35090-95-0

• 常用中文名：[4-哌啶基(1-吡咯烷基)甲酮]
• 常用英文名：4-Piperidinyl(1-pyrrolidinyl)methanone
• CAS号：35090-95-0
• 分子式：C₁₀H₁₈N₂O
• 分子量：182.263
• 发布时间：2018-07-15 12:25:56
• 更新时间：2024-01-23 18:04:14

名称

• 中文名: 4-哌啶基(1-吡咯烷基)甲酮
• 英文名: piperidin-4-yl(pyrrolidin-1-yl)methanone
• 中文别名: 4-(吡咯烷-1-基羰基)哌啶
• 英文别名: 1-(4-piperidinylcarbonyl)pyrrolidine; 1-(piperidine-4-carbonyl)-pyrrolidine; 4-Pyrrolidinocarbonylpiperidine HCl; 4-[(Pyrrolidin-1-yl)carbonyl]piperidine; MFCD03372520; 4-Piperidinyl(1-pyrrolidinyl)methanone; piperidin-4-yl(pyrrolidin-1-yl)methanone; Methanone, 4-piperidinyl-1-pyrrolidinyl-; Piperidin-4-yl-pyrrolidin-1-yl-methanone

物化性质

• 密度: 1.1±0.1 g/cm3
• 沸点: 335.3±35.0 °C at 760 mmHg
• 熔点: 45ºC
• 分子式: C₁₀H₁₈N₂O
• 分子量: 182.263
• 闪点: 156.6±25.9 °C
• 精确质量: 182.141907
• PSA: 32.34000
• LogP: 0.37
• 蒸汽压: 0.0±0.7 mmHg at 25°C
• 折射率: 1.513
• 储存条件: 2-8°C

MSDS

Name: 4-Piperidinyl(1-pyrrolidinyl)methanone Material Safety Data Sheet Synonym: None Known CAS: 35090-95-0 Section 1 - Chemical Product MSDS Name:4-Piperidinyl(1-pyrrolidinyl)methanone Material Safety Data Sheet Synonym:None Known Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 35090-95-0 4-Piperidinyl(1-pyrrolidinyl)methanone 97+ unlisted Hazard Symbols: C Risk Phrases: 20/21/22 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Causes burns. Potential Health Effects Eye: Causes eye burns. Skin: Harmful if absorbed through the skin. Causes skin burns. Ingestion: Harmful if swallowed. Causes gastrointestinal tract burns. Inhalation: Harmful if inhaled. Causes chemical burns to the respiratory tract. Chronic: Chronic exposure may cause effects similar to those of acute exposure. Section 4 - FIRST AID MEASURES Eyes: Do NOT allow victim to rub eyes or keep eyes closed. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately. Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Wash clothing before reuse. Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Vacuum or sweep up material and place into a suitable, dry disposal container. Section 7 - HANDLING and STORAGE Handling: Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. Use only with adequate ventilation. Storage: Keep container closed when not in use. Corrosives area. Store in a cool, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 35090-95-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 45-46 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C10H18N2O Molecular Weight: 182.27 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Dust generation. Incompatibilities with Other Materials: Oxidizing agents, acids, acid chlorides. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 35090-95-0 unlisted. LD50/LC50: Not available. Carcinogenicity: 4-Piperidinyl(1-pyrrolidinyl)methanone - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Ecotoxicity: Fish: Pseudomonas putida: Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: CORROSIVE SOLID, TOXIC, N.O.S. Hazard Class: 8 UN Number: 2923 Packing Group: III IMO Shipping Name: CORROSIVE SOLID, TOXIC, N.O.S. Hazard Class: 8 UN Number: 2923 Packing Group: III RID/ADR Shipping Name: CORROSIVE SOLID, TOXIC, N.O.S. Hazard Class: 8 UN Number: 2923 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 34 Causes burns. Safety Phrases: S 22 Do not breathe dust. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 35090-95-0: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 35090-95-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 35090-95-0 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): C: Corrosive;Xi: Irritant;
• 风险声明 (欧洲): R20/21/22
• 安全声明 (欧洲): 22-36/37/39
• 海关编码: 2933990090

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海关

海关编码	2933990090
中文概述	2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
Summary	2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%