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1298-55-1生产厂家

1298-55-1价格

1298-55-1

1298-55-1结构式
1298-55-1结构式

化源商城直购

中文名 三(环戊二烯)化钐
英文名 tris(cyclopentadienyl)samarium
中文别名 三(环戊二烯)钐(III)
英文别名 Samarium (III) tris(cyclopentadienyl)
samarium tris(cyclopentadienide)
tris(eta5-cyclopenta-2,4-dien-1-yl)samarium
tris(cyclopentadienyl)samarium(III)
MFCD00013755
Samarium tricyclopentadienide
EINECS 215-075-7
沸点 41.5ºC at 760 mmHg
熔点 356ºC
分子式 C15H15Sm
分子量 345.64000
精确质量 347.03700
LogP 3.06450
蒸汽压 418mmHg at 25°C
储存条件

保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置

稳定性

如果遵照规格使用和储存则不会分解,未有已知危险反应,避免氧化物、水分/潮湿、空气

分子结构

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:347.037075 Da

8、标称质量:347 Da

9、平均质量:345.6396 Da

计算化学

1、 氢键供体数量:0

2、 氢键受体数量:15

3、 可旋转化学键数量:0

4、 拓扑分子极性表面积(TPSA):0

5、 重原子数量:16

6、 表面电荷:-15

7、 复杂度:58.1

8、 同位素原子数量:0

9、 确定原子立构中心数量:0

10、 不确定原子立构中心数量:0

11、 确定化学键立构中心数量:0

12、 不确定化学键立构中心数量:0

13、 共价键单元数量:4

更多

1. 性状:粉末

2. 密度(g/mL,25℃):未确定

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):>350

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,0.05mmHg):未确定

7. 折射率(n20/D):未确定

8. 闪点(ºF):38

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):未确定

11. 蒸气压(mmHg,20ºC):未确定

12. 饱和蒸气压(kPa,60ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:与水反应


Section 1: Product Identification
Chemical Name:Tris(cyclopentadienyl)samarium(99.9%-Sm) (REO)
CAS Registry Number:1298-55-1
Formula:(C5H5)3Sm
EINECS Number:215-55-1
Chemical Family:metallocene
Synonym:tris(eta5-2,4-cyclopentadien-1-yl)samarium

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound1298-55-1100%no datano data

Section 3: Hazards Identification
Emergency Overview:May be irritating to skin, eyes, and mucous membranes. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:May cause slight to mild irritation of the eyes.
Skin Contact:May cause slight to mild irritation of the skin.
Inhalation:(If dust) May be irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:May be irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
Inhalation:
breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide or dry powder
If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: Flammable solid. Dust may form explosive mixtures with air.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Store and handle the material under an inert atmosphere of dry nitrogen or argon. Keep away from heat, air
Handling and Storage:
and moisture.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:orange powder
Molecular Weight:345.69
Melting Point:356°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air sensitive, moisture sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:Air and moisture. Keep away from ignition sources.
Incompatibility:halogens and oxidizing agents
Decomposition Products:carbon monoxide, carbon dioxide, samarium oxide and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data available
Mutagenic Effects:no data available
Tetratogenic Effects:no data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Flammable solids, Organic, N.O.S.
Hazard Class (CFR):4.1
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN# 1325
Shipping Name (IATA):Flammable solid, Organic, N.O.S.
Hazard Class (IATA):4.1
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 1325

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

生态学数据:

对是水稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统,若无政府许可,勿将材料排入周围环境。

危害码 (欧洲) F: Flammable;
风险声明 (欧洲) R11
安全声明 (欧洲) 43-7/8
危险品运输编码 UN 3395 4
包装等级 III
危险类别 4.1
海关编码 2902199090
海关编码 2902199090
中文概述 2902199090 其他环烷烃、环烯烃及环萜烯。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:2.0%。普通关税:30.0%
申报要素 品名, 成分含量
Summary 2902199090 other cyclanes, cyclenes and cyclotherpenes。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%