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3855-87-6生产厂家

3855-87-6价格

3855-87-6

3855-87-6结构式
3855-87-6结构式

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中文名 6,8-二溴香豆素-3-羧酸
英文名 6,8-Dibromo-2-oxo-2H-chromene-3-carboxylic acid
中文别名 6,8-二溴-2-氧代-2H-色烯-3-羧酸
6,8-二溴甲氧基香豆素-3-甲酸
英文别名 6,8-Dibromo-2-oxo-2h-chromene-3-carboxylic acid,95+
6,8-Dibrom-2-oxo-2H-chromen-3-carbonsaeure
MFCD00173735
IFLAB-BB F0777-0666
6,8-DIBROMOCOUMARIN-3-CARBOXYLIC ACID
6,8-diBrCcaH
密度 2.178g/cm3
沸点 483.2ºC at 760mmHg
熔点 221ºC
分子式 C10H4Br2O4
分子量 347.94400
闪点 246ºC
精确质量 345.84800
PSA 67.51000
LogP 3.01620
外观性状 固体
储存条件

常温,避光,通风干燥处,密封保存

稳定性

常温常压下稳定

Name: 6 8-Dibromo-2-oxo-2h-chromene-3-carboxylic acid 95+ Material Safety Data Sheet
Synonym: 6,8-Dibromocoumarin-3-carboxylic aci
CAS: 3855-87-6
Section 1 - Chemical Product MSDS Name:6 8-Dibromo-2-oxo-2h-chromene-3-carboxylic acid 95+ Material Safety Data Sheet
Synonym:6,8-Dibromocoumarin-3-carboxylic aci

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
3855-87-6 6,8-Dibromo-2-oxo-2H-chromene-3-carbox 95+% unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 3855-87-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 221 - 224 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H4Br2O4
Molecular Weight: 348

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide, bromine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 3855-87-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
6,8-Dibromo-2-oxo-2H-chromene-3-carboxylic acid - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 3855-87-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 3855-87-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3855-87-6 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

生态学数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境

危害码 (欧洲) Xn:Harmful;
风险声明 (欧洲) R20/21/22;R36/37/38
安全声明 (欧洲) S26-S36/37/39
海关编码 2932209090

~89%

3855-87-6结构式

3855-87-6

文献:Bonsignore, Leonardo; Cottiglia, Filippo; Maccioni, Anna M.; Secci, Daniela; Lavagna, Silvio M. Journal of Heterocyclic Chemistry, 1995 , vol. 32, # 2 p. 573 - 578

~92%

3855-87-6结构式

3855-87-6

文献:Undale, Kedar A.; Gaikwad, Dipak S.; Shaikh, Tarannum S.; Desai, Uday V.; Pore, Dattaprasad M. Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2012 , vol. 51, # 7 p. 1039 - 1042

~%

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3855-87-6

文献:Watson, Brett T.; Christiansen, Gerda E. Tetrahedron Letters, 1998 , vol. 39, # 33 p. 6087 - 6090

~%

3855-87-6结构式

3855-87-6

文献:Endo Prod. Inc. Patent: US2683720 , 1949 ;

~%

3855-87-6结构式

3855-87-6

文献:Pandya; Pandya Proceedings - Indian Academy of Sciences, Section A, 1943 , # 18 p. 164,166
海关编码 2932209090
中文概述 2932209090. 其他内酯. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素 品名, 成分含量, 用途
Summary 2932209090. other lactones. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%