122135-83-5

• 常用中文名：2-(三氟甲基磺酰氧)环己-1-烯甲酸乙酯
• 常用英文名：ETHYL2-(TRIFLUOROMETHYLSULFONYLOXY)-1-CYCLOHENXENE-1-CARBOXYLATE
• CAS号：122135-83-5
• 分子式：C₁₀H₁₃F₃O₅S
• 分子量：302.26700
• 发布时间：2019-01-01 23:52:29
• 更新时间：2024-01-09 09:20:28

名称

• 中文名: 2-(三氟甲基 磺酰氧基)-1-环乙烯-1-羧酸乙酯
• 英文名: ethyl 2-(trifluoromethylsulfonyloxy)cyclohexene-1-carboxylate
• 中文别名: 2-(三氟甲基磺酰氧)环己-1-烯甲酸乙酯
• 英文别名: Ethyl 2-(trifluoromethyl sulfonyloxy)-1-cyclohenxene-1-carboxylate; ethyl 2-[[(trifluoromethyl)sulfonyl]oxy]-1-cyclohexene-1-carboxylate; 2-[[(Trifluoromethyl)Sulfonyl]Oxy]-1-Cyclohexene-1-carboxylic Acid Ethyl Ester; 2-ethoxycarbonyl-1-cyclohexenyl trifluoromethanesulfonate; ethyl 2-{[(trifluoromethyl)sulfonyl]oxy}cyclohex-1-ene-1-carboxylate; ethyl 2-(trifluoromethanesulfonyloxy)-1-cyclohexenecarboxylate; (Z)-trifluoromethanesulfonyloxy-cyclohexanecarboxylic acid ethyl ester; ethyl 2-(trifluoromethylsulfonyloxy)cyclohex-1-enecarboxylate; 2-trifluoromethanesulfonyloxy-cyclohex-1-enecarboxylic acid ethyl ester

物化性质

• 密度: 1.41g/cm3
• 沸点: 326.9ºC at 760mmHg
• 分子式: C₁₀H₁₃F₃O₅S
• 分子量: 302.26700
• 闪点: 151.5ºC
• 精确质量: 302.04400
• PSA: 78.05000
• LogP: 3.32460
• 蒸汽压: 0.00021mmHg at 25°C
• 折射率: 1.46
• 储存条件: 2-8℃

安全

• 海关编码: 2916209090

合成路线

358-23-6 1655-07-8 ~98% 122135-83-5

文献：Gagnier, Steve V.; Larock, Richard C. Journal of the American Chemical Society, 2003 , vol. 125, # 16 p. 4804 - 4807

145100-51-2 1655-07-8 ~88% 122135-83-5

文献：Raghavan, Subharekha; Tria, G. Scott; Shen, Hong C.; Ding, Fa-Xiang; Taggart, Andrew K.; Ren, Ning; Wilsie, Larrisa C.; Krsmanovic, Mihajlo L.; Holt, Tom G.; Wolff, Michael S.; Waters, M. Gerard; Hammond, Milton L.; Tata, James R.; Colletti, Steven L. Bioorganic and Medicinal Chemistry Letters, 2008 , vol. 18, # 11 p. 3163 - 3167

456-64-4 1655-07-8 ~% 122135-83-5

文献：Scheiper, Bodo; Bonnekessel, Melanie; Krause, Helga; Fuerstner, Alois Journal of Organic Chemistry, 2004 , vol. 69, # 11 p. 3943 - 3949

358-23-6 4840-68-0 ~% 122135-83-5

文献：Wu, Xiaojin; Lu, Yunpeng; Hirao, Hajime; Zhou, Jianrong Chemistry - A European Journal, 2013 , vol. 19, # 19 p. 6014 - 6020

37595-74-7 1655-07-8 ~92% 122135-83-5

文献：Selles; Mueller Organic Letters, 2004 , vol. 6, # 2 p. 277 - 279

1655-07-8 ~% 122135-83-5

文献：Harper, Steven; Summa, Vincenzo; Liverton, Nigel J.; McCauley, John A.; Butcher, John W.; Di Filippo, Marcello; Di Francesco, Maria Emilia; Ferrara, Marco; Romano, Joseph J.; Rudd, Michael T. Patent: US2010/183551 A1, 2010 ;

海关

海关编码	2916209090
中文概述	2916209090 其他（环烷、环烯、环萜烯）一元羧酸（包括酸酐、酰卤化物，过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装
监管条件	A.入境货物通关单 B.出境货物通关单
检验检疫	R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验
Summary	2916209090 other cyclanic, cyclenic or cyclotherpenic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%