16883-61-7

• 常用中文名：异丁酸三甲基硅酯
• 常用英文名：Trimethylsilyl 2-methylpropanoate
• CAS号：16883-61-7
• 分子式：C₇H₁₆O₂Si
• 分子量：160.286
• 发布时间：2018-08-06 12:08:22
• 更新时间：2024-01-09 22:29:26

名称

• 中文名: 异丁酸三甲基硅酯
• 英文名: trimethylsilyl 2-methylpropanoate
• 中文别名: 三甲基甲硅烷基 异丁酸
• 英文别名: Isobuttersaeure-trimethylsilylester; isobutyric acid trimethylsilanyl ester; Propanoic acid, 2-methyl-, trimethylsilyl ester; 2-methylpropionic acid trimethylsilylester; Trimethylsilyl isobutyrate; trimethylsilyl 2-methylpropionate; Isobutyryloxy-trimethyl-silan; Isobutyric acid, trimethylsilyl ester; Isobutyric acid,trimethylsilyl ester; MFCD01632553; Trimethyl-isobutyryloxy-silan; Trimethylsilyl 2-methylpropanoate

物化性质

• 密度: 0.9±0.1 g/cm3
• 沸点: 134.2±9.0 °C at 760 mmHg
• 分子式: C₇H₁₆O₂Si
• 分子量: 160.286
• 闪点: 29.2±14.3 °C
• 精确质量: 160.091949
• PSA: 26.30000
• LogP: 2.11
• 外观性状: 透明无色液体
• 蒸汽压: 8.2±0.2 mmHg at 25°C
• 折射率: 1.404
• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：无可用

  5. 沸点（ºC,常压）：132

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  计算化学数据 纠错 | 编辑

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:2

  4.可旋转化学键数量:3

  5.互变异构体数量:无

  6.拓扑分子极性表面积26.3

  7.重原子数量:10

  8.表面电荷:0

  9.复杂度:124

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

MSDS

Name: TRIMETHYLSILYL ISOBUTYRATE Material Safety Data Sheet Synonym: CAS: 16883-61-7 Section 1 - Chemical Product MSDS Name:TRIMETHYLSILYL ISOBUTYRATE Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 16883-61-7 TRIMETHYLSILYL ISOBUTYRATE unlisted Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a tightly closed container. Keep refrigerated. (Store below 4C/39F.) Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 16883-61-7: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 132 deg C Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: Molecular Weight: 160.29 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 16883-61-7 unlisted. LD50/LC50: Not available. Carcinogenicity: TRIMETHYLSILYL ISOBUTYRATE - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 16883-61-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 16883-61-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 16883-61-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 安全声明 (欧洲): S24/25
• 海关编码: 2931900090

合成路线

56583-93-8 908093-98-1 ~20% 119-61-9 16883-61-7

文献：Journal of Organic Chemistry, , vol. 47, # 15 p. 2900 - 2903

75-77-4 79-31-2 ~% 16883-61-7

文献：Journal of Organometallic Chemistry, , vol. 46, p. 73 - 87

25561-30-2 79-31-2 ~% 16883-61-7

文献：Central European Journal of Chemistry, , vol. 9, # 5 p. 813 - 824

75-77-4 996-30-5 ~% 16883-61-7

文献：Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 528 Chem.Abstr., , # 6298

75669-59-9 ~% 107-46-0 16883-61-7

文献：J. Gen. Chem. USSR (Engl. Transl.), , vol. 50, # 5 p. 1059 - 1064,851 - 855

海关

海关编码	2931900090
中文概述	2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
Summary	2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%