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25753-22-4

25753-22-4结构式
25753-22-4结构式

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中文名 2,4,6-三(三氟甲基)苯胺
英文名 2,4,6-tris(trifluoromethyl)aniline
中文别名 1,1'-(1,1,2,2-四甲基-1,2-亚乙基)二苯
英文别名 2',4',6'-Tris-(trifluormethyl)-anilin
2,4,6-tris(trifluoromethyl)phenylamine
2,3-DIMETHYL-2,3-DIPHENYLBUTANE
密度 1.545g/cm3
沸点 149.8ºC at 760 mmHg
熔点 57-59ºC
分子式 C9H4F9N
分子量 297.12000
闪点 55.5ºC
精确质量 297.02000
PSA 26.02000
LogP 4.90640
蒸汽压 3.97mmHg at 25°C
折射率 1.388
Name: 2 4 6-Tris(trifluoromethyl)aniline 97% Material Safety Data Sheet
Synonym:
CAS: 25753-22-4
Section 1 - Chemical Product MSDS Name:2 4 6-Tris(trifluoromethyl)aniline 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
25753-22-4 2,4,6-Tris(trifluoromethyl)aniline 97% unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.Air sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store under an inert atmosphere.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 25753-22-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 57 - 59 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H4F9N
Molecular Weight: 297

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to air.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, fluorine, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 25753-22-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,4,6-Tris(trifluoromethyl)aniline - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 25753-22-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 25753-22-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 25753-22-4 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
危害码 (欧洲) Xi: Irritant;
风险声明 (欧洲) R20/21/22;R36/37/38
安全声明 (欧洲) S26-S36/37/39
海关编码 2921420090

~55%

25753-22-4结构式

25753-22-4

文献:Edelbach, Brian L.; Pharoah, Blaze M.; Bellows, Sarina M.; Thayer, Peter R.; Fennie, Charles N.; Cowley, Ryan E.; Holland, Patrick L. Synthesis (Germany), 2012 , vol. 44, # 23 art. no. SS-2012-M0747-OP, p. 3595 - 3597

~77%

25753-22-4结构式

25753-22-4

文献:Ahlemann, Jens-T; Roesky, Herbert W.; Noltemeyer, Mathias; Schmidt, Hans-G.; Markovsky, Leonid N.; Shermolovich, Yuri G. Journal of Fluorine Chemistry, 1998 , vol. 87, # 1 p. 87 - 90

~%

25753-22-4结构式

25753-22-4

文献:Journal of Fluorine Chemistry, , vol. 87, # 1 p. 87 - 90

~%

25753-22-4结构式

25753-22-4

文献:Journal of Fluorine Chemistry, , vol. 87, # 1 p. 87 - 90

~%

25753-22-4结构式

25753-22-4

文献:Journal of Fluorine Chemistry, , vol. 87, # 1 p. 87 - 90

~55%

25753-22-4结构式

25753-22-4

文献:Journal of Fluorine Chemistry, , vol. 131, # 1 p. 98 - 105
海关编码 2921420090
中文概述 2921420090 其他苯胺衍生物及其盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素 品名, 成分含量, 用途
Summary HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%