46429-76-9
46429-76-9结构式
- 常用中文名：N,N -二甲基-3,5-硝基苯
- 常用英文名：N,N-Dimethyl-3,5-dinitroaniline
- CAS号：46429-76-9
- 分子式：C8H9N3O4
- 分子量：211.17500
- 发布时间：2018-10-23 14:44:59
- 更新时间：2024-01-05 19:55:09
| 中文名 | N,N -二甲基-3,5-硝基苯 |
|---|---|
| 英文名 | N,N-Dimethyl-3,5-dinitroaniline |
| 中文别名 |
N,N-二甲基-3,5-硝基苯
N,N-二甲基-3,5-二硝基苯胺 |
| 英文别名 |
OXIFFLMOPHMUEE-UHFFFAOYSA
N,N-dimethyl-3,5-dinitro-aniline Benzenamine,N,N-dimethyl-3,5-dinitro N,N-Dimethyl-3,5-dinitro-anilin N,N-Dimethyl-2,4-dinitro-anilin 3,4-Dinitro-N,N-dimethyl-anilin |
| 密度 | 1.397g/cm3 |
|---|---|
| 沸点 | 342.848ºC at 760 mmHg |
| 分子式 | C8H9N3O4 |
| 分子量 | 211.17500 |
| 闪点 | 161.149ºC |
| 精确质量 | 211.05900 |
| PSA | 94.88000 |
| LogP | 2.61540 |
| 折射率 | 1.628 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:1.7 2.氢键供体数量:0 3.氢键受体数量:5 4.可旋转化学键数量:1 5.互变异构体数量:无 6.拓扑分子极性表面积94.9 7.重原子数量:15 8.表面电荷:0 9.复杂度:236 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
|
N,N-Dimethyl-3,5-dinitroaniline
SAFETY DATA SHEET Section1. IDENTIFICATION Product name:N,N-Dimethyl-3,5-dinitroaniline Section2. HAZARDS IDENTIFICATION GHS classification
PHYSICAL HAZARDS
Type C Self-reactive substances and mixtures HEALTH HAZARDS Category 4 Acute toxicity (Oral) Acute toxicity (Dermal)Category 4 Category 4 Acute toxicity (Inhalation) Skin corrosion/irritationCategory 2 Category 2A Serious eye damage/eye irritation ENVIRONMENTAL HAZARDSNot classified GHS label elements, including precautionary statements Pictograms or hazard symbols Danger Signal word Hazard statementsHeating may cause a fire Harmful if swallowed, in contact with skin or if inhaled Causes skin irritation Causes serious eye irritation Precautionary statements: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. [Prevention] Keep away from incompatible materials such as oxidizing agents. Keep only in original container. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Wear protective gloves and eye/face protection. N,N-Dimethyl-3,5-dinitroaniline Section2. HAZARDS IDENTIFICATION [Response]IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. [Storage]Store away from other materials. Store in a well-ventilated place. Keep cool. [Disposal]Dispose of contents/container through a waste management company authorized by the local government. Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance N,N-Dimethyl-3,5-dinitroaniline Components: Percent:.... CAS Number:46429-76-9 Chemical Formula:C8H9N3O4 Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. A rescuer should wear personal protective equipment, such as rubber gloves and air- Protection of first-aiders: tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Specific hazards arising Explosion risk in case of fire. Fight fire remotely due to the risk of explosion. from the chemical:Take care as it may decompose upon combustion or in high temperatures to generate poisonous fume. Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by spraying with water. Eliminate all ignition sources if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Use personal protective equipment. Keep people away from and upwind of spill/leak. Personal precautions, protective equipment and Entry to non-involved personnel should be controlled around the leakage area by emergency procedures: roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it. containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with up: appropriate laws and regulations. N,N-Dimethyl-3,5-dinitroaniline Section6. ACCIDENTAL RELEASE MEASURES Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in hazards:case of a fire. Use spark-proof tools and explosion-proof equipment. Section7. HANDLING AND STORAGE Precautions for safe handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Be careful not to cause leakage, overflow, or dispersion. Steam should not be generated unnecessarily. Keep away from heat/sparks/open flame/hot surfaces. -No smoking. Take measures to prevent the build up of electrostatic charge. Use explosion-proof equipment. Avoid shock and friction. Wash hands and face before breaks and immediately after handling the product. Use a local exhaust if dust or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Storage conditions:Keep container tightly closed. Store in a cool, dark and well-ventilated place. Be sure not to give the container unexpected impacts, such as falling down or falling off. Store away from other materials. Packaging material:Comply with laws. Keep only in original container. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust as possible so that workers should not be exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Dust respirator. Follow local and national regulations. Protective gloves. Hand protection: Eye protection:Safety glasses. A face-shield, if the situation requires. Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Solid Form:Crystal- Powder Pale yellow - Reddish yellow Colour: Odour:No data available pH: No data available Melting point/freezing point:166°C Boiling point/range:No data available Flash point:No data available Flammability or explosive limits: Lower:No data available Upper:No data available Relative density:No data available Solubility(ies): [Water]No data available [Other solvents]No data available Section10. STABILITY AND REACTIVITY Chemical stability:Stable under proper conditions. Possibility of hazardous May explosively decompose on heating, shock, friction, etc. reactions: Heat, Spark, Open flame, Shock, Friction Conditions to avoid: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx) products: N,N-Dimethyl-3,5-dinitroaniline Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: No data available IARC = NTP =No data available No data available Reproductive toxicity: Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available Crustacea:No data available Algae:No data available Persistence / degradability: No data available BioaccumulativeNo data available potential(BCF): Mobility in soil Log Pow:No data available Soil adsorption (Koc):No data available Henry's LawNo data available constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities and an expert of disposal. You may be able to dissolve or mix material with a combustible solvent and little by little burn in a chemical incinerator equipped with an afterburner and scrubber system. If a large amount of the substance is burned at a time, an explosion may occur. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:4.1: Flammable solid. UN-No:3224 Proper shipping name:Self-reactive solid type C Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 海关编码 | 2921430090 |
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46429-76-9 |
| 文献：Dutov, Mikhail D.; Serushkina, Olga V. Mendeleev Communications, 2013 , vol. 23, # 3 p. 174 - 175 |
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~92%
46429-76-9 |
| 文献：Chao, Qian; Jinqiang, Liu; Xinzhi, Chen Journal of Chemical Research, 2008 , # 2 p. 70 - 71 |
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| 文献：Lothrop et al. Journal of the American Chemical Society, 1951 , vol. 73, p. 3581 |
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| 文献：Roberts; Selby Journal of the Chemical Society, 1949 , p. 2785,2788 |
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| 文献：Roberts; Selby Journal of the Chemical Society, 1949 , p. 2785,2788 |
| 海关编码 | 2921430090 |
|---|---|
| 中文概述 | 2921430090 甲苯胺及其衍生物以及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 原产地证据文件及编号(例 附原产地证书, 原产于欧盟的 |
| Summary | HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |