181124-40-3

• 常用中文名：1,3-苯并噻唑-6-磺酰氯
• 常用英文名：1,3-Benzothiazole-6-sulfonyl chloride
• CAS号：181124-40-3
• 分子式：C₇H₄ClNO₂S₂
• 分子量：233.695
• 发布时间：2018-07-18 13:15:08
• 更新时间：2024-01-02 15:29:50
• 下载msds

名称

• 中文名: 1,3-苯并噻唑-6-磺酰氯
• 英文名: 1,3-benzothiazole-6-sulfonyl chloride
• 英文别名: 1,3-Benzothiazol-6-ylsulfonyl chloride; 1,3-benzothiazole-6-sulphonyl chloride; 1,3-Benzothiazole-6-sulfonyl chloride; benzothiazole-6-sulfonyl chloride; 1,3-BENZOTHIAZOLE; Benzo[d]thiazole-6-sulfonyl chloride; benzthiazole-6-sulfonyl chloride; 1,3-benzothiazole-6-sulfonylchloride; 6-Benzothiazolesulfonyl chloride; benzothiazol-6-ylchlorosulfone

物化性质

• 密度: 1.6±0.1 g/cm3
• 沸点: 377.0±15.0 °C at 760 mmHg
• 熔点: 118-119ºC
• 分子式: C₇H₄ClNO₂S₂
• 分子量: 233.695
• 闪点: 181.8±20.4 °C
• 精确质量: 232.937195
• PSA: 83.65000
• LogP: 1.78
• 外观性状: 灰白色至黄色固体
• 蒸汽压: 0.0±0.8 mmHg at 25°C
• 折射率: 1.678
• 储存条件: 2-8°C

MSDS

Name: 1 3-Benzothiazole-6-sulfonyl chloride 90+% Material Safety Data Sheet Synonym: CAS: 181124-40-3 Section 1 - Chemical Product MSDS Name:1 3-Benzothiazole-6-sulfonyl chloride 90+% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 181124-40-3 1,3-Benzothiazole-6-sulfonyl chloride 90+% unlisted Hazard Symbols: C Risk Phrases: 22 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful if swallowed. Causes burns.Moisture sensitive. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 181124-40-3: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 140.8 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H4ClNO2S2 Molecular Weight: 233.7 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to moist air or water. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 181124-40-3 unlisted. LD50/LC50: Not available. Carcinogenicity: 1,3-Benzothiazole-6-sulfonyl chloride - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.* Hazard Class: 8 UN Number: 3261 Packing Group: III IMO Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. Hazard Class: 8 UN Number: 3261 Packing Group: III RID/ADR Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. Hazard Class: 8 UN Number: 3261 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 22 Harmful if swallowed. R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 181124-40-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 181124-40-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 181124-40-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): C:Corrosive;
• 风险声明 (欧洲): R20/21/22;R29;R34
• 安全声明 (欧洲): S26-S36/37/39-S45
• 危险品运输编码: 1759.0
• 海关编码: 2934999090

合成路线

18101-58-1 ~% 181124-40-3

文献：Bioorganic and Medicinal Chemistry, , vol. 11, # 22 p. 4769 - 4777

145708-16-3 ~% 181124-40-3

文献：Bioorganic and Medicinal Chemistry, , vol. 11, # 22 p. 4769 - 4777

533-30-2 7758-99-8 ~% 181124-40-3

文献：EP1803709 A1, ;

上下游产品

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145708-16-3 533-30-2 7758-99-8 18101-58-1
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海关

海关编码	2934999090
中文概述	2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%