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51011-54-2

51011-54-2结构式
51011-54-2结构式

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中文名 1-(6-氯-1,3-苯并噻唑-2-基)肼
英文名 (6-chloro-1,3-benzothiazol-2-yl)hydrazine
中文别名 (6-氯-1,3-苯并噻唑-2-基)肼
英文别名 F1908-0017
1,2-Hydrazino-6-chlorobenzothiazole
6-chloro-2-hydrazino-benzothiazole
(6-chlorobenzothiazol-2-yl)hydrazine
1-(6-CHLOROBENZO[D]THIAZOL-2-YL)HYDRAZINE
1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine
6-Chloro-2-hydrazinylbenzo[d]thiazole
6-chloro-2-hydrazino-1,3-benzothiazole
6-chloro-2-hydrazinyl-1,3-benzothiazole
2-hydrazino-6-chloro-1,3-benzothiazole
密度 1.599g/cm3
沸点 361.293ºC at 760 mmHg
熔点 263ºC
分子式 C7H6ClN3S
分子量 199.66100
闪点 172.304ºC
精确质量 198.99700
PSA 79.18000
LogP 3.00860
折射率 1.813
Name: 1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine, 97% Material Safety Data Sheet
Synonym:
CAS: 51011-54-2
Section 1 - Chemical Product MSDS Name: 1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine, 97% Material Safety Data Sheet
Synonym:

SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
51011-54-2 1-(6-Chloro-1,3-benzothiazol-2-yl)hydr 97% unlisted
+++++
Hazard Symbols: XN
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.
SECTION 4 - FIRST AID MEASURES
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.
SECTION 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 51011-54-2: Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 212 - 215 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H6ClN3S
Molecular Weight: 199.66
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 51011-54-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-(6-Chloro-1,3-benzothiazol-2-yl)hydrazine - Not listed by ACGIH, IARC, or NTP.
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 51011-54-2: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 51011-54-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 51011-54-2 is not listed on the TSCA inventory. It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 6/10/2003 Revision #0 Date: Original. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A
危害码 (欧洲) Xi
风险声明 (欧洲) R20/21/22;R36/37/38
安全声明 (欧洲) S26-S36/37/39
海关编码 2934200090

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51011-54-2结构式

51011-54-2

文献:Himaja; Munirajasekhar; Karigar, Asif; Ramana; Sikarwar, Mukesh Asian Journal of Chemistry, 2012 , vol. 24, # 6 p. 2789 - 2792

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51011-54-2结构式

51011-54-2

文献:Varma, R. S.; Tewari, Manju Journal of the Indian Chemical Society, 1989 , vol. 66, p. 39 - 41

~%

51011-54-2结构式

51011-54-2

文献:Stella, Alessandro; Segers, Kenneth; De Jonghe, Steven; Vanderhoydonck, Bart; Rozenski, Jef; Anne, Jozef; Herdewijn, Piet Chemistry and Biodiversity, 2011 , vol. 8, # 2 p. 253 - 265

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51011-54-2结构式

51011-54-2

文献:Varma, R. S.; Tewari, Manju Journal of the Indian Chemical Society, 1989 , vol. 66, p. 39 - 41
海关编码 2934200090
中文概述 2934200090. 其他含一个苯并噻唑环系的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素 品名, 成分含量, 用途
Summary 2934200090. other compounds containing in the structure a benzothiazole ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%