15884-65-8

• 常用中文名：3,4-(亚甲基二氧基)硫代甲酰氨
• 常用英文名：1,3-BENZODIOXOLE-5-CARBOTHIOAMIDE
• CAS号：15884-65-8
• 分子式：C₈H₇NO₂S
• 分子量：181.212
• 发布时间：2018-12-28 20:17:04
• 更新时间：2024-04-02 13:18:40

名称

• 中文名: 3,4-(亚甲基二氧基)硫代甲酰氨
• 英文名: 1,3-benzodioxole-5-carbothioamide
• 中文别名: 1,3-苯并二氧代-5-硫代甲酰胺
• 英文别名: 2H-1,3-benzodioxole-5-carbothioamide; benzo[1,3]dioxole-5-carbothioic acid amide; 1,3-BENZODIOXOLE-5-CARBOTHIOAMIDE; Benzo[1,3]dioxol-5-thiocarbonsaeure-amid; THIOPIPERONYLAMIDE; 3,4-methylenedioxythiobenzamide

物化性质

• 密度: 1.4±0.1 g/cm3
• 沸点: 321.5±52.0 °C at 760 mmHg
• 熔点: 183ºC
• 分子式: C₈H₇NO₂S
• 分子量: 181.212
• 闪点: 148.3±30.7 °C
• 精确质量: 181.019745
• PSA: 76.57000
• LogP: 0.90
• 蒸汽压: 0.0±0.7 mmHg at 25°C
• 折射率: 1.690
• 储存条件: 室温

MSDS

Name: 1 3-Benzodioxole-5-carbothioamide 97% Material Safety Data Sheet Synonym: CAS: 15884-65-8 Section 1 - Chemical Product MSDS Name:1 3-Benzodioxole-5-carbothioamide 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 15884-65-8 1,3-Benzodioxole-5-carbothioamide 97% unlisted Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 15884-65-8: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 179 - 181 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C8H7NO2S Molecular Weight: 181 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Acid chlorides, acids, strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 15884-65-8 unlisted. LD50/LC50: Not available. Carcinogenicity: 1,3-Benzodioxole-5-carbothioamide - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 15884-65-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 15884-65-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 15884-65-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 风险声明 (欧洲): 36/37/38
• 安全声明 (欧洲): 26-37
• 海关编码: 2932999099

合成路线

19172-47-5 25054-53-9 ~% 15884-65-8

文献：US6599917 B1, ;

4421-09-4 ~% 15884-65-8

文献：Journal of the American Chemical Society, , vol. 52, p. 1585

上下游产品

上游产品  3
19172-47-5 25054-53-9 4421-09-4
下游产品  4
4421-09-4 80784-88-9 5423-17-6 55315-33-8

海关

海关编码	2932999099
中文概述	2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%