29949-75-5

• 常用中文名：二烯丙基苯磷化氢
• 常用英文名：diallylphenylphosphine
• CAS号：29949-75-5
• 分子式：C₁₂H₁₅P
• 分子量：190.22100
• 相关类别： 有机原料 有机膦化合物
• 发布时间：2018-02-21 08:00:00
• 更新时间：2024-01-03 07:58:55

名称

• 中文名: 二烯丙基苯磷化氢
• 英文名: phenyl-bis(prop-2-enyl)phosphane
• 中文别名: 二烯丙基苯基膦
• 英文别名: diallyl-phenyl-phosphine; bis-allylnphenylphosphine; MFCD00014955; diallylphenyl phosphane; phenyldiallylphosphin

物化性质

• 密度: 0.969 g/mL at 25ºC(lit.)
• 沸点: 127ºC14 mm Hg(lit.)
• 分子式: C₁₂H₁₅P
• 分子量: 190.22100
• 闪点: 112.4ºC
• 精确质量: 190.09100
• PSA: 13.59000
• LogP: 3.16580
• 蒸汽压: 0.0246mmHg at 25°C
• 折射率: n20/D 1.568(lit.)
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、摩尔折射率：无可用

  2、 摩尔体积（cm³/mol）：无可用

  3、 等张比容（90.2K）：无可用

  4、 表面张力（dyne/cm）：无可用

  5、 极化率：无可用

• 计算化学:

  1.疏水参数计算参考值（XlogP）:2.8

  2.氢键供体数量:0

  3.氢键受体数量:0

  4.可旋转化学键数量:5

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:13

  8.表面电荷:0

  9.复杂度:147

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：0.969

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：无可用

  5. 沸点（ºC,常压）：127

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：1.568

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Name: Diallylphenylphosphine Material Safety Data Sheet Synonym: CAS: 29949-75-5 Section 1 - Chemical Product MSDS Name:Diallylphenylphosphine Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 29949-75-5 Diallylphenylphosphine unlisted Hazard Symbols: XI F Risk Phrases: 17 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Spontaneously flammable in air. Irritating to eyes, respiratory system and skin.Air sensitive. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Material can spontaneously ignite (pyrophoric) when exposed to air at normal or slightly elevated temperatures. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Use a spark-proof tool. Section 7 - HANDLING and STORAGE Handling: Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use and store under nitrogen. Use only in a chemical fume hood. Storage: Keep away from sources of ignition. Do not store near combustible materials. Store in a cool, dry place. Store in a tightly closed container. Flammables-area. Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 29949-75-5: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 127 deg C @ 14 mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: .9690g/cm3 Molecular Formula: C12H15P Molecular Weight: 190.23 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, ignition sources, exposure to air. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of phosphorus, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 29949-75-5 unlisted. LD50/LC50: Not available. Carcinogenicity: Diallylphenylphosphine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: PYROPHORIC LIQUID, ORGANIC, N.O.S.* Hazard Class: 4.2 UN Number: 2845 Packing Group: I IMO Shipping Name: PYROPHORIC LIQUID, ORGANIC, N.O.S. Hazard Class: 4.2 UN Number: 2845 Packing Group: I RID/ADR Shipping Name: PYROPHORIC LIQUID, ORGANIC, N.O.S. Hazard Class: 4.2 UN Number: 2845 Packing group: I Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI F Risk Phrases: R 17 Spontaneously flammable in air. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 29949-75-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 29949-75-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 29949-75-5 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。

安全

• 危害码 (欧洲): F: Flammable;Xi: Irritant;
• 风险声明 (欧洲): R17
• 安全声明 (欧洲): 16-26-27-28-36/37/39-37/39
• 危险品运输编码: UN 2845 4.2/PG 1
• WGK德国: 3
• 包装等级: I
• 危险类别: 4.2

合成路线

644-97-3 1730-25-2 ~% 29949-75-5

文献：Journal of the Chemical Society, , p. 1446,1449

58359-50-5 3052-45-7 ~% 29949-75-5

文献：Journal of Organometallic Chemistry, , vol. 301, p. 289 - 298

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