中文名 | 3-(甲基硫代)异氰酸苯酯 |
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英文名 | 1-isocyanato-3-methylsulfanylbenzene |
中文别名 |
3-(甲基硫代)苯基异氰酸酯
3-(甲硫基)苯基异氰酸酯 3-(甲硫基)苯基异氰酸酯 |
英文别名 |
3-thiomethyl-phenylisocyanate
Benzene, 1-isocyanato-3-(methylthio)- 3-(Methylthio)phenyl isocyanate 3-(methylthio)phenylisocyanate MFCD00013863 1-isocyanato-3-(methylthio)benzene 3-Methylthiophenyl isocyanate 1-Isocyanato-3-(methylsulfanyl)benzene 3-Isocyanatophenyl methyl sulfide 3-methylsulfanyl-phenyl isocyanate 3-methylthiobenzenisocyanate |
密度 | 1.1±0.1 g/cm3 |
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沸点 | 253.2±23.0 °C at 760 mmHg |
分子式 | C8H7NOS |
分子量 | 165.212 |
闪点 | 106.9±22.6 °C |
精确质量 | 165.024841 |
PSA | 54.73000 |
LogP | 3.15 |
外观性状 | 浅黄色液体 |
蒸汽压 | 0.0±0.5 mmHg at 25°C |
折射率 | 1.566 |
储存条件 | 冷藏保存 |
稳定性 | 如果遵照规格使用和储存则不会分解,未有已知危险反应 避免氧化物 |
计算化学 | 1.疏水参数计算参考值(XlogP):3.2 2.氢键供体数量:0 3.氢键受体数量:3 4.可旋转化学键数量:2 5.互变异构体数量:无 6.拓扑分子极性表面积54.7 7.重原子数量:11 8.表面电荷:0 9.复杂度:166 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
更多 | 1. 性状:有刺激性的灰黄色液体 2. 密度(g/mL,20℃):1.199 3. 相对蒸汽密度(g/mL,空气=1):未确定 4. 熔点(ºC):未确定 5. 沸点(ºC,常压):未确定 6. 沸点(ºC, 0.67KPa):129-130 7. 折射率:n20/D 1.603 8. 闪点(ºC):>110 9. 比旋光度(º):未确定 10. 自燃点或引燃温度(ºC):113 11. 蒸气压(Pa,23ºC):未确定 12. 饱和蒸气压(KPa,20ºC):未确定 13. 燃烧热(KJ/mol):未确定 14. 临界温度(ºC):未确定 15. 临界压力(KPa):未确定 16. 油水(辛醇/水)分配系数的对数值:未确定 17. 爆炸上限(%,V/V):未确定 18. 爆炸下限(%,V/V):未确定 19. 溶解性:可溶于水 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin.Air sensitive. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 28479-19-8: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 129 - 130 deg C @5mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: > 110 deg C (> 230.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.199 Molecular Formula: C8H7NOS Molecular Weight: 165 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to air. Incompatibilities with Other Materials: Oxidizing agents, reducing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide, acrid smoke and fumes. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 28479-19-8 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-(Methylthio)phenyl isocyanate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: ISOCYANATE SOLUTION, TOXIC, N.O.S.* Hazard Class: 6.1 UN Number: 2206 Packing Group: III IMO Shipping Name: ISOCYANATE SOLUTION, TOXIC, N.O.S. Hazard Class: 6.1 UN Number: 2206 Packing Group: III RID/ADR Shipping Name: ISOCYANATE SOLUTION, TOXIC, N.O.S. Hazard Class: 6.1 UN Number: 2206 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 28479-19-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 28479-19-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 28479-19-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
生态学数据: 通常对水是稍微有危害的,若无政府许可,勿将材料排入周围环境。
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危害码 (欧洲) | Xn:Harmful; |
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风险声明 (欧洲) | R20/22;R36/37/38;R42 |
安全声明 (欧洲) | S23-S26-S36 |
危险品运输编码 | UN 2922 8/PG 2 |
WGK德国 | 3 |
包装等级 | III |
危险类别 | 6.1 |
海关编码 | 2930909090 |
上游产品 0 | |
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下游产品 1 | |
海关编码 | 2930909090 |
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中文概述 | 2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0% |
申报要素 | 品名, 成分含量, 用途 |
Summary | 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |