12145-90-3

• 常用中文名：1,1’-双(氯化汞)二茂铁
• 常用英文名：Chloro(cyclopentyl)mercury-iron (2:1)
• CAS号：12145-90-3
• 分子式：C₁₀H₁₈Cl₂FeHg₂
• 分子量：666.181
• 发布时间：2018-06-30 12:36:23
• 更新时间：2024-04-03 22:41:38

名称

• 中文名: 1,1’-双(氯化汞)二茂铁
• 英文名: Chloro(cyclopentyl)mercury-iron (2:1)
• 中文别名: 1,1'-双(氯化汞)二茂铁
• 英文别名: Chloro(cyclopentyl)mercury - iron (2:1); Mercury, chlorocyclopentyl-, iron salt (2:1)

物化性质

• 熔点: 300ºC
• 分子式: C₁₀H₁₈Cl₂FeHg₂
• 分子量: 666.181
• 精确质量: 667.954712
• LogP: 3.04190

MSDS

Name: 1 1 -Bis(chloromercuri)ferrocene tech. Material Safety Data Sheet Synonym: 1,1'-Bis(chloromercurio)ferrocene; Mercury, dichloro-mu-1,1'-ferrocenediyldi- CAS: 12145-90-3 Section 1 - Chemical Product MSDS Name:1 1 -Bis(chloromercuri)ferrocene tech. Material Safety Data Sheet Synonym:1,1'-Bis(chloromercurio)ferrocene; Mercury, dichloro-mu-1,1'-ferrocenediyldi- Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 12145-90-3 1,1'-Bis(chloromercuri)ferrocene 100 unlisted Hazard Symbols: T+ N Risk Phrases: 26/27/28 33 50/53 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Very toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inorganic mercury compounds may cause central and peripheral nervous system effects. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Acute exposure to high concentrations of mercury vapors may cause severe respiratory tract irritation. Chronic: Chronic exposure to mercury may cause permanent central nervous system damage, fatigue, weight loss, tremors, personality changes. Chronic ingestion may cause accumulation of mercury in body tissues. Chronic exposure to mercury vapors may produce weakness, fatigue, anorexia, loss of weight and gastrointestinal disturbances which is collectively referred to as asthenic-vegetative syndrome or micromercurialism. Chronic exposure to mercury compounds may produce immunologic glomerular disease. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Poison room locked. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 12145-90-3: United States OSHA: 0.1 mg/m3 Ceiling (listed under Mercury, ary and inorganic compounds). Belgium - TWA: (listed as mercury, alkyl compounds): 0.01 mg/m3 V (as Hg) Belgium - STEL: (listed as mercury, alkyl compounds): 0.03 mg/m3 (as Hg) France - VME: (listed as mercury, alkyl compounds): 0.01 mg/m3 VM (as Hg) Germany: (listed as mercury, alkyl compounds): 0.01 mg/m3 VME (as Malaysia: (listed as mercury, alkyl compounds): 0.01 mg/m3 TWA (a Hg) Netherlands: (listed as mercury, alkyl compounds): 0.02 mg/m3 STE (as Hg) Netherlands: (listed as mercury, alkyl compounds): 0.01 mg/m3 MAC Hg) Spain: (listed as mercury, alkyl compounds): 0.01 mg/m3 VLA-ED (a Hg) Spain: (listed as mercury, alkyl compounds): 0.03 mg/m3 VLA-EC (a Hg) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: almost white Odor: none reported pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: > 300 deg C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: >1.0 Molecular Formula: C10H8Cl2FeHg2 Molecular Weight: 656.10 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, dust generation, excess heat. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, mercury/mercury oxides. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 12145-90-3 unlisted. LD50/LC50: Not available. Carcinogenicity: 1,1'-Bis(chloromercuri)ferrocene - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: MERCURY COMPOUND, SOLID, N.O.S. Hazard Class: 6.1 UN Number: 2025 Packing Group: II IMO Shipping Name: MERCURY COMPOUND, SOLID, N.O.S. Hazard Class: 6.1 UN Number: 2025 Packing Group: II RID/ADR Shipping Name: MERCURY COMPOUND, SOLID, N.O.S. Hazard Class: 6.1 UN Number: 2025 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T+ N Risk Phrases: R 26/27/28 Very toxic by inhalation, in contact with skin and if swallowed. R 33 Danger of cumulative effects. R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety Phrases: S 13 Keep away from food, drink and animal feeding stuffs. S 28A After contact with skin, wash immediately with plenty of water. S 36 Wear suitable protective clothing. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 12145-90-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 12145-90-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 12145-90-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): T+:Very toxic; N:Dangerous for the environment;
• 风险声明 (欧洲): R26/27/28;R33;R50/53
• 安全声明 (欧洲): S13-S28-S36-S45-S60-S61