常用英文名：Gold, [1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN](triphenylphosphine)-
• CAS号：866395-16-6
• 分子式：C₂₀H₁₅AuF₆NO₄PS₂
• 分子量：739.39800
• 发布时间：2019-01-15 01:15:15
• 更新时间：2024-01-09 18:25:37

名称

• 中文名: 三苯基膦金(I)双(三氟甲磺酰基)亚胺盐
• 英文名: Triphenylphosphinegold(I) bis(trifluoromethanesulfonyl)imidate
• 中文别名: 三苯基膦(I)二(三氟甲基)亚胺
• 英文别名: Gold, [1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN](triphenylphosphine)-

物化性质

• 分子式: C₂₀H₁₅AuF₆NO₄PS₂
• 分子量: 739.39800
• 精确质量: 738.97500
• PSA: 101.87000
• LogP: 6.05580
• 储存条件: 室温，干燥

MSDS

Section 1: Product Identification Chemical Name:Triphenylphosphinegold(I) bis(trifluoromethanesulfonyl)imidate, min. 98% CAS Registry Number:866395-16-6 Formula:C20H15AuF6NO4PS2 EINECS Number:none Chemical Family:metal-phosphine complex Synonym:[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphino)gold(I) Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound866395-16-6100%2.5mg/m3 (as F)2.5mg/m3 (as F) Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Inhalation, skin, eyes Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Product contains fluorine which, under certain conditions of use, decomposition or metabolism, may generate Chronic Health Affects:fluoride ion causing nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth structure, kidney and liver damage. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry powder or foam If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and vapors of phosphorous pentoxide. Decomposion Products: Unusual Fire or Explosion Hazards: No unususal fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store cold, in a tightly sealed container under an inert atmosphere of nitrogen or argon. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white to off-white powder Molecular Weight:739.40 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive, light sensitive (store cold) Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:strong oxidizing agents Decomposition Products:carbon monoxide, phosphorous pentoxide, sulfur and nitrogen oxides, hydrofluoric acid and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

合成路线

1176664-00-8 ~% 866395-16-6

文献：Weber, Dieter; Tarselli, Michael A.; Gagne, Michel R. Angewandte Chemie, International Edition, 2009 , vol. 48, p. 5733 - 5736 Angewandte Chemie, 2009 , vol. 121, p. 5843 - 5846

1176663-98-1 82113-65-3 ~% 866395-16-6

文献：Weber, Dieter; Tarselli, Michael A.; Gagne, Michel R. Angewandte Chemie, International Edition, 2009 , vol. 48, p. 5733 - 5736 Angewandte Chemie, 2009 , vol. 121, p. 5843 - 5846

1176663-98-1 ~% 866395-16-6

文献：Weber, Dieter; Tarselli, Michael A.; Gagne, Michel R. Angewandte Chemie, International Edition, 2009 , vol. 48, p. 5733 - 5736 Angewandte Chemie, 2009 , vol. 121, p. 5843 - 5846

1176664-00-8 82113-65-3 ~% 866395-16-6

文献：Weber, Dieter; Tarselli, Michael A.; Gagne, Michel R. Angewandte Chemie, International Edition, 2009 , vol. 48, p. 5733 - 5736 Angewandte Chemie, 2009 , vol. 121, p. 5843 - 5846

14243-64-2 189114-61-2 ~% 866395-16-6

文献：Iwai, Tomohiro; Okochi, Hiori; Ito, Hideto; Sawamura, Masaya Angewandte Chemie - International Edition, 2013 , vol. 52, # 15 p. 4239 - 4242 Angew. Chem., 2013 , vol. 125, # 15 p. 4333 - 4336,4

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