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7789-39-1生产厂家

7789-39-1价格

7789-39-1

7789-39-1结构式
7789-39-1结构式

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中文名 溴化铷
英文名 Rubidium bromide
英文别名 Rubidium bromide
rubidium(1+),bromide
MFCD00011186
EINECS 232-162-5
密度 3.35 g/mL at 25 °C(lit.)
沸点 1340 °C
熔点 693 °C
分子式 BrRb
分子量 165.372
闪点 1340°C
精确质量 163.830124
外观性状 白色结晶粉末
折射率 1.5530
储存条件

密封干燥保存。

稳定性

如果遵照规格使用和储存则不会分解

避免接触酸,水分/潮湿. RbBr易溶于水,在16℃每100g水溶解104.8g;对空气稳定,在氮气氛下,熔体不显碱性。

水溶解性 不同温度(℃)时每100毫升水中的溶解克数: 90g/0℃;99g/10℃;108g/20℃;119g/30℃;132g/40℃ 158g/60℃
计算化学

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:1

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:2

8.表面电荷:0

9.复杂度:2

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

更多

1. 性状:呈立方面心晶格。有吸湿性。

2. 密度(g/mL 25ºC):3.349

3. 相对蒸汽密度(g/mL,空气=1):3.35

4. 熔点(ºC):6821

5. 沸点(ºC,常压):1350

6. 沸点(ºC,5.2kPa):未确定

7. 折射率(n20/D):1.5530

8. 闪点(ºC,):1340

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):未确定

11. 蒸气压(kPa,25ºC):未确定

12. 饱和蒸气压(kPa,60ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值(25℃):未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性(mg/mL):溶于水,微溶于乙醇,水溶液呈中性。

Name: Rubidium bromide 99% Material Safety Data Sheet
Synonym:
CAS: 7789-39-1
Section 1 - Chemical Product MSDS Name:Rubidium bromide 99% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
7789-39-1 Rubidium bromide 99.0 232-162-5
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects was found.
Skin:
No information regarding skin irritation and other potential effects was found.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
Inhalation of dust may cause respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7789-39-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 1340 deg C @ 760.00mm Hg
Freezing/Melting Point: 682 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in about 1 part cold water; 0.5
Specific Gravity/Density: 3.35
Molecular Formula: BrRb
Molecular Weight: 165.38

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents Hazardous Decomposition Products:
Hydrogen chloride, hydrogen bromide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7789-39-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Rubidium bromide - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7789-39-1: 1
Canada
CAS# 7789-39-1 is listed on Canada's DSL List.
CAS# 7789-39-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7789-39-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

生态学数据:

对水是稍微危害的,若无政府许可,勿将材料排入周围环境

个人防护装备 Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
危害码 (欧洲) Xi
安全声明 (欧洲) S22-S24/25
危险品运输编码 NONH for all modes of transport
WGK德国 3

主要有两个,一是碳酸铷用氢溴酸中和,另一是硫酸铷和相当量的氢氧化钡反应得到铷的氢氧化物,再用氢溴酸转化。

为得到纯品,通常在得到RbOH后,用酒石酸处理;生成酒石酸氢铷,在铂皿中析晶,加热转化为碳酸盐。冷却此残渣,用氢溴酸作用,滤去不溶物,将滤液蒸发析晶,并加氢溴酸进一步转化为溴化铷。加热直到熔体呈中性反应。