2017-68-7

• 常用中文名：2-氨乙基萘
• 常用英文名：2-(NAPHTHALEN-2-YL)ETHANAMINE
• CAS号：2017-68-7
• 分子式：C₁₂H₁₃N
• 分子量：171.23800
• 发布时间：2018-05-09 08:00:00
• 更新时间：2024-01-06 14:46:37

名称

• 中文名: 2-萘-2-乙胺
• 英文名: 2-naphthalen-2-ylethanamine
• 英文别名: 2-Naphthaleneethanamine; naphth-2-ylethyl amine

物化性质

• 密度: 1.069g/cm3
• 沸点: 313.9ºC at 760 mmHg
• 分子式: C₁₂H₁₃N
• 分子量: 171.23800
• 闪点: 153ºC
• 精确质量: 171.10500
• PSA: 26.02000
• LogP: 3.04130
• 蒸汽压: 0.000482mmHg at 25°C
• 折射率: 1.633
• 储存条件: 2-8°C，避光，保存于惰性气体中

MSDS

SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifiers Product name: 2-(2-NAPHTHYL)ETHANAMINE REACH No.: A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline. SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 4), H302 Serious eye damage (Category 1), H318 Acute aquatic toxicity (Category 1), H400 For the full text of the H-Statements mentioned in this Section, see Section 16. Classification according to EU Directives 67/548/EEC or 1999/45/EC Xn, N Harmful, Dangerous for the R22, R41, R50/53 environment For the full text of the R-phrases mentioned in this Section, see Section 16. Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal wordDanger Hazard statement(s) Harmful if swallowed. Causes serious eye damage. Very toxic to aquatic life. Precautionary statement(s) Avoid release to the environment. Wear protective gloves/ eye protection/ face protection. P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Supplemental Hazardnone Statements Other hazards - none SECTION 3: Composition/information on ingredients Substances Formula: C12H13N Molecular Weight: 171,24 g/mol Hazardous ingredients according to Regulation (EC) No 1272/2008 ComponentClassificationConcentration 2-(2-Naphthyl)ethanamine Acute Tox. 4; Eye Dam. 1;- Aquatic Acute 1; H302, H318, Hazardous ingredients according to Directive 1999/45/EC ComponentClassificationConcentration 2-(2-Naphthyl)ethanamine Xn, N, R22 - R41 - R50 - R53 - For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 SECTION 4: First aid measures Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 Indication of any immediate medical attention and special treatment needed no data available SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx) Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. SECTION 7: Handling and storage Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection. For precautions see section 2.2. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Specific end use(s) A part from the uses mentioned in section 1.2 no other specific uses are stipulated SECTION 8: Exposure controls/personal protection Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties a) AppearanceForm: solid b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingno data available point f) Initial boiling point and no data available boiling range g) Flash pointno data available h) Evapouration rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerno data available flammability or explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative densityno data available n) Water solubilityno data available o) Partition coefficient: n- log Pow: 2,496 octanol/water p) Auto-ignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available SECTION 10: Stability and reactivity Reactivity no data available Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials Strong oxidizing agents Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation Serious eye damage/eye irritation Severe eye irritation Respiratory or skin sensitisation no data available Germ cell mutagenicity no data available Carcinogenicity IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Additional Information RTECS: Not available To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. SECTION 12: Ecological information Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted Other adverse effects Very toxic to aquatic life. SECTION 13: Disposal considerations Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. SECTION 14: Transport information UN number ADR/RID: 3077IMDG: 3077IATA: 3077 UN proper shipping name ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-(2- Naphthyl)ethanamine) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-(2- Naphthyl)ethanamine) IATA:Environmentally hazardous substance, solid, n.o.s. (2-(2-Naphthyl)ethanamine) Transport hazard class(es) ADR/RID: 9IMDG: 9IATA: 9 Packaging group ADR/RID: IIIIMDG: IIIIATA: III Environmental hazards ADR/RID: yesIMDG Marine pollutant: yesIATA: yes Special precautions for user Further information EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids. SECTION 15: Regulatory information This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment NDangerous for the environment XnHarmful R22Harmful if swallowed. R41Risk of serious damage to eyes. R50Very toxic to aquatic organisms. R50/53Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R53May cause long-term adverse effects in the aquatic environment. Further information only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 海关编码: 2921499090

合成路线

7498-57-9 ~69% 2017-68-7

文献：E. I. Du Pont de Nemours and Company Patent: US5378708 A1, 1995 ;

406953-48-8 ~% 2017-68-7

文献：The Procter and Gamble Company Patent: US2006/128613 A1, 2006 ; Location in patent: Page/Page column 24 ; US 20060128613 A1

1485-07-0 ~87% 2017-68-7

文献：Sun, Weilin; Pelletier, Jeffrey C. Tetrahedron Letters, 2007 , vol. 48, # 44 p. 7745 - 7746

33108-85-9 ~% 2017-68-7

文献：Korosec, Tina; Acimovic, Jure; Seliskar, Matej; Kocjan, Darko; Tacer, Klementina Fon; Rozman, Damjana; Urleb, Uros Bioorganic and Medicinal Chemistry, 2008 , vol. 16, # 1 p. 209 - 221

73130-31-1 ~% 2017-68-7

文献：Mayer; Schnecko Chemische Berichte, 1923 , vol. 56, p. 1413

184166-51-6 ~% 2017-68-7

文献：Mayer,F.; Sieglitz Chemische Berichte, 1922 , vol. 55, p. 1854

939-26-4 ~% 2017-68-7

文献：Mayer; Schnecko Chemische Berichte, 1923 , vol. 56, p. 1413

827-54-3 ~% 2017-68-7 3082-62-0 1201-74-7

文献：Fernandez, Elena; Hooper, Mark W.; Knight, Frances I.; Brown, John M. Chemical Communications, 1997 , # 2 p. 173 - 174

7498-57-9 7664-93-9 64-19-7 ~% 2017-68-7

文献：Kindler et al. Archiv der Pharmazie (Weinheim, Germany), 1939 , vol. 277, p. 25,26 Anm.2

上下游产品

上游产品  9
7498-57-9 1485-07-0 33108-85-9 73130-31-1
184166-51-6 939-26-4 827-54-3 7664-93-9
64-19-7
下游产品  2
109220-61-3 861798-14-3

海关

海关编码	2921499090
中文概述	2921499090 其他芳香单胺及衍生物及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%