10025-97-5

• 常用中文名：四氯化铱
• 常用英文名：iridium(+3) cation tetrachloride
• CAS号：10025-97-5
• 分子式：Cl₄Ir----
• 分子量：334.030
• 相关类别： 无机化工 无机盐 金属卤化物及卤酸盐 金属氯化物及盐
• 发布时间：2018-09-20 12:24:44
• 更新时间：2024-01-02 13:17:45

名称

• 中文名: 四氯化铱(IV) 水合物
• 英文名: Iridium(IV) Chloride, Premion
• 中文别名: 四氯化铱
• 英文别名: MFCD00016155; Iridium chloride hydrate; EINECS 233-048-8; Iridium chloride(IV) hydrate; tetrachloroiridium; Iridium(IV) chloride

物化性质

• 分子式: Cl₄Ir----
• 分子量: 334.030
• 精确质量: 332.838867
• 外观性状: 玻璃非晶形的粉末
• 储存条件: 室温
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：332.838311 Da

  8、标称质量：333 Da

  9、平均质量：334.029 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:0

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:5

  8.表面电荷:0

  9.复杂度:19.1

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：深棕色晶体。

  2. 密度（g/mL,25℃）：2.18

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）： 100

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,20ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：溶于水

MSDS

Section 1: Product Identification Chemical Name:Iridium (IV) chloride hydrate CAS Registry Number:10025-97-5 Formula:IrCl4.XH2O EINECS Number:none Chemical Family:metal halide Synonym:Iridium tetrachloride Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound10025-97-5100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Harmful if swallowed. Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust. Eye Contact:Causes mild irritation to the eyes. Skin Contact:Causes slight irritation of the skin. Inhalation:Inhalation of dust leads to irritation of the respiratory tract. Ingestion:Harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. harmful if swallowed. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:none required If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andnone Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable Spill and Leak Procedures: inert material and swept up. SECTION 7: Handling and Storage Handling and Storage:Store solid in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:If possible, handle the material in an efficient fume hood. If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators Respirator: requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:black pwdr. Molecular Weight:334.03 Melting Point:dec. Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:very soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:active metals Decomposition Products:none SECTION 11: Toxicological Information RTECS Data:Oral (rat); LD50: 1560 mg/kg. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 1、急性毒性：大鼠经口LD50：1560 mg/kg； CHEMICAL IDENTIFICATION RTECS NUMBER : NO3610000 CHEMICAL NAME : Iridium(IV) chloride CAS REGISTRY NUMBER : 10025-97-5 LAST UPDATED : 199701 DATA ITEMS CITED : 2 MOLECULAR FORMULA : Cl4-Ir MOLECULAR WEIGHT : 334.00 WISWESSER LINE NOTATION : .IR..G4 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1560 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 21(7),55,1977

安全

• 危害码 (欧洲): Xi
• 风险声明 (欧洲): R34
• 安全声明 (欧洲): 26-36/37/39:-
• 危险品运输编码: UN 3260

合成路线

92561-82-5 ~% 10025-97-5

文献：Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan), , vol. 63, p. 1938 - 1943

上下游产品

上游产品  0
下游产品  1
10025-83-9