13520-92-8

• 常用中文名：氯氧化锆,八水
• 常用英文名：Zirconyl chloride octahydrate
• CAS号：13520-92-8
• 分子式：Cl₂H₁₆O₉Zr
• 分子量：322.25200
• 相关类别： 无机化工 无机盐 金属卤化物及卤酸盐 金属氯化物及盐
• 发布时间：2018-09-17 15:55:13
• 更新时间：2024-01-02 15:57:14
• 用途一：用做制造二氧化锆原料。也用做橡胶添加剂、涂料干燥剂、耐火材料、陶瓷、釉药和纤维的处理剂。
  用途二：其它锆产品的中间体，也作橡胶添加剂，油漆催干剂等。
  用途三：用作润滑脂添加剂、防水剂和鞣剂等。
  用途四：广泛用于橡胶添加剂、油漆催干剂、耐火材料和陶瓷釉等。

名称

• 中文名: 氧氯化锆
• 英文名: Zirconyl chloride octahydrate
• 中文别名: 氯氧化锆,八水; 次氯酸锆; 八水氧氯化锆
• 英文别名: Zirconium(IV) oxychloride octahydrate; oxozirconium,octahydrate,dihydrochloride; EINECS 231-717-9; Zirconium(IV) oxide chloride; MFCD00149898

物化性质

• 密度: 1.91
• 熔点: 400°C (dec.)
• 分子式: Cl₂H₁₆O₉Zr
• 分子量: 322.25200
• 精确质量: 319.92200
• PSA: 90.91000
• LogP: 0.74580
• 外观性状: 固体
• 折射率: 1.552
• 储存条件:

  应贮存在通风、干燥的库房中。运输时，要防止雨淋受潮，防日光曝晒。

• 稳定性:

  常温常压下稳定

  避免的物料 水分/潮湿氧化物 碱金属。在150℃失去6个结晶水，210℃变成无水物。溶于水、甲醇、乙醇和醚，微溶于盐酸，不溶于其他有机溶剂。在空气中稳定。可溶于冷水、乙醇。加热则脱水、分解而转变为氧化锆。
• 水溶解性: SOLUBLE
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：319.921839 Da

  8、标称质量：320 Da

  9、平均质量：322.2516 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:10

  3.氢键受体数量:9

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积25.1

  7.重原子数量:12

  8.表面电荷:0

  9.复杂度:6

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:11

• 更多:

