460092-03-9

• 常用中文名：三己基(十四烷基)膦双(三氟甲磺酰基)酰胺
• 常用英文名：trihexyl(tetradecyl)phosphonium bis(trifluoromethylsulfonyl)imide
• CAS号：460092-03-9
• 分子式：C₃₄H₆₈F₆NO₄PS₂
• 分子量：764.00200
• 相关类别： 化学试剂 有机试剂 离子液体
• 发布时间：2018-12-28 18:04:30
• 更新时间：2024-01-02 16:29:20
• Trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)amide [P6,6,6,14][Ntf2] is an ionic liquid generally used in biosensorselectrodeposition,and synthetic chemistry applications.

名称

• 中文名: 三己基(四癸基)膦 双(三氟甲基磺酰)氨
• 英文名: bis(trifluoromethylsulfonyl)azanide,trihexyl(tetradecyl)phosphanium
• 中文别名: 三己基十四烷基膦双(三氟甲基磺酰基)酰胺
• 英文别名: tetradecyltrihexylphosphonium NTf2; Tetradecyltrihexylphosphonium bis(trifluoromethylsulfonyl)amide; [PR4][Tf2N]; MFCD04117695; Trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)amide; [P6,6,6,14][NTf2]; [TDTHP][NTf2]; [THTDP][NTf2]

物化性质

• 密度: 1.07 g/mL at 20ºC(lit.)
• 分子式: C₃₄H₆₈F₆NO₄PS₂
• 分子量: 764.00200
• 闪点: 52ºC
• 精确质量: 763.42300
• PSA: 98.63000
• LogP: 15.66690
• 外观性状: liquid | colorless
• 储存条件:

  密封于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、摩尔折射率：无可用

  2、 摩尔体积（cm³/mol）：无可用

  3、 等张比容（90.2K）：无可用

  4、 表面张力（dyne/cm）：无可用

  5、 极化率：无可用

• 计算化学:

  1、 疏水参数计算参考值（XlogP）：无可用

  2、 氢键供体数量：0

  3、 氢键受体数量：11

  4、 可旋转化学键数量：30

  5、 拓扑分子极性表面积（TPSA）：69.3

  6、 重原子数量：48

  7、 表面电荷：0

  8、 复杂度：693

  9、 同位素原子数量：0

  10、 确定原子立构中心数量：0

  11、 不确定原子立构中心数量：0

  12、 确定化学键立构中心数量：0

  13、 不确定化学键立构中心数量：0

  14、 共价键单元数量：2

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：1.07

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：无可用

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：52

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Section 1: Product Identification Chemical Name:Trihexyl(tetradecyl)phosphonium bis(trifluoromethanesulfonyl)amide, min. 97% CYPHOS IL 109 CAS Registry Number:460092-03-9 Formula:[(C6H13)3(C14H29)P]+[(CF3SO2)N]- EINECS Number:none Chemical Family:organophosphine compound Synonym:CYPHOSIL 109 Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound460092-03-9100%2.5mg(F)/m32.5mg(F)/m3 Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, skin Eye Contact:Causes mild to moderate irritation to the eyes. Skin Contact:Causes mild to moderate irritation of the skin. Inhalation:As a liquid aerosol, irritating to the nose, mucous membranes and respiratory tract. Ingestion:No specific information is available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed. Product contains fluorine which, under certain conditions of use, decomposition or metabolism, may generate Chronic Health Affects:fluoride ion causing nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth structure and kidney and liver damage. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam. Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus Special Fire Fighting Procedures: and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Keep container tightly closed. Store in a cool, dry place. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:colorless liq. Molecular Weight:764 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:strong oxidizing agents Decomposition Products:carbon monoxide, phosphorous pentoxide, sulfur and nitrogen oxides, hydrofluoric acid and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to federal, state, and local regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。

安全

• 危害码 (欧洲): C
• 风险声明 (欧洲): R10;R22;R34
• 安全声明 (欧洲): S26;S45;S36/S37/S39
• 危险品运输编码: UN 2920 8/PG 2
• WGK德国: 3