66315-23-9

• 常用中文名：3-氨基-4-甲胺基苯甲酸乙酯
• 常用英文名：Ethyl 3-amino-4-(methylamino)benzoate
• CAS号：66315-23-9
• 分子式：C₁₀H₁₄N₂O₂
• 分子量：194.230
• 发布时间：2019-01-12 16:10:02
• 更新时间：2024-01-23 10:36:28
• 下载msds

名称

• 中文名: 3-氨基-4-(甲胺基)苯甲酸乙酯
• 英文名: Ethyl 3-amino-4-(methylamino)benzoate
• 中文别名: 3-氨基-4-甲胺基苯甲酸乙酯; 3-氨基-4-(甲基氨基)苯甲酸乙酯
• 英文别名: Ethyl 3-amino-4-(methylamino)benzoate; Benzoic acid, 3-amino-4-(methylamino)-, ethyl ester; Ethyl3-amino-4-(methylamino)benzoate

物化性质

• 密度: 1.2±0.1 g/cm3
• 沸点: 357.4±32.0 °C at 760 mmHg
• 熔点: 81ºC
• 分子式: C₁₀H₁₄N₂O₂
• 分子量: 194.230
• 闪点: 169.9±25.1 °C
• 精确质量: 194.105530
• PSA: 64.35000
• LogP: 1.85
• 蒸汽压: 0.0±0.8 mmHg at 25°C
• 折射率: 1.598
• 储存条件: 2-8°C

MSDS

Name: Ethyl 3-amino-4-(methylamino)benzoate 97% Material Safety Data Sheet Synonym: CAS: 66315-23-9 Section 1 - Chemical Product MSDS Name:Ethyl 3-amino-4-(methylamino)benzoate 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 66315-23-9 Ethyl 3-amino-4-(methylamino)benzoate 97% unlisted Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 66315-23-9: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 81 - 85 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C10H14N2O2 Molecular Weight: 194.23 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 66315-23-9 unlisted. LD50/LC50: Not available. Carcinogenicity: Ethyl 3-amino-4-(methylamino)benzoate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 66315-23-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 66315-23-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 66315-23-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi:Irritant;
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S37/39
• 海关编码: 2922499990

合成路线

71254-71-2 ~80% 66315-23-9

文献：Uchida, Hiroshi; Asagarasu, Akira; Matsui, Teruaki Patent: US2013/79306 A1, 2013 ; Location in patent: Paragraph 0234; 0235; 0236; 0237 ;

453-71-4 ~% 66315-23-9

文献：US2013/79306 A1, ;

367-80-6 ~% 66315-23-9

文献：US2013/79306 A1, ;

上下游产品

上游产品  3
71254-71-2 453-71-4 367-80-6
下游产品  2
53484-19-8 115576-91-5

海关

海关编码	2922499990
中文概述	2922499990 其他氨基酸及其酯及它们的盐（含有一种以上含氧基的除外）. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装
监管条件	A.入境货物通关单 B.出境货物通关单
检验检疫	P.进境动植物、动植物产品检疫 Q.出境动植物、动植物产品检疫 R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验
Summary	HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%