460-32-2

• 常用中文名：3-溴-1,1,1-三氟丙烷
• 常用英文名：3,3,3-Trifluoropropyl Bromide
• CAS号：460-32-2
• 分子式：C₃H₄BrF₃
• 分子量：176.963
• 相关类别： 有机原料 有机氟化合物 氟丙烷系列
• 发布时间：2018-06-29 20:04:06
• 更新时间：2024-01-04 08:23:01

名称

• 中文名: 3-溴-1,1,1-三氟丙烷
• 英文名: 3-bromo-1,1,1-trifluoropropane
• 中文别名: 3-溴-1.1.1-三氟丙烷; 3-活-1,1,1-三氟丙烷
• 英文别名: 3,3,3-Trifluoropropyl Bromide; 1-bromo-2-trifluoromethylethane; 3,3,3-trifluoro-1-bromopropane; 1-Bromo-3,3,3-trifluoro propane; MFCD00042193; 3-bromo-1,1,1-trifluoro-propane; 3-BROMO-1,1,1-TRIFLUOROPROPANE; ZLC0170; 1-Bromo-3,3,3-trifluoropropane; Propane, 3-bromo-1,1,1-trifluoro-

物化性质

• 密度: 1.6±0.1 g/cm3
• 沸点: 64.8±8.0 °C at 760 mmHg
• 熔点: 62-63ºC
• 分子式: C₃H₄BrF₃
• 分子量: 176.963
• 闪点: -26.0±14.3 °C
• 精确质量: 175.944839
• LogP: 1.99
• 外观性状: 透明无色液体
• 蒸汽压: 174.5±0.1 mmHg at 25°C
• 折射率: 1.366
• 计算化学:

  1.疏水参数计算参考值（XlogP）:2.5

  2.氢键供体数量:0

  3.氢键受体数量:3

  4.可旋转化学键数量:1

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:7

  8.表面电荷:0

  9.复杂度:48.6

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：未确定

  2. 密度（g/mL,25℃）：1.662

  3. 相对密度（25℃，4℃）：未确定

  4. 常温折射率（n²⁵）：1.3602

  5. 沸点（ºC,常压）：62.5

  6. 沸点（ºC,11mmHg）：未确定

  7. 折射率(n20/D)：1.654（lit.）

  8. 闪点（ºC）：＞110

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（mmHg,25ºC）：未确定

  12. 饱和蒸气压（kPa,25ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Name: 3-Bromo-1 1 1-trifluoropropane Material Safety Data Sheet Synonym: 1-Bromo-3,3,3-trifluoropropan CAS: 460-32-2 Section 1 - Chemical Product MSDS Name:3-Bromo-1 1 1-trifluoropropane Material Safety Data Sheet Synonym:1-Bromo-3,3,3-trifluoropropan Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 460-32-2 3-Bromo-1,1,1-trifluoropropane 100.0 unlisted Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: No information regarding eye irritation and other potential effects was found. Skin: No information regarding skin irritation and other potential effects was found. Ingestion: The toxicological properties of this substance have not been fully investigated. Inhalation: The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use agent most appropriate to extinguish fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 460-32-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: none reported pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 63.5 deg C @ 760.00mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: > 230 deg C (> 446.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.662 Molecular Formula: C3H4BrF3 Molecular Weight: 176.96 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizers, acids, bases, and metals Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen fluoride gas, hydrogen bromide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 460-32-2 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-Bromo-1,1,1-trifluoropropane - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 460-32-2: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 460-32-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 460-32-2 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi: Irritant;N: Dangerous for the environment;
• 风险声明 (欧洲): R59
• 安全声明 (欧洲): S59-S37/39-S26
• 海关编码: 2903799090

上下游产品

上游产品  10
2240-88-2 677-21-4 460-25-3 13749-37-6
421-07-8 590-92-1 7446-70-0 10035-10-6
7664-39-3 7647-18-9
下游产品  7
406-93-9 460-37-7 677-21-4 1579-80-2
659-73-4 421-07-8 460-66-2

海关

海关编码	2903799090
中文概述	2903799090 其他无环烃卤化衍生物（含二种或三种以上不同卤素）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%
Summary	2903799090 halogenated derivatives of acyclic hydrocarbons containing two or more different halogens。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%