  1. 性状：白色正方晶系晶体

  2. 密度（g/mL,25/4℃）：1.91

  3. 熔点（ºC）：400

  4. 溶解性：可溶解的

MSDS

Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE Product identifiers Product name: Zirconium atomic spectroscopy standard concentrate 1.00 g Zr : Fluka Section2. HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Skin corrosion (Category 1B) Specific target organ toxicity - single exposure (Category 3) Classification according to EU Directives 67/548/EEC or 1999/45/EC Causes burns. Irritating to respiratory system. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal wordDanger Hazard statement(s) Causes severe skin burns and eye damage. May cause respiratory irritation. Precautionary statement(s) Avoid breathing vapours. Wear protective gloves/ protective clothing/ eye protection/ face protection. P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Supplemental Hazardnone Statements According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R34Causes burns. R37Irritating to respiratory system. S-phrase(s) S26In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39Wear suitable protective clothing, gloves and eye/face protection. S45In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Other hazards - none Section3. COMPOSITION/INFORMATION ON INGREDIENTS Mixtures Synonyms: Zirconium(IV) oxychloridesolution Molecular Weight: 178,13 g/mol ComponentClassificationConcentration Hydrochloric acid CAS-No.7647-01-0Skin Corr. 1B; STOT SE 3;10 - 20 % EC-No.231-595-7H314, H335 Index-No.017-002-01-XC, R34 - R37 Zirconium dichloride oxide CAS-No.13520-92-8Skin Corr. 1B; H3145 - 10 % EC-No.231-717-9C, R34 For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 Section4. FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea Indication of any immediate medical attention and special treatment needed no data available Section5. FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Hydrogen chloride gas, Zirconium oxides Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available Section6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. Section7. HANDLING AND STORAGE Precautions for safe handling Avoid inhalation of vapour or mist. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Specific end uses no data available Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Section9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) AppearanceForm: liquid Colour: yellow b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingno data available point f) Initial boiling point and no data available boiling range g) Flash pointnot applicable h) Evaporation rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerno data available flammability or explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative densityno data available n) Water solubilityno data available o) Partition coefficient: n- no data available octanol/water p) Autoignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available Section10. STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials Bases, Alkali metals, Strong oxidizing agents, Metals, Amines, permanganates, e.g. potassium permanganate, Fluorine, hexalithium disilicide Hazardous decomposition products Other decomposition products - no data available Section11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC:3 - Group 3: Not classifiable as to its carcinogenicity to humans (Hydrochloric acid) Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. IngestionMay be harmful if swallowed. Causes burns. SkinMay be harmful if absorbed through skin. Causes skin burns. Eyes Causes eye burns. Signs and Symptoms of Exposure Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea Additional Information RTECS: Not available Section12. ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects no data available Section13. DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. Section14. TRANSPORT INFORMATION UN number ADR/RID: 3264IMDG: 3264IATA: 3264 UN proper shipping name ADR/RID: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Hydrochloric acid, Zirconium dichloride oxide) IMDG: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Hydrochloric acid, Zirconium dichloride oxide) IATA:Corrosive liquid, acidic, inorganic, n.o.s. (Hydrochloric acid, Zirconium dichloride oxide) Transport hazard class(es) ADR/RID: 8IMDG: 8IATA: 8 Packaging group ADR/RID: IIIIMDG: IIIIATA: III Environmental hazards ADR/RID: noIMDG Marine pollutant: noIATA: no Special precautions for user no data available Section15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment Causes severe skin burns and eye damage. May cause respiratory irritation. Skin Corr.Skin corrosion STOT SESpecific target organ toxicity - single exposure CCorrosive R34Causes burns. R37Irritating to respiratory system. Further information only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 急性毒性：小鼠口经LD50：990 mg/kg。 主要的刺激性影响： 在皮肤上面：在皮肤和粘膜上造成腐蚀性影响，刺激皮肤和粘膜； 在眼睛上面：强烈的腐蚀性影响，刺激的影响；没有已知的敏化影响。 生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。 CHEMICAL IDENTIFICATION RTECS NUMBER : ZH7250000 CHEMICAL NAME : Zirconium chloride oxide octahydrate CAS REGISTRY NUMBER : 13520-92-8 LAST UPDATED : 199712 DATA ITEMS CITED : 24 MOLECULAR FORMULA : Cl2-O-Zr.8H2-O MOLECULAR WEIGHT : 322.28 WISWESSER LINE NOTATION : .ZR..O.G2 QH8 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intradermal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 800 ug/kg TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Sense Organs and Special Senses (Ear) - effect, not otherwise specified Musculoskeletal - tumors MUTATION DATA TEST SYSTEM : Rodent - mouse DOSE/DURATION : 220 mg/kg REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 243,29,1990 *** REVIEWS *** ACGIH TLV-TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 5 mg(Zr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,285,1971 OSHA PEL (Gen Indu):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL-DENMARK:TWA 5 mg(Zr)/m3 JAN 1993 OEL-FINLAND:TWA 5 mg(Zr)/m3 JAN 1993 OEL-GERMANY:TWA 5 mg(Zr)/m3 JAN 1993 OEL-HUNGARY:STEL 5 mg(Zr)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 5 mg(Zr)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 5 mg(Zr)/m3 JAN 1993 OEL-SWITZERLAND:TWA 5 mg(Zr)/m3 JAN 1993 OEL-TURKEY:TWA 5 mg(Zr)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

安全

• 符号: GHS05
• 信号词: Danger
• 危害声明: H314
• 警示性声明: P280-P305 + P351 + P338-P310
• 个人防护装备: Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
• 危害码 (欧洲): C:Corrosive;
• 风险声明 (欧洲): R22;R34
• 安全声明 (欧洲): S26-S36/37/39-S45-S27
• 危险品运输编码: UN 3264 8/PG 3
• WGK德国: 1
• RTECS号: ZH7250000
• 包装等级: III
• 危险类别: 8

上下游产品

上游产品  0
下游产品  1
7440-67-7

制备

氢氧化锆盐酸法锆英石与烧碱熔融，漂洗、除硅之后与硫酸作用，再加入氨水，得到氢氧化锆沉淀，用盐酸溶解沉淀物，得到氯氧化锆，经蒸发浓缩、冷却结晶、晶体粉碎，制得二氯氧化锆成品。

将30g四氯化锆、15mL的36％的盐酸及200mL的水混合，置于水浴上加热浓缩以达到饱和。冷却该溶液即可析出八水合物，过滤，用丙酮洗涤除去过剩的盐酸。