32083-31-1
32083-31-1结构式
- 常用中文名：3-氨基-2-[(4-氯苯基)磺酰基]丙烯腈
- 常用英文名：3-AMINO-2-[(4-CHLOROPHENYL)SULFONYL]ACRYLONITRILE
- CAS号：32083-31-1
- 分子式：C9H7ClN2O2S
- 分子量：242.68200
- 发布时间：2018-12-18 03:06:26
- 更新时间：2024-01-10 18:22:03
| 中文名 | 3-氨基-2-[(4-氯苯基)磺酰基]丙烯腈 |
|---|---|
| 英文名 | 3-amino-2-(4-chlorophenyl)sulfonylprop-2-enenitrile |
| 英文别名 |
2-Propenenitrile,3-amino-2-[(4-chlorophenyl)sulfonyl]
3-amino-2-[(4-chlorophenyl)sulfonyl]acrylonitrile Acrylonitrile,3-amino-2-[(p-chlorophenyl)sulfonyl]-(8CI) |
| 密度 | 1.456g/cm3 |
|---|---|
| 沸点 | 513.8ºC at 760mmHg |
| 熔点 | 213ºC |
| 分子式 | C9H7ClN2O2S |
| 分子量 | 242.68200 |
| 闪点 | 264.6ºC |
| 精确质量 | 241.99200 |
| PSA | 92.33000 |
| LogP | 3.21848 |
| 折射率 | 1.606 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 32083-31-1: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 91 - 93 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C9H7ClN2O2S Molecular Weight: 242.68 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, chlorine, hydrogen cyanide, nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 32083-31-1 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-Amino-2-[(4-chlorophenyl)sulfonyl]acrylonitrile - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: NITRILES, SOLID, TOXIC, N.O.S.* Hazard Class: 6.1 UN Number: 3276 Packing Group: III IMO Shipping Name: NITRILES, TOXIC, N.O.S. Hazard Class: 6.1 UN Number: 3276 Packing Group: III RID/ADR Shipping Name: NITRILES, TOXIC, N.O.S. Hazard Class: 6.1 UN Number: 3276 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 32083-31-1: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 32083-31-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 32083-31-1 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xn:Harmful; |
|---|---|
| 风险声明 (欧洲) | R20/21/22;R36/37/38 |
| 安全声明 (欧洲) | S26-S36/37/39 |
| 海关编码 | 2926909090 |
|
~85%
32083-31-1 |
| 文献：Lazukina, L. A.; Mushkalo, I. L.; Neplyuev, V. M.; Kukhar', V. P. Journal of Organic Chemistry USSR (English Translation), 1983 , p. 2114 - 2117 Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 11 p. 2417 - 2420 |
|
~%
32083-31-1 |
| 文献：Journal of Heterocyclic Chemistry, , vol. 8, p. 975 - 982 |
|
~%
32083-31-1 |
| 文献：Journal of Organic Chemistry USSR (English Translation), , vol. 14, p. 1811 - 1816 Zhurnal Organicheskoi Khimii, , vol. 14, # 9 p. 1953 - 1958 |
| 上游产品 3 | |
|---|---|
| 下游产品 0 | |
| 海关编码 | 2926909090 |
|---|---|
| 中文概述 | 2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |