1530-39-8

• 常用中文名：4-氯苄基三苯基氯化磷鎓盐
• 常用英文名：(4-Chlorobenzyl)(triphenyl)phosphonium chloride
• CAS号：1530-39-8
• 分子式：C₂₅H₂₁Cl₂P
• 分子量：423.314
• 相关类别： 化学试剂 有机试剂 卤化磷
• 发布时间：2018-08-17 20:19:31
• 更新时间：2024-01-04 09:53:19
• 下载msds

名称

• 中文名: 4-氯苄基三苯基氯化磷蓊盐
• 英文名: (4-chlorobenzyl)triphenylphosphonium chloride
• 中文别名: (4-氯苄基)三苯基氯化磷; 4-氯苄基三苯基氯化磷鎓盐; 4-(氯苄基)三苯基氯化磷鎓盐
• 英文别名: [(4-Chlorophenyl)methyl]triphenylphosphonium chloride; EINECS 216-228-0; (4-Chlorobenzyl)triphenylphosphonium Chloride; (4-Chlorobenzyl)(triphenyl)phosphonium chloride; Phosphonium, [(4-chlorophenyl)methyl]triphenyl-, chloride (1:1); (4-chlorophenyl)methyl-triphenylphosphanium,chloride; MFCD00041533

物化性质

• 熔点: >300 °C(lit.)
• 分子式: C₂₅H₂₁Cl₂P
• 分子量: 423.314
• 精确质量: 422.075806
• PSA: 13.59000
• LogP: 2.83810
• 外观性状: 固体;White to Almost white powder to crystal
• 储存条件:

  保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置

• 稳定性:

  如果遵照规格使用和储存则不会分解，未有已知危险反应，避免氧化物

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:1

  4.可旋转化学键数量:5

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:28

  8.表面电荷:0

  9.复杂度:378

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:2

• 更多:

  1. 性状：粉末。

  2. 密度（g/mL,25/4℃）： 未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：>300

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,5.2kPa）： 未确定

  7. 折射率： 未确定

  8. 闪点（ºC）： 未确定

  9. 比旋光度（º）： 未确定

  10. 自燃点或引燃温度（ºC）： 未确定

  11. 蒸气压（kPa,25ºC）： 未确定

  12. 饱和蒸气压（kPa,60ºC）： 未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）： 未确定

  15. 临界压力（KPa）： 未确定

  16. 油水（辛醇/水）分配系数的对数值： 未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）： 未确定

  19. 溶解性：未确定

MSDS

Name: (4-Chlorobenzyl)triphenylphosphonium chloride 98% Material Safety Data Sheet Synonym: CAS: 1530-39-8 Section 1 - Chemical Product MSDS Name:(4-Chlorobenzyl)triphenylphosphonium chloride 98% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 1530-39-8 (4-Chlorobenzyl)triphenylphosphonium c 98 216-228-0 Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1530-39-8: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Crystalline powder Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 280 - 283 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: soluble in water Specific Gravity/Density: Molecular Formula: Molecular Weight: 423.32 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, oxides of phosphorus, carbon dioxide. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1530-39-8 unlisted. LD50/LC50: Not available. Carcinogenicity: (4-Chlorobenzyl)triphenylphosphonium chloride - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 1530-39-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 1530-39-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1530-39-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 对是水稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统，若无政府许可，勿将材料排入周围环境。

安全

• 符号: GHS07
• 信号词: Warning
• 危害声明: H315-H319-H335
• 警示性声明: P261-P305 + P351 + P338
• 个人防护装备: dust mask type N95 (US);Eyeshields;Gloves
• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): 36/37/38
• 安全声明 (欧洲): S26-S36
• 危险品运输编码: NONH for all modes of transport
• WGK德国: 3
• 海关编码: 2931900090

合成路线

104-83-6 603-35-0 ~86% 1530-39-8

文献：Warner, Philip; Sutherland, Robert Journal of Organic Chemistry, 1992 , vol. 57, # 23 p. 6294 - 6300

873-76-7 ~% 1530-39-8

文献：Journal of Medicinal Chemistry, , vol. 42, # 6 p. 1007 - 1017

74-11-3 ~% 1530-39-8

文献：Journal of Organic Chemistry, , vol. 58, # 21 p. 5643 - 5649

603-35-0 873-76-7 ~% 1530-39-8

文献：Journal of Organic Chemistry, , vol. 58, # 21 p. 5643 - 5649

上下游产品

上游产品  4
104-83-6 603-35-0 873-76-7 74-11-3
下游产品  7
22711-23-5 1762-83-0 15107-41-2 86508-29-4
62102-59-4 630413-80-8 5216-35-3

海关

海关编码	2931900090
中文概述	2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
Summary	2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%