2-(NAPHTHALEN-2-YL)ETHANAMINE

Modify Date: 2024-01-06 14:46:37

2-(NAPHTHALEN-2-YL)ETHANAMINE Structure
2-(NAPHTHALEN-2-YL)ETHANAMINE structure
Common Name 2-(NAPHTHALEN-2-YL)ETHANAMINE
CAS Number 2017-68-7 Molecular Weight 171.23800
Density 1.069g/cm3 Boiling Point 313.9ºC at 760 mmHg
Molecular Formula C12H13N Melting Point N/A
MSDS N/A Flash Point 153ºC

 Names

Name 2-naphthalen-2-ylethanamine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.069g/cm3
Boiling Point 313.9ºC at 760 mmHg
Molecular Formula C12H13N
Molecular Weight 171.23800
Flash Point 153ºC
Exact Mass 171.10500
PSA 26.02000
LogP 3.04130
Vapour Pressure 0.000482mmHg at 25°C
Index of Refraction 1.633

 MSDS


SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifiers
Product name: 2-(2-NAPHTHYL)ETHANAMINE
REACH No.: A registration number is not available for this substance as the substance
or its uses are exempted from registration, the annual tonnage does not
require a registration or the registration is envisaged for a later
registration deadline.


SECTION 2: Hazards identification
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Serious eye damage (Category 1), H318
Acute aquatic toxicity (Category 1), H400
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Xn, N Harmful, Dangerous for the R22, R41, R50/53
environment
For the full text of the R-phrases mentioned in this Section, see Section 16.
Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal wordDanger
Hazard statement(s)
Harmful if swallowed.
Causes serious eye damage.
Very toxic to aquatic life.
Precautionary statement(s)
Avoid release to the environment.
Wear protective gloves/ eye protection/ face protection.
P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazardnone
Statements
Other hazards - none

SECTION 3: Composition/information on ingredients
Substances
Formula: C12H13N
Molecular Weight: 171,24 g/mol
Hazardous ingredients according to Regulation (EC) No 1272/2008
ComponentClassificationConcentration
2-(2-Naphthyl)ethanamine
Acute Tox. 4; Eye Dam. 1;-
Aquatic Acute 1; H302, H318,
Hazardous ingredients according to Directive 1999/45/EC
ComponentClassificationConcentration
2-(2-Naphthyl)ethanamine
Xn, N, R22 - R41 - R50 - R53 -
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

SECTION 4: First aid measures
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
Indication of any immediate medical attention and special treatment needed
no data available

SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx)
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

SECTION 7: Handling and storage
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire
protection.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific end use(s)
A part from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering
controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such
as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.

SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
a) AppearanceForm: solid
b) Odourno data available
c) Odour Thresholdno data available
d) pHno data available
e) Melting point/freezingno data available
point
f) Initial boiling point and no data available
boiling range
g) Flash pointno data available
h) Evapouration rateno data available
i) Flammability (solid, gas) no data available
j) Upper/lowerno data available
flammability or
explosive limits
k) Vapour pressureno data available
l) Vapour densityno data available
m) Relative densityno data available
n) Water solubilityno data available
o) Partition coefficient: n- log Pow: 2,496
octanol/water
p) Auto-ignitionno data available
temperature
q) Decompositionno data available
temperature
r) Viscosityno data available
s) Explosive propertiesno data available
t) Oxidizing propertiesno data available
Other safety information
no data available

SECTION 10: Stability and reactivity
Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5

SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
Serious eye damage/eye irritation
Severe eye irritation
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.

SECTION 12: Ecological information
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
Very toxic to aquatic life.

SECTION 13: Disposal considerations
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material. Dissolve or mix the material with a
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

SECTION 14: Transport information
UN number
ADR/RID: 3077IMDG: 3077IATA: 3077
UN proper shipping name
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-(2-
Naphthyl)ethanamine)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-(2-
Naphthyl)ethanamine)
IATA:Environmentally hazardous substance, solid, n.o.s. (2-(2-Naphthyl)ethanamine)
Transport hazard class(es)
ADR/RID: 9IMDG: 9IATA: 9
Packaging group
ADR/RID: IIIIMDG: IIIIATA: III
Environmental hazards
ADR/RID: yesIMDG Marine pollutant: yesIATA: yes
Special precautions for user
Further information
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination
packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

SECTION 15: Regulatory information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
NDangerous for the environment
XnHarmful
R22Harmful if swallowed.
R41Risk of serious damage to eyes.
R50Very toxic to aquatic organisms.
R50/53Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R53May cause long-term adverse effects in the aquatic environment.
Further information
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

HS Code 2921499090

 Synthetic Route

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2-(NAPHTHALEN-2-YL)ETHANAMINE Structure

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CAS#:2017-68-7

Literature: E. I. Du Pont de Nemours and Company Patent: US5378708 A1, 1995 ;

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2-(NAPHTHALEN-2-YL)ETHANAMINE Structure

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CAS#:2017-68-7

Literature: The Procter and Gamble Company Patent: US2006/128613 A1, 2006 ; Location in patent: Page/Page column 24 ; US 20060128613 A1

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2-(NAPHTHALEN-2-YL)ETHANAMINE Structure

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CAS#:2017-68-7

Literature: Sun, Weilin; Pelletier, Jeffrey C. Tetrahedron Letters, 2007 , vol. 48, # 44 p. 7745 - 7746

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2-(NAPHTHALEN-2-YL)ETHANAMINE Structure

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CAS#:2017-68-7

Literature: Korosec, Tina; Acimovic, Jure; Seliskar, Matej; Kocjan, Darko; Tacer, Klementina Fon; Rozman, Damjana; Urleb, Uros Bioorganic and Medicinal Chemistry, 2008 , vol. 16, # 1 p. 209 - 221

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2-(NAPHTHALEN-2-YL)ETHANAMINE Structure

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CAS#:2017-68-7

Literature: Mayer; Schnecko Chemische Berichte, 1923 , vol. 56, p. 1413

~%

2-(NAPHTHALEN-2-YL)ETHANAMINE Structure

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CAS#:2017-68-7

Literature: Mayer,F.; Sieglitz Chemische Berichte, 1922 , vol. 55, p. 1854

~%

2-(NAPHTHALEN-2-YL)ETHANAMINE Structure

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CAS#:2017-68-7

Literature: Mayer; Schnecko Chemische Berichte, 1923 , vol. 56, p. 1413

~%

2-(NAPHTHALEN-2-YL)ETHANAMINE Structure

2-(NAPHTHALEN-2...

CAS#:2017-68-7

Literature: Fernandez, Elena; Hooper, Mark W.; Knight, Frances I.; Brown, John M. Chemical Communications, 1997 , # 2 p. 173 - 174

~%

2-(NAPHTHALEN-2-YL)ETHANAMINE Structure

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CAS#:2017-68-7

Literature: Kindler et al. Archiv der Pharmazie (Weinheim, Germany), 1939 , vol. 277, p. 25,26 Anm.2

 Customs

HS Code 2921499090
Summary 2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Synonyms

2-Naphthaleneethanamine
naphth-2-ylethyl amine
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