20634-12-2

• 常用中文名：四氨合硝酸铂
• 常用英文名：Platinum(2+) nitrate ammoniate (1:2:4)
• CAS号：20634-12-2
• 分子式：H₁₂N₆O₆Pt
• 分子量：387.216
• 相关类别： 有机原料 有机金属类化合物 有机铪、汞、银、铂等
• 发布时间：2018-08-10 17:13:26
• 更新时间：2024-01-02 16:06:02
• 下载msds

名称

• 中文名: 四氨合硝酸铂
• 英文名: azane,platinum(2+),dinitrate
• 中文别名: 硝酸四氨合铂(II)
• 英文别名: MFCD00011624; Tetraammineplatinum(II) nitrate; Platinum(2+) nitrate ammoniate (1:2:4); EINECS 243-929-9; Tetraammineplatinum dinitrate

物化性质

• 沸点: 83ºC at 760 mmHg
• 熔点: 262 °C (dec.)(lit.)
• 分子式: H₁₂N₆O₆Pt
• 分子量: 387.216
• 精确质量: 387.046631
• PSA: 150.72000
• LogP: 1.86130
• 外观性状: 白色至淡黄色结晶粉末或晶体
• 储存条件:

  保持贮藏器密封

  放入紧密的贮藏器内，储存在阴凉，干燥的地方

• 稳定性:

  如果遵照规格使用和储存则不会分解

  避免接触还原剂，易氧化材料，有机材料

  水溶液与碱金属，碱土金属和许多有机无机的活性化学药品是不相溶的

  金属粉末

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:4

  3.氢键受体数量:10

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积130

  7.重原子数量:13

  8.表面电荷:0

  9.复杂度:18.8

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:7

• 更多:

  1.性状：无色液体

  2.密度（g/mL,25/4℃）：未确定

  3.相对蒸汽密度（g/mL,空气=1）：未确定

  4.熔点（ºC）：262

  5.沸点（ºC,常压）：未确定

  6.沸点（ºC,5.2kPa）：未确定

  7.折射率：未确定

  8.闪点（ºC）：未确定

  9.比旋光度（º）：未确定

  10.自燃点或引燃温度（ºC）：未确定

  11.蒸气压（kPa,25ºC）：未确定

  12.饱和蒸气压（kPa,60ºC）：未确定

  13.燃烧热（KJ/mol）：未确定

  14.临界温度（ºC）：未确定

  15.临界压力（KPa）：未确定

  16.油水（辛醇/水）分配系数的对数值：未确定

  17.爆炸上限（%,V/V）：未确定

  18.爆炸下限（%,V/V）：未确定

  19.溶解性：未确定

MSDS

Name: Tetraammineplatinum(II) nitrate Material Safety Data Sheet Synonym: CAS: 20634-12-2 Section 1 - Chemical Product MSDS Name:Tetraammineplatinum(II) nitrate Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 20634-12-2 Tetraammineplatinum(II) nitrate 243-929-9 Hazard Symbols: XI O Risk Phrases: 36/37/38 43 5 8 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. Heating may cause an explosion. Contact with combustible material may cause fire.Hygroscopic (absorbs moisture from the air). Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. May cause sensitization by skin contact. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Do not store near combustible materials. Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 20634-12-2: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 262 deg C (dec.) Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Soluble. Specific Gravity/Density: Molecular Formula: H12N6O6Pt Molecular Weight: 387.22 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, excess heat, combustible materials, exposure to moist air or water. Incompatibilities with Other Materials: Reducing agents, phosphorus, sulfur, organic matter. Hazardous Decomposition Products: Nitrogen oxides, ammonia. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 20634-12-2 unlisted. LD50/LC50: Not available. Carcinogenicity: Tetraammineplatinum(II) nitrate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: NITRATES, INORGANIC, N.O.S. Hazard Class: 5.1 UN Number: 1477 Packing Group: III IMO Shipping Name: NITRATES, INORGANIC, N.O.S. Hazard Class: 5.1 UN Number: 1477 Packing Group: III RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI O Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. R 43 May cause sensitization by skin contact. R 5 Heating may cause an explosion. R 8 Contact with combustible material may cause fire. Safety Phrases: S 17 Keep away from combustible material. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 20634-12-2: 2 Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 20634-12-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 20634-12-2 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 对水是稍微危害的，若无政府许可，勿将材料排入周围环境。

安全

• 符号: GHS03, GHS07
• 信号词: Danger
• 危害声明: H272-H315-H317-H319-H335
• 警示性声明: P220-P261-P280-P305 + P351 + P338
• 个人防护装备: dust mask type N95 (US);Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
• 危害码 (欧洲): O:Oxidizingagent;Xi:Irritant;
• 风险声明 (欧洲): R5;R8;R36/37/38;R43
• 安全声明 (欧洲): S15-S26-S27-S36/37/39
• 危险品运输编码: UN 1479 5.1/PG 2
• WGK德国: 3
• 包装等级: III
• 危险类别: 5.1