中文名 | 2,4,6-三(三氟甲基)苯胺 |
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英文名 | 2,4,6-tris(trifluoromethyl)aniline |
中文别名 | 1,1'-(1,1,2,2-四甲基-1,2-亚乙基)二苯 |
英文别名 |
2',4',6'-Tris-(trifluormethyl)-anilin
2,4,6-tris(trifluoromethyl)phenylamine 2,3-DIMETHYL-2,3-DIPHENYLBUTANE |
密度 | 1.545g/cm3 |
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沸点 | 149.8ºC at 760 mmHg |
熔点 | 57-59ºC |
分子式 | C9H4F9N |
分子量 | 297.12000 |
闪点 | 55.5ºC |
精确质量 | 297.02000 |
PSA | 26.02000 |
LogP | 4.90640 |
蒸汽压 | 3.97mmHg at 25°C |
折射率 | 1.388 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin.Air sensitive. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 25753-22-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 57 - 59 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C9H4F9N Molecular Weight: 297 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to air. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, fluorine, hydrogen fluoride gas. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 25753-22-4 unlisted. LD50/LC50: Not available. Carcinogenicity: 2,4,6-Tris(trifluoromethyl)aniline - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2811 Packing Group: III IMO Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: III RID/ADR Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 25753-22-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 25753-22-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 25753-22-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
危害码 (欧洲) | Xi: Irritant; |
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风险声明 (欧洲) | R20/21/22;R36/37/38 |
安全声明 (欧洲) | S26-S36/37/39 |
海关编码 | 2921420090 |
~55% 25753-22-4 |
文献:Edelbach, Brian L.; Pharoah, Blaze M.; Bellows, Sarina M.; Thayer, Peter R.; Fennie, Charles N.; Cowley, Ryan E.; Holland, Patrick L. Synthesis (Germany), 2012 , vol. 44, # 23 art. no. SS-2012-M0747-OP, p. 3595 - 3597 |
~77% 25753-22-4 |
文献:Ahlemann, Jens-T; Roesky, Herbert W.; Noltemeyer, Mathias; Schmidt, Hans-G.; Markovsky, Leonid N.; Shermolovich, Yuri G. Journal of Fluorine Chemistry, 1998 , vol. 87, # 1 p. 87 - 90 |
~% 25753-22-4 |
文献:Journal of Fluorine Chemistry, , vol. 87, # 1 p. 87 - 90 |
~% 25753-22-4 |
文献:Journal of Fluorine Chemistry, , vol. 87, # 1 p. 87 - 90 |
~% 25753-22-4 |
文献:Journal of Fluorine Chemistry, , vol. 87, # 1 p. 87 - 90 |
~55% 25753-22-4 |
文献:Journal of Fluorine Chemistry, , vol. 131, # 1 p. 98 - 105 |
上游产品 6 | |
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下游产品 0 |
海关编码 | 2921420090 |
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中文概述 | 2921420090 其他苯胺衍生物及其盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0% |
申报要素 | 品名, 成分含量, 用途 |
Summary | HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |