290347-66-9

• 常用中文名：(-)-1,1-双((2S,4S)-2,4-二乙基膦)二茂铁
• 常用英文名：(-)-1,1'-bis((2s,4s)-2,4-diethylphosphotano)ferrocene
• CAS号：290347-66-9
• 分子式：C₂₄H₃₆FeP₂
• 分子量：442.33500
• 发布时间：2018-12-05 18:01:17
• 更新时间：2024-01-15 22:50:53

名称

• 中文名: (-)-1,1-双((2S,4S)-2,4-二乙基膦)二茂铁
• 英文名: (-)-1,1'-bis((2s,4s)-2,4-diethylphosphotano)ferrocene
• 英文别名: Et-Ferrotane; Carbonotrithioic acid,dimethyl ester; R,R-Et-FerroTANE; Dimethyl trithiocarbonate; CARBONIC ACID,TRITHIO-,DIMETHYL ESTER; S,S-dimethyl trithiocarbonate; Trithiocarbonic acid dimethyl ester; dimethyl carbonotrithioate

物化性质

• 熔点: 76ºC
• 分子式: C₂₄H₃₆FeP₂
• 分子量: 442.33500
• 精确质量: 442.16400
• PSA: 27.18000
• LogP: 7.00870
• 更多:

  1. 性状：未确定

  2. 密度（g/mL）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：76

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC0.8mmHg）：未确定

  7. 折射率：未确定

  8. 闪点（ºF）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Section 1: Product Identification Chemical Name:(-)-1,1'-Bis((2S,4S)-2,4-diethylphosphotano)ferrocene, min. 95% (S,S)-Et-FerroTANE® CAS Registry Number:290347-66-9 Formula:[C5H4(C7H14P)]2Fe EINECS Number:none Chemical Family:organometallic complexes Synonym:none Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound290347-66-9100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and mucous membranes. Primary Routes of Exposure:Ingestion, skin, inhalation, eyes Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information available on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry area away from heat and direct sunlight. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:yellow-orange pwdr. Molecular Weight:442.35 Melting Point:76° Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:no data Solubility in Water:no data SECTION 10: Stability and Reactivity Stability:air-sensitive solid Hazardous Polymerization:none Conditions to Avoid:none Incompatibility:strong oxidizing agents Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, phosphorus oxides, and iron oxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Not reportable under SARA Title 313 Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 风险声明 (欧洲): 36/37/38
• 安全声明 (欧洲): 26-36/37/39