14221-00-2

• 常用中文名：四(亚磷酸三苯酯)镍(0)
• 常用英文名：Tetrakis(triphenylphosphite)nickel(0)
• CAS号：14221-00-2
• 分子式：C₇₂H₆₀NiO₁₂P₄
• 分子量：1299.83000
• 相关类别： 有机原料 有机金属类化合物 有机镍
• 发布时间：2018-02-19 08:00:00
• 更新时间：2024-01-03 21:28:18

名称

• 中文名: 四(亚磷酸三苯酯)镍
• 英文名: nickel,triphenyl phosphite
• 中文别名: 四(三苯基亚磷酸盐)镍; 四-(三磷酸三苯酯)镍(0)
• 英文别名: MFCD00010007; Nickel tetrakis(triphenoxyphosphine) Tetrakis(triphenoxyphosphine)nickel [(PhO)3P]4Ni

物化性质

• 熔点: 145ºC (dec.)(lit.)
• 分子式: C₇₂H₆₀NiO₁₂P₄
• 分子量: 1299.83000
• 精确质量: 1298.24000
• PSA: 165.12000
• LogP: 21.80120
• 储存条件: Refrigerator (+4°C)
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：1298.23887 Da

  8、标称质量：1298 Da

  9、平均质量：1299.828 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:12

  4.可旋转化学键数量:24

  5.互变异构体数量:无

  6.拓扑分子极性表面积111

  7.重原子数量:89

  8.表面电荷:0

  9.复杂度:247

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:5

• 更多:

  1. 性状：未确定

  2. 密度（g/mL,25/4℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：145

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：不适用的

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Name: Tetrakis(triphenyl phosphite)nickel(0) Material Safety Data Sheet Synonym: CAS: 14221-00-2 Section 1 - Chemical Product MSDS Name:Tetrakis(triphenyl phosphite)nickel(0) Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 14221-00-2 Tetrakis(triphenyl phosphite)nickel(0) unlisted Hazard Symbols: XN Risk Phrases: 36/37/38 40 42/43 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. May cause sensitization by inhalation and skin contact.Air sensitive. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. May cause sensitization by skin contact. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Possible risk of irreversible effects. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a tightly closed container. Keep refrigerated. (Store below 4C/39F.) Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 14221-00-2: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: tan Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 145 deg C (dec) Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C72H64NiO12P4 Molecular Weight: 1303.026 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to air. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of phosphorus, carbon dioxide, nickel oxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 14221-00-2 unlisted. LD50/LC50: Not available. Carcinogenicity: Tetrakis(triphenyl phosphite)nickel(0) - California: carcinogen, initial date 5/7/04 (listed as Nickel compound NTP: Known carcinogen (listed as Nickel compounds). IARC: Group 1 carcinogen (listed as Nickel compounds). Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. R 40 Limited evidence of a carcinogenic effect. R 42/43 May cause sensitization by inhalation and skin contact. Safety Phrases: S 22 Do not breathe dust. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 14221-00-2: No information available. Canada CAS# 14221-00-2 is listed on Canada's NDSL List. CAS# 14221-00-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 14221-00-2 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xn: Harmful;
• 风险声明 (欧洲): R36/37/38;R40;R43
• 安全声明 (欧洲): S26-S36/37
• WGK德国: 3

合成路线

101-02-0 3264-82-2 ~% 14221-00-2

文献：Bulletin of the Chemical Society of Japan, , vol. 55, # 1 p. 325 - 326

101-02-0 14552-96-6 ~% 14221-00-2

文献：BE610876 , ; C. A., , vol. 57, p. 16662

101-02-0 14653-44-2 ~% 14221-00-2

文献：BE610876 , ; C. A., , vol. 57, p. 16662

101-02-0 1271-28-9 ~% 14221-00-2

文献：US3152158 , ; C. A., , vol. 61, p. 14230

101-02-0 17112-33-3 ~0% 14221-00-2

文献：Chemische Berichte, , vol. 98, p. 3070 - 3080

101-02-0 7440-02-0 ~18% 14221-00-2

文献：Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 8 p. 1401 - 1407

101-02-0 130126-40-8 ~% 14221-00-2

文献：Journal of Organometallic Chemistry, , vol. 389, # 3 p. 399 - 408

101-02-0 13463-39-3 ~% 14221-00-2

文献：Bulletin de la Societe Chimique de France, , p. 741 - 742 Ni: Org.Verb.1, 1.1.5.4.1.3.6, page 230 - 251

101-02-0 77450-60-3 ~% 14221-00-2 86901-64-6

文献：Organometallics, , vol. 2, p. 1391 - 1396

上下游产品

上游产品  7
101-02-0 3264-82-2 14653-44-2 77450-60-3
1271-28-9 7440-02-0 13463-39-3
下游产品  